Patent EP0343131A2 successfully refreshed from Google Patents.
Patent US4026761A successfully refreshed from Google Patents.
US4026761A
Expired / Lapsed
US
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Process for the preparation of diepoxides
Assignee: Societa Italiana Resine SpA SIR
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Filing: 1976-07-08
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Granted: 1977-05-31
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Expires: 1996-07-08
Abstract
Abstract Diepoxides of the general formula: ##STR1## wherein n has an average value not exceeding 0.03 and R is the bisphenyl radical of bisphenol-A are recovered from an epoxy resin of the same general formula with n varying from 0.07 to 0.30, by removing the low-boiling substance from the epoxy resin at 0.1-1 mm Hg and 165°-200° C and distilling off said diepoxide from the thus treated epoxy resin at 0.1-0.005 mm Hg and a temperature not exceeding 240° C. The low viscosity, narrow molecular weight distribution and excellent purity of these diepoxides allow their use in critical application fields.
Inventors
- 👤 Silvio Vargiu
- 👤 Giancarlo Crespolini
- 👤 Giulio Grazzini
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-09 15:40
CPC Classifications
C; C08; C08G; C08G59/00; C08G59/02; C08G59/025; C08G59/04; C08G59/06; C08G59/063; Y; Y10; Y10S; Y10S159/00; Y10S159/08; Y10S159/15; Y10S159/16
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
166 words
A method for recovering a diepoxide having a viscosity of from 3,000 to 4,600 cps at 25° C., defined by means of the formula: ##STR4## wherein R is the bisphenyl radical of bisphenol-A (HO--R--OH) and n has an average value not exceeding 0.03, from a liquid epoxy resin having a viscosity of from 7,000 to 40,000 cps at 25° C. defined by means of formula (I) wherein n has an average value of from 0.07 to 0.30, characterized by removing in a first evaporation step the low-boiling substances from said epoxy resin at a pressure of from 0.1 to 1 mm Hg and at a temperature of from 165° to 200° C., and distilling off said diepoxide from the thus treated epoxy resin, in a second evaporation step, at a pressure of from 0.1 to 0.005 mm Hg and at a temperature not exceeding 240° C., the overall residence time of said epoxy resin in said first and second evaporation steps not exceeding about 100 seconds.
Claim 2
Independent Claim
166 words
A method for recovering a diepoxide having a viscosity of from 3,000 to 4,600 cps at 25° C., defined by means of the formula: ##STR4## wherein R is the bisphenyl radical of bisphenol-A (HO--R--OH) and n has an average value not exceeding 0.03, from a liquid epoxy resin having a viscosity of from 7,000 to 40,000 cps at 25° C. defined by means of formula (I) wherein n has an average value of from 0.07 to 0.30, characterized by removing in a first evaporation step the low-boiling substances from said epoxy resin at a pressure of from 0.1 to 1 mm Hg and at a temperature of from 165° to 200° C., and distilling off said diepoxide from the thus treated epoxy resin, in a second evaporation step, at a pressure of from 0.1 to 0.005 mm Hg and at a temperature not exceeding 240° C., the overall residence time of said epoxy resin in said first and second evaporation steps not exceeding about 100 seconds.
Claim 3
Dependent Claim
25 words
The method of claim 1, wherein said first evaporation step is carried out in a thin falling film evaporation of the static or dynamic type.
Claim 4
Dependent Claim
24 words
The method of claim 1, wherein the residence time of said epoxy resin in said first evaporation step is from 30 to 60 seconds.
Claim 5
Dependent Claim
30 words
The method of claim 1, wherein an amount of low-boiling substances of from 0.5 to 1.5 wt.% with respect to said epoxy resin is removed in said first evaporation step.
Claim 6
Dependent Claim
22 words
The method of claim 1, wherein said second evaporation step is carried out at a temperature of from 180° to 240° C.
Claim 7
Dependent Claim
22 words
The method of claim 1, wherein said second evaporation step is carried out in a guided rotating film evaporator with internal condensation.
Claim 8
Dependent Claim
25 words
The method of claim 1, wherein the residence time of said treated epoxy resin in said second evaporation step is from 20 to 40 seconds.
Claim 9
Dependent Claim
31 words
The method of claim 1, wherein an amount of diepoxide of from 60 to 85 wt.% with respect to said treated epoxy resin is distilled off in said second evaporation step.
Claim 10
Dependent Claim
38 words
The method of claim 1, wherein said diepoxide distilled off in said second evaporation step has an average value of n of from 0 to 0.01 and a viscosity at 25° C. of from 3,000 to 3,800 cps.
References Cited (Backward Citations)
US3410761A
Cited
US3892634A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-30 | 1980-11-29 | 1981-05-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-30 | 1984-11-29 | 1985-05-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-30 | 1988-11-29 | 1989-05-31 | $7700.00 | Window Closed / Lapsed |