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US4024093A
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Flame retardant polyphenylene ether resin compositions containing a halogenated flame retardant and selected organic iron salts
Assignee: General Electric Co
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Filing: 1975-01-23
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Granted: 1977-05-17
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Expires: 1995-01-23
Abstract
Abstract Novel flame retardant polyphenylene ether resin compositions are disclosed which include, as a combination of flame retardants, a halogenated flame retardant and an organic iron compound wherein the organic group is derived from a compound of the formula: ##STR1## WHEREIN R 1 is selected from the group consisting of hydrogen, hydroxyl and lower alkylene carboxy wherein the alkylene moiety has from 1-4 carbon atoms; R 2 is selected from the group consisting of hydrogen, hydroxyl and lower alkyl of 1-4 carbon atoms; R 3 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms, hydroxyl, lower alkylene carboxy, aryl, aralkyl, alkaryl, lower alkylidene carboxy wherein the alkylidene moiety has from 1-4 carbon atoms and n is a whole number of from 1 to 20 with the proviso that no compound has more than six hydroxy groups.
Inventors
- 👤 Visvaldis Abolins
- 👤 Fred F. Holub
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 20:39
CPC Classifications
C; C08; C08L; C08L51/00; C08L51/04; C08K; C08K5/00; C08K5/02; C08K5/03; C08K5/04; C08K5/09; C08K5/098; C08L25/00; C08L25/02; C08L25/04; C08L53/00; C08L53/02; C08L55/00; C08L55/02; C08L71/00; C08L71/08; C08L71/10; C08L71/12; C08L71/123; C08L2201/00; C08L2201/02; C08L25/18; C08L69/00
Claims Analysis
Total Claims: 29
Claim 1
Independent Claim
157 words
A flame retardant thermoplastic molding composition which comprises: a. a polyphenylene ether resin; b. a vinyl aromatic resin; c. a flame retardant amount of an aromatic halogenated flame retardant; and d. a flame retardant amount of an organic iron compound in which the organic group is derived from a compound of the formula: ##STR9## wherein R 1 is selected from the group consisting of hydrogen, hydroxyl and lower alkylene carboxy wherein the alkylene moiety has from 1-4 carbon atoms; R 2 is selected from the group consisting of hydrogen, hydroxyl and lower alkyl of 1-4 carbon atoms; R 3 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms, hydroxyl, lower alkylene carboxy, aryl, aralkyl, alkaryl, lower alkylidene carboxy wherein the alkylidene moiety has from 1 to 4 carbon atoms and n is a whole number of from 1 to 20 with the proviso that no compound has more than six hydroxy groups.
Claim 2
Dependent Claim
157 words
A flame retardant thermoplastic molding composition which comprises: a. a polyphenylene ether resin; b. a vinyl aromatic resin; c. a flame retardant amount of an aromatic halogenated flame retardant; and d. a flame retardant amount of an organic iron compound in which the organic group is derived from a compound of the formula: ##STR9## wherein R 1 is selected from the group consisting of hydrogen, hydroxyl and lower alkylene carboxy wherein the alkylene moiety has from 1-4 carbon atoms; R 2 is selected from the group consisting of hydrogen, hydroxyl and lower alkyl of 1-4 carbon atoms; R 3 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms, hydroxyl, lower alkylene carboxy, aryl, aralkyl, alkaryl, lower alkylidene carboxy wherein the alkylidene moiety has from 1 to 4 carbon atoms and n is a whole number of from 1 to 20 with the proviso that no compound has more than six hydroxy groups.
Claim 3
Dependent Claim
76 words
A composition as defined in claim 1 wherein the aromatic halogenated flame retardant is selected from the group consisting of chlorinated benzene, brominated benzene, chlorinated biphenyl, chlorinated terphenyl, brominated biphenyl, brominated terphenyl, a compound comprising two phenyl radicals separated by a divalent alkylene or oxygen group and having at least two substituents selected from the group consisting of chlorine and bromine per phenyl radical, monochloropolystyrene, bromine containing aromatic polycarbonates, chlorine containing aromatic polycarbonates and mixtures thereof.
Claim 4
Dependent Claim
16 words
A composition as defined in claim 2 wherein said aromatic halogenated flame retardant is decabromodiphenyl oxide.
Claim 5
Dependent Claim
15 words
A composition as defind in claim 2 wherein said aromatic halogenated flame retardant is hexabromobiphenyl.
Claim 6
Dependent Claim
15 words
A composition as defined in claim 2 wherein said aromatic halogenated flame retardant is hexachlorobiphenyl.
Claim 7
Dependent Claim
16 words
A composition as defined in claim 2 wherein said aromatic halogenated flame retardant is chlorinated terphenyl.
Claim 8
Dependent Claim
61 words
A composition as defined in claim 2 wherein said aromatic halogenated flame retardant is a bromo containing polycarbonate that is an aromatic carbonate copolymer in which from 25 to 75 wt. percent of the repeating units comprise and are derived from bromo substituted dihydric phenol units and the remainder of the repeating units comprise and are derived from dihydric phenol units.
Claim 9
Dependent Claim
39 words
A composition as defined in claim 1 wherein from 10 to 30 parts by weight of the aromatic halogenated flame retardant compound is employed and from 0.1 to 2.5 parts by weight of said organic iron compound is employed.
Claim 10
Dependent Claim
97 words
A composition as defined in claim 1 wherein said polyphenylene ether has the repeating structural formula: ##STR10## wherein the oxygen ether atom of one unit is connected to the benzene nucleus of the next adjoining unit, n is a positive integer and is at least 50, and each Q is a monovalent substituent selected from the group consisting of hydrogen, halogen, hydrocarbon radicals free of a tertiary alpha carbon atom, halohydrocarbon radicals having at least two carbon atoms between the halogen atom and the phenyl nucleus, hydrocarbonoxy radicals and halohydrocarbonoxy radicals having at least two carbon atoms.
Claim 11
Dependent Claim
119 words
A composition as defined in claim 1 wherein at least 25% of the units of said vinyl aromatic resin are of the formula: ##STR11## wherein R 1 and R 2 are selected from the group consisting of lower alkyl or alkenyl groups of from 1 to 6 carbon atoms and hydrogen; R 3 and R 4 are selected from the group consisting of chloro, bromo, hydrogen and lower alkyl of from 1 to 6 carbon atoms; R 5 and R 6 are selected from the group consisting of hydrogen and lower alkyl and alkenyl groups of from 1 to 6 carbons or R 5 and R 6 may be concatenated together with hydrocarbyl groups to form a naphthyl group.
Claim 12
Dependent Claim
176 words
A flame retardant thermoplastic molding composition which comprises: a. from 10-90 parts by weight of a polyphenylene ether resin; b. from 90-10 parts by weight of a rubber modified high-impact polystyrene resin; c. from 10 to 30 parts by weight of an aromatic halogenated flame retardant compound; and d. from 0.1 to 2.5 parts by weight of an organic iron compound in which the organic component is derived from a group of the formula: ##STR12## wherein R 1 is selected from the group consisting of hydrogen, hydroxyl and lower alkylene carboxy wherein the alkylene moiety has from 1-4 carbon atoms; R 2 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms and hydroxyl; R 3 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms, hydroxyl, lower alkylene carboxy, aryl, aralkyl, alkaryl, lower alkylidene carboxy wherein the alkylidene moiety has from 1-4 carbon atoms and n is a whole number of from 1 to 20 with the proviso that no compound has more than six hydroxy groups.
Claim 13
Dependent Claim
176 words
A flame retardant thermoplastic molding composition which comprises: a. from 10-90 parts by weight of a polyphenylene ether resin; b. from 90-10 parts by weight of a rubber modified high-impact polystyrene resin; c. from 10 to 30 parts by weight of an aromatic halogenated flame retardant compound; and d. from 0.1 to 2.5 parts by weight of an organic iron compound in which the organic component is derived from a group of the formula: ##STR12## wherein R 1 is selected from the group consisting of hydrogen, hydroxyl and lower alkylene carboxy wherein the alkylene moiety has from 1-4 carbon atoms; R 2 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms and hydroxyl; R 3 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms, hydroxyl, lower alkylene carboxy, aryl, aralkyl, alkaryl, lower alkylidene carboxy wherein the alkylidene moiety has from 1-4 carbon atoms and n is a whole number of from 1 to 20 with the proviso that no compound has more than six hydroxy groups.
Claim 14
Dependent Claim
23 words
A composition as defined in claim 11 wherein said polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether and said aromatic halogenated flame retardant is monochloropolystyrene.
Claim 15
Dependent Claim
68 words
A composition as defined in claim 11 wherein said polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether and said aromatic halogenated flame retardant is bromo containing polycarbonate that is an aromatic carbonate copolymer in which from 25 to 75 wt. percent of the repeating units comprise and are derived from bromo substituted dihydric phenol units and the remainder of the repeating units comprise and are derived from dihydric phenol units.
Claim 16
Dependent Claim
47 words
A composition as defined in claim 11 wherein said polyphenylene ether resin is poly(2,6-dimethyl-1,4-phenylene) ether and said aromatic halogenated flame retardant is a bromo containing polycarbonate that is an aromatic carbonate homopolymer in which the repeating units comprise and are derived from bromo substituted dihydric phenol units.
Claim 17
Dependent Claim
15 words
A composition as defined in claim 11 wherein the organic iron compound is ferric acetate.
Claim 18
Dependent Claim
15 words
A composition as defined in claim 11 wherein the organic iron compound is ferric stearate.
Claim 19
Dependent Claim
15 words
A composition as defined in claim 11 wherein the organic iron compound is ferric citrate.
Claim 20
Dependent Claim
15 words
A composition as defined in claim 11 wherein the organic iron compound is ferrous gluconate.
Claim 21
Dependent Claim
90 words
A flame retardant thermoplastic molding composition which comprises: a. from 10-90 parts by weight of poly(2,6-dimethyl-1,4-phenylene)ether. b. from 10-90 parts by weight of a rubber modified high impact polystyrene resin; c. from 10-30 parts by weight of an aromatic halogenated flame retardant agent; d. from 0.1 to 2.5 parts by weight of an organic iron compound selected from the group consisting of the iron salts of alkanoic acids having from 2-20 carbon atoms, the iron salts of hydroxy substituted alkanoic acids and the iron salts of hydroxy substituted tricarboxylic acids.
Claim 22
Dependent Claim
90 words
A flame retardant thermoplastic molding composition which comprises: a. from 10-90 parts by weight of poly(2,6-dimethyl-1,4-phenylene)ether. b. from 10-90 parts by weight of a rubber modified high impact polystyrene resin; c. from 10-30 parts by weight of an aromatic halogenated flame retardant agent; d. from 0.1 to 2.5 parts by weight of an organic iron compound selected from the group consisting of the iron salts of alkanoic acids having from 2-20 carbon atoms, the iron salts of hydroxy substituted alkanoic acids and the iron salts of hydroxy substituted tricarboxylic acids.
Claim 23
Dependent Claim
15 words
A composition as defined in claim 19 wherein the organic iron compound is ferric acetate.
Claim 24
Dependent Claim
15 words
A composition as defined in claim 19 wherein the organic iron compound is ferric stearate.
Claim 25
Dependent Claim
15 words
A composition as defined in claim 19 wherein the organic iron compound is ferrous gulconate.
Claim 26
Dependent Claim
15 words
A composition as defined in claim 19 wherein the organic iron compound is ferric citrate.
Claim 27
Dependent Claim
159 words
A flame retardant thermoplastic molding composition which consists essentially of: a. a polyphenylene ether resin; b. a vinyl aromatic resin; c. a flame retardant amount of an aromatic brominated flame retardant; and d. a flame retardant amount of an organic iron compound in which the organic group is derived from a compound of the formula: ##STR13## wherein R 1 is selected from the group consisting of hydrogen, hydroxyl and lower alkylene carboxy wherein the alkylene moiety has from 1-4 carbon atoms; R 2 is selected from the group consisting of hydrogen, hydroxyl and lower alkyl of 1-4 carbon atoms; R 3 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms, hydroxyl, lower alkylene carboxy, aryl, aralkyl, alkaryl, lower alkylidene carboxy wherein the alkylidene moiety has from 1 to 4 carbon atoms and n is a whole number of from 1 to 20 with the proviso that no compound has more than six hydroxy groups.
Claim 28
Dependent Claim
159 words
A flame retardant thermoplastic molding composition which consists essentially of: a. a polyphenylene ether resin; b. a vinyl aromatic resin; c. a flame retardant amount of an aromatic brominated flame retardant; and d. a flame retardant amount of an organic iron compound in which the organic group is derived from a compound of the formula: ##STR13## wherein R 1 is selected from the group consisting of hydrogen, hydroxyl and lower alkylene carboxy wherein the alkylene moiety has from 1-4 carbon atoms; R 2 is selected from the group consisting of hydrogen, hydroxyl and lower alkyl of 1-4 carbon atoms; R 3 is selected from the group consisting of hydrogen, lower alkyl of 1-4 carbon atoms, hydroxyl, lower alkylene carboxy, aryl, aralkyl, alkaryl, lower alkylidene carboxy wherein the alkylidene moiety has from 1 to 4 carbon atoms and n is a whole number of from 1 to 20 with the proviso that no compound has more than six hydroxy groups.
Claim 29
Dependent Claim
19 words
A composition as defined in claim 1 wherein the aromatic halogenated flame retardant is a thermally stable bromine compound.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-16 | 1980-11-15 | 1981-05-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-16 | 1984-11-15 | 1985-05-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-16 | 1988-11-15 | 1989-05-17 | $7700.00 | Window Closed / Lapsed |