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Acid modified phenol-aldehyde resinous condensation products and friction particles therefrom

Assignee: CARDOLITE Corp A CORP OF NEW JERSEY
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Filing: 1976-04-16
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Granted: 1977-05-31
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Expires: 1996-04-16
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Abstract

Abstract Friction modifying particles are formed from acid modified phenol-aldehyde resins and the polyvalent metal salts thereof.

Inventors

  • 👤 Robert A. Gardiner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 12:30
CPC Classifications
F; F16; F16D; F16D69/00; F16D69/02; F16D69/025; C; C08; C08G; C08G8/00; C08G8/04; C08G8/08; C08G8/18

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 34 words
A resinous condensation product of (1) the ene reaction adduct of dienophilic alpha-beta-unsaturated aliphatic carboxylic acid or anhydride or ester thereof with unsaturated cashew nut shell liquid phenol or oligomer thereof and (2) aldehyde.
Claim 2
Dependent Claim 34 words
A resinous condensation product of (1) the ene reaction adduct of dienophilic alpha-beta-unsaturated aliphatic carboxylic acid or anhydride or ester thereof with unsaturated cashew nut shell liquid phenol or oligomer thereof and (2) aldehyde.
Claim 3
Dependent Claim 22 words
The resinous condensation product of claim 1 wherein alpha-beta unsaturated acid or derivative is maleic acid or anhydride and aldehyde is formaldehyde.
Claim 4
Dependent Claim 108 words
As a composition of matter, a resinous condensation product of aldehyde and phenol wherein the phenol comprises meta(carboxy-alkenyl)substituted phenol of the formula: ##STR3## wherein R is a carboxy-alkenyl group containing at least one ethylenic double bond of the formula --C.sub.n H.sub.2n.sub.-x (CO.sub.2 M).sub.m where n is 17 to 21, m is an integer from 1 to y'1, x is an integer from 2 to 11 inclusive and is odd when m is even and even when m is odd, x-m=y, y is 1, 3 or 5, M is H or one equivalent of a polyvalent metal and X is H or OH; or an oligomer of said phenol.
Claim 5
Dependent Claim 108 words
As a composition of matter, a resinous condensation product of aldehyde and phenol wherein the phenol comprises meta(carboxy-alkenyl)substituted phenol of the formula: ##STR3## wherein R is a carboxy-alkenyl group containing at least one ethylenic double bond of the formula --C.sub.n H.sub.2n.sub.-x (CO.sub.2 M).sub.m where n is 17 to 21, m is an integer from 1 to y'1, x is an integer from 2 to 11 inclusive and is odd when m is even and even when m is odd, x-m=y, y is 1, 3 or 5, M is H or one equivalent of a polyvalent metal and X is H or OH; or an oligomer of said phenol.
Claim 6
Dependent Claim 20 words
The resinous composition of matter according to claim 3 wherein n is 17, m is 2 and y is 1.
Claim 7
Dependent Claim 20 words
The resinous composition of matter according to claim 3 wherein n is 19, m is 4 and y is 3.
Claim 8
Dependent Claim 109 words
A friction modifying particle comprising a fully cured condensation product of aldehyde and phenol wherein the phenol comprises meta-(carboxy-alkenyl)substituted phenol of the formula: ##STR4## wherein R is a carboxy-alkenyl group containing at least one ethylenic double bond of the formula --C.sub.n H.sub.2n.sub.-x (CO.sub.2 M).sub.m where n is 17 to 21, m is an integer from 1 to y+1, x is an integer from 2 to 11 inclusive and is odd when m is even and even when m is odd, x-m=y, y is 1, 3 or 5, M is H or one equivalent of a polyvalent metal and X is H or OH; or an oligomer of said phenol.
Claim 9
Dependent Claim 109 words
A friction modifying particle comprising a fully cured condensation product of aldehyde and phenol wherein the phenol comprises meta-(carboxy-alkenyl)substituted phenol of the formula: ##STR4## wherein R is a carboxy-alkenyl group containing at least one ethylenic double bond of the formula --C.sub.n H.sub.2n.sub.-x (CO.sub.2 M).sub.m where n is 17 to 21, m is an integer from 1 to y+1, x is an integer from 2 to 11 inclusive and is odd when m is even and even when m is odd, x-m=y, y is 1, 3 or 5, M is H or one equivalent of a polyvalent metal and X is H or OH; or an oligomer of said phenol.
Claim 10
Dependent Claim 11 words
A friction component comprising friction modifying particles according to claim 6.

References Cited (Backward Citations)

US2114121A Cited
US2506904A Cited
US3020254A Cited
US3624038A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-30 1980-11-29 1981-05-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-30 1984-11-29 1985-05-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-30 1988-11-29 1989-05-31 $7700.00 Window Closed / Lapsed

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