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US4025566A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for preparing monoalkyl ethers of dihydric phenols

Assignee: Ube Corp
•
Filing: 1976-02-10
•
Granted: 1977-05-24
•
Expires: 1996-02-10
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Abstract

Abstract Process for preparing monoalkyl ethers of dihydric phenols using a catalyst comprising Al, B and P.

Inventors

  • 👤 Shigeki Nagai
  • 👤 Hiroshi Yoshida
  • 👤 Teruhiko Inoue

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 04:28
CPC Classifications
B; B01; B01J; B01J27/00; B01J27/14; B01J27/16; B01J27/18; B01J27/1802

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 72 words
A process for preparing a monoalkyl ether of a dihydric phenol which comprises contacting from 2 to 0.1 part by weight of a dihydric phenol with one part by weight of a lower alcohol having from 1 to 4 carbon atoms with a catalyst comprising aluminum, boron and phosphorus at a temperature of from 250° C. to 350° C., the atomic ratio of Al:B:P in said catalyst being from 1:1:2 to 1:3:4.
Claim 2
Dependent Claim 72 words
A process for preparing a monoalkyl ether of a dihydric phenol which comprises contacting from 2 to 0.1 part by weight of a dihydric phenol with one part by weight of a lower alcohol having from 1 to 4 carbon atoms with a catalyst comprising aluminum, boron and phosphorus at a temperature of from 250° C. to 350° C., the atomic ratio of Al:B:P in said catalyst being from 1:1:2 to 1:3:4.
Claim 3
Dependent Claim 29 words
The process as claimed in claim 1, wherein the dihydric phenol is substituted with a lower alkyl radical having from 1 to 4 carbon atoms or a halogen atom.
Claim 4
Dependent Claim 33 words
The process as claimed in claim 1, wherein said dihydric phenol and said lower alcohol are so contacted in a gaseous state with a fixed bed of said catalyst at substantially atmospheric pressure.
Claim 5
Dependent Claim 13 words
The process as claimed in claim 1, wherein said dihydric phenol is catechol.
Claim 6
Dependent Claim 13 words
The process as claimed in claim 1, wherein said dihydric phenol is hydroquinone.
Claim 7
Dependent Claim 14 words
The process as claimed in claim 1, wherein said lower alcohol is methyl alcohol.
Claim 8
Dependent Claim 14 words
The process as claimed in claim 1, wherein said lower alcohol is ethyl alcohol.
Claim 9
Dependent Claim 25 words
The process as claimed in claim 1, wherein said monoalkyl ether is guaiacol, said dihydric phenol is catechol and said lower alcohol is methyl alcohol.
Claim 10
Dependent Claim 27 words
The process as claimed in claim 1, wherein said monoalkyl ether is catechol monoethyl ether, said dihydric phenol is catechol and said lower alcohol is ethyl alcohol.
Claim 11
Dependent Claim 27 words
The process as claimed in claim 1, wherein said monoalkyl ether is hydroquinone monomethyl ether, said dihydric phenol is hydroquinone and said lower alcohol is methyl alcohol.

References Cited (Backward Citations)

US2615051A Cited
US2782239A Cited
US3895076A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-23 1980-11-22 1981-05-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-23 1984-11-22 1985-05-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-23 1988-11-22 1989-05-24 $7700.00 Window Closed / Lapsed

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