Plasma etching process for making a microcircuit device

Claim 1

A method of making a microcircuit on a semiconductor substrate comprising the steps of: covering said semiconductor substrate with an insulating film; photoetching said insulating film at desired locations to form windows therein exposing the said semiconductor substrate; forming a reactive electrically conductive metal layer selected from the group consisting of tungsten, molybdenum, rhenium, osmium and iridium covering said insulating film and extending through said windows for covering the exposed semiconductor substrate; forming a mask layer of photoresist in a desired pattern on said reactive electrically conductive metal layer; contacting said semiconductor substrate with a plasma composed only of a halogenated gas consisting essentially of a perhalogenated organic compound containing fluorine atoms generated by a high-frequency electromagnetic field in an inert carrier gas under a reduced pressure of about 0.10 to 0.55 mm Hg, thereby converting said reactive electrically conductive metal of those areas which are not covered with said mask layer to a metal fluoride and removing said metal fluoride; and removing said photoresist mask layer with a gas containing oxygen in a plasma state to form a wiring layer of the reactive electrically conductive metal layer remaining on said insulating film.

Claim 2

A method of making a microcircuit on a semiconductor substrate comprising the steps of: covering said semiconductor substrate with an insulating film; photoetching said insulating film at desired locations to form windows therein exposing the said semiconductor substrate; forming a reactive electrically conductive metal layer selected from the group consisting of tungsten, molybdenum, rhenium, osmium and iridium covering said insulating film and extending through said windows for covering the exposed semiconductor substrate; forming a mask layer of photoresist in a desired pattern on said reactive electrically conductive metal layer; contacting said semiconductor substrate with a plasma composed only of a halogenated gas consisting essentially of a perhalogenated organic compound containing fluorine atoms generated by a high-frequency electromagnetic field in an inert carrier gas under a reduced pressure of about 0.10 to 0.55 mm Hg, thereby converting said reactive electrically conductive metal of those areas which are not covered with said mask layer to a metal fluoride and removing said metal fluoride; and removing said photoresist mask layer with a gas containing oxygen in a plasma state to form a wiring layer of the reactive electrically conductive metal layer remaining on said insulating film.