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US4025566A
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Process for preparing monoalkyl ethers of dihydric phenols
Assignee: Ube Corp
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Filing: 1976-02-10
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Granted: 1977-05-24
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Expires: 1996-02-10
Abstract
Abstract Process for preparing monoalkyl ethers of dihydric phenols using a catalyst comprising Al, B and P.
Inventors
- 👤 Shigeki Nagai
- 👤 Hiroshi Yoshida
- 👤 Teruhiko Inoue
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 05:05
CPC Classifications
B; B01; B01J; B01J27/00; B01J27/14; B01J27/16; B01J27/18; B01J27/1802
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
72 words
A process for preparing a monoalkyl ether of a dihydric phenol which comprises contacting from 2 to 0.1 part by weight of a dihydric phenol with one part by weight of a lower alcohol having from 1 to 4 carbon atoms with a catalyst comprising aluminum, boron and phosphorus at a temperature of from 250° C. to 350° C., the atomic ratio of Al:B:P in said catalyst being from 1:1:2 to 1:3:4.
Claim 2
Dependent Claim
72 words
A process for preparing a monoalkyl ether of a dihydric phenol which comprises contacting from 2 to 0.1 part by weight of a dihydric phenol with one part by weight of a lower alcohol having from 1 to 4 carbon atoms with a catalyst comprising aluminum, boron and phosphorus at a temperature of from 250° C. to 350° C., the atomic ratio of Al:B:P in said catalyst being from 1:1:2 to 1:3:4.
Claim 3
Dependent Claim
29 words
The process as claimed in claim 1, wherein the dihydric phenol is substituted with a lower alkyl radical having from 1 to 4 carbon atoms or a halogen atom.
Claim 4
Dependent Claim
33 words
The process as claimed in claim 1, wherein said dihydric phenol and said lower alcohol are so contacted in a gaseous state with a fixed bed of said catalyst at substantially atmospheric pressure.
Claim 5
Dependent Claim
13 words
The process as claimed in claim 1, wherein said dihydric phenol is catechol.
Claim 6
Dependent Claim
13 words
The process as claimed in claim 1, wherein said dihydric phenol is hydroquinone.
Claim 7
Dependent Claim
14 words
The process as claimed in claim 1, wherein said lower alcohol is methyl alcohol.
Claim 8
Dependent Claim
14 words
The process as claimed in claim 1, wherein said lower alcohol is ethyl alcohol.
Claim 9
Dependent Claim
25 words
The process as claimed in claim 1, wherein said monoalkyl ether is guaiacol, said dihydric phenol is catechol and said lower alcohol is methyl alcohol.
Claim 10
Dependent Claim
27 words
The process as claimed in claim 1, wherein said monoalkyl ether is catechol monoethyl ether, said dihydric phenol is catechol and said lower alcohol is ethyl alcohol.
Claim 11
Dependent Claim
27 words
The process as claimed in claim 1, wherein said monoalkyl ether is hydroquinone monomethyl ether, said dihydric phenol is hydroquinone and said lower alcohol is methyl alcohol.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-23 | 1980-11-22 | 1981-05-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-23 | 1984-11-22 | 1985-05-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-23 | 1988-11-22 | 1989-05-24 | $7700.00 | Window Closed / Lapsed |