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Freeze-thaw stable, self-inverting, water-in-oil emulsion

Assignee: Wyeth Holdings LLC
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Filing: 1975-10-24
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Granted: 1977-05-10
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Expires: 1995-10-24
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Abstract

Abstract A freeze-thaw stable, self-inverting, water-in-oil emulsion comprising an aqueous phase of a polymer of acrylamide, a hydrocarbon oil, a water-in-oil emulsifying agent and an inverting surfactant mixture comprising sodium bis(2-ethylhexyl)sulfosuccinate and a sodium bis(C 11 -C 15 alkyl)sulfosuccinate or an ethoxylated octyl or nonyl phenol and a method for the preparation thereof.

Inventors

  • 👤 Joseph Michael Schmitt

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 21:43
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/09; C08F; C08F220/00; C08F220/02; C08F220/52; C08F220/54; C08F220/56; C08K; C08K5/00; C08K5/01; C08K5/36; C08K5/41; C08K5/42; C09; C09K; C09K23/00; C09K23/02; C08J2333/00; C08J2333/24; C08J2333/26

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 306 words
A freeze-thaw stable, self-inverting, non-creaming water-in-oil emulsion containing a dispersion therein of finely-divided polymer particles, said emulsion comprising: A. an aqueous phase ranging from about 70% to about 95%, by weight, based on the total weight of A and B, which is comprised of: 1. a water-soluble acrylamide polymer containing from about 0% to about 35%, by weight of the polymer, of a copolymerizable monomer of an acrylic acid or (methacrylamidopropyl)trimethylammonium chloride, the acrylic acid in said polymer, if any, being from about 50% to about 100% neutralized, and having a concentration from about 27% to about 68%, by weight, based on the total weight of A, and 2. water in an amount ranging from about 32% to about 73%, by weight, based on the total weight of A, B. a liquid hydrocarbon oil in an amount ranging from about 5% to about 30%, by weight, based on the total weight of A and B, C. a water-in-oil emulsifying agent disposed between said aqueous phase and said liquid hydrocarbon at a concentration of about 0.1% to about 15.0%, by weight, based on the total weight of A, B and C and D. an inverting surfactant mixture comprising sodium bis(2-ethylhexyl) sulfosuccinate and a sodium bis(C 11 -C 15 alkyl) sulfosuccinate or an ethoxylated octyl or nonyl phenol, the amount of said sodium bis(2-ethylhexyl) sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said polymer is cationic, and from about 2.8% to about 7.0%, by weight, when said polymer is anionic or non-ionic, the amount of said sodium bis(C 11 -C 15 alkyl) sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated octyl or nonyl phenol ranging from about 1.5% to about 2.5%, by weight, said weight being based on the total weight of A, B, C and D.
Claim 2
Dependent Claim 306 words
A freeze-thaw stable, self-inverting, non-creaming water-in-oil emulsion containing a dispersion therein of finely-divided polymer particles, said emulsion comprising: A. an aqueous phase ranging from about 70% to about 95%, by weight, based on the total weight of A and B, which is comprised of: 1. a water-soluble acrylamide polymer containing from about 0% to about 35%, by weight of the polymer, of a copolymerizable monomer of an acrylic acid or (methacrylamidopropyl)trimethylammonium chloride, the acrylic acid in said polymer, if any, being from about 50% to about 100% neutralized, and having a concentration from about 27% to about 68%, by weight, based on the total weight of A, and 2. water in an amount ranging from about 32% to about 73%, by weight, based on the total weight of A, B. a liquid hydrocarbon oil in an amount ranging from about 5% to about 30%, by weight, based on the total weight of A and B, C. a water-in-oil emulsifying agent disposed between said aqueous phase and said liquid hydrocarbon at a concentration of about 0.1% to about 15.0%, by weight, based on the total weight of A, B and C and D. an inverting surfactant mixture comprising sodium bis(2-ethylhexyl) sulfosuccinate and a sodium bis(C 11 -C 15 alkyl) sulfosuccinate or an ethoxylated octyl or nonyl phenol, the amount of said sodium bis(2-ethylhexyl) sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said polymer is cationic, and from about 2.8% to about 7.0%, by weight, when said polymer is anionic or non-ionic, the amount of said sodium bis(C 11 -C 15 alkyl) sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated octyl or nonyl phenol ranging from about 1.5% to about 2.5%, by weight, said weight being based on the total weight of A, B, C and D.
Claim 3
Dependent Claim 18 words
An emulsion according to claim 1 wherein said polymer comprises about 70% acrylamide and about 30% acrylic acid.
Claim 4
Dependent Claim 18 words
An emulsion according to claim 1 wherein said polymer comprises about 75% acrylamide and about 25% (methacrylamidopropyl)trimethylammonium chloride.
Claim 5
Dependent Claim 18 words
An emulsion according to claim 1 wherein said polymer comprises about 97% acrylamide and about 3% acrylic acid.
Claim 6
Dependent Claim 11 words
An emulsion according to claim 1 wherein said polymer is polyacrylamide.
Claim 7
Dependent Claim 17 words
An emulsion according to claim 1 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and sodium bis(tridecyl)sulfosuccinate.
Claim 8
Dependent Claim 33 words
An emulsion according to claim 1 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl) sulfosuccinate and the reaction product of about one mole of nonyl phenol with about 6 moles of ethylene oxide.
Claim 9
Dependent Claim 32 words
An emulsion according to claim 1 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and the reaction product of about one mole of ocyl phenol with about 7.5 moles of ethylene oxide.
Claim 10
Dependent Claim 181 words
A method of preparing the freeze-thaw stable emulsion of claim 1 which comprises: A. forming a water-in-oil emulsion of 1. from about 70% to about 95%, by weight, based on the total weight of 1 and 2, of a solution of a. a mixture of acrylamide and from about 0% to about 35%, by weight, based on the total weight of the mixture, of a copolymerizable monomer of an acrylic acid or (methacrylamidopropyl)trimethylammonium chloride, the acrylic acid, if any, being from about 50.75% neutralized, having a concentration from about 27% and about 68%, by weight, based on the total weight of a and b, and b. water, in an amount ranging from about 32%, to about 73%, by weight, based on the total weight of a and b, 2. a liquid hydrocarbon oil in an amount ranging from about 5% to about 30%, by weight, based on the total weight of 1 and 2, 3. a water-in-oil emulsifying agent in a concentration of about 0.1% to about 15.0%, by weight, based on the total weight of 1, 2 and 3, and
Claim 11
Dependent Claim 156 words
a free radical initiator comprising sodium metabisulfite and a hydroperoxide, B. polymerizing said monomers under free-radical polymerizing conditions to form a water-in-oil emulsion which contains dispersed therein finely divided particles of a polymer of said acrylamide, and C. adding to said oil-in-water emulsion an inverting surfactant mixture comprising sodium bis(2-ethylhexyl)sulfosuccinate and a sodium bis(C 11 -C 15 alkyl)sulfosuccinate or an ethoxylated nonyl or octyl phenol, the amount of said sodium bis(2-ethylhexyl)sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said comonomer is cationic, and from about 2.8% to about 7.0%, by weight, when said comonomer is anionic or non-ionic or is absent, the amount of said sodium bis(C 11-C 15 alkyl)sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated nonyl or octyl phenyl ranging from about 1.5% to about 2.5%, by weight, said weights being based on the total weight of said 1, 2, 3 and C.
Claim 12
Dependent Claim 156 words
a free radical initiator comprising sodium metabisulfite and a hydroperoxide, B. polymerizing said monomers under free-radical polymerizing conditions to form a water-in-oil emulsion which contains dispersed therein finely divided particles of a polymer of said acrylamide, and C. adding to said oil-in-water emulsion an inverting surfactant mixture comprising sodium bis(2-ethylhexyl)sulfosuccinate and a sodium bis(C 11 -C 15 alkyl)sulfosuccinate or an ethoxylated nonyl or octyl phenol, the amount of said sodium bis(2-ethylhexyl)sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said comonomer is cationic, and from about 2.8% to about 7.0%, by weight, when said comonomer is anionic or non-ionic or is absent, the amount of said sodium bis(C 11-C 15 alkyl)sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated nonyl or octyl phenyl ranging from about 1.5% to about 2.5%, by weight, said weights being based on the total weight of said 1, 2, 3 and C.
Claim 13
Dependent Claim 21 words
A method according to claim 9 wherein said monomer mixture comprises about 70% acrylamide and about 30% of an acrylic acid.
Claim 14
Dependent Claim 20 words
A method according to claim 9 wherein said monomer mixture comprises about 75% acrylamide and about 25% of (methacrylamidopropyl)trimethylammonium chloride.
Claim 15
Dependent Claim 19 words
A method according to claim 9 wherein said monomer mixture comprises about 97% acrylamide and about 3% acrylic acid.
Claim 16
Dependent Claim 11 words
A method according to claim 9 wherein said monomer comprises acrylamide.
Claim 17
Dependent Claim 17 words
A method according to claim 9 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and sodium bis(tridecyl)sulfosuccinate.
Claim 18
Dependent Claim 32 words
A method according to claim 9 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and the reaction product of about one mole of nonyl phenol and about 6 moles of ethylene oxide.
Claim 19
Dependent Claim 32 words
A method according to claim 9 wherein said inverting surfactant mixture comrpises sodium bis(2-ethylhexyl)sulfosuccinate and the reaction product of about one mole of octyl phenol and about 7.5 moles of ethylene oxide.

References Cited (Backward Citations)

US3284393A Cited
US3624019A Cited
US3852234A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-09 1980-11-08 1981-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-09 1984-11-08 1985-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-09 1988-11-08 1989-05-10 $7700.00 Window Closed / Lapsed

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