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US4022731A
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Freeze-thaw stable, self-inverting, water-in-oil emulsion
Assignee: Wyeth Holdings LLC
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Filing: 1975-10-24
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Granted: 1977-05-10
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Expires: 1995-10-24
Abstract
Abstract A freeze-thaw stable, self-inverting, water-in-oil emulsion comprising an aqueous phase of a polymer of acrylamide, a hydrocarbon oil, a water-in-oil emulsifying agent and an inverting surfactant mixture comprising sodium bis(2-ethylhexyl)sulfosuccinate and a sodium bis(C 11 -C 15 alkyl)sulfosuccinate or an ethoxylated octyl or nonyl phenol and a method for the preparation thereof.
Inventors
- 👤 Joseph Michael Schmitt
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 21:43
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/09; C08F; C08F220/00; C08F220/02; C08F220/52; C08F220/54; C08F220/56; C08K; C08K5/00; C08K5/01; C08K5/36; C08K5/41; C08K5/42; C09; C09K; C09K23/00; C09K23/02; C08J2333/00; C08J2333/24; C08J2333/26
Claims Analysis
Total Claims: 19
Claim 1
Independent Claim
306 words
A freeze-thaw stable, self-inverting, non-creaming water-in-oil emulsion containing a dispersion therein of finely-divided polymer particles, said emulsion comprising: A. an aqueous phase ranging from about 70% to about 95%, by weight, based on the total weight of A and B, which is comprised of: 1. a water-soluble acrylamide polymer containing from about 0% to about 35%, by weight of the polymer, of a copolymerizable monomer of an acrylic acid or (methacrylamidopropyl)trimethylammonium chloride, the acrylic acid in said polymer, if any, being from about 50% to about 100% neutralized, and having a concentration from about 27% to about 68%, by weight, based on the total weight of A, and 2. water in an amount ranging from about 32% to about 73%, by weight, based on the total weight of A, B. a liquid hydrocarbon oil in an amount ranging from about 5% to about 30%, by weight, based on the total weight of A and B, C. a water-in-oil emulsifying agent disposed between said aqueous phase and said liquid hydrocarbon at a concentration of about 0.1% to about 15.0%, by weight, based on the total weight of A, B and C and D. an inverting surfactant mixture comprising sodium bis(2-ethylhexyl) sulfosuccinate and a sodium bis(C 11 -C 15 alkyl) sulfosuccinate or an ethoxylated octyl or nonyl phenol, the amount of said sodium bis(2-ethylhexyl) sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said polymer is cationic, and from about 2.8% to about 7.0%, by weight, when said polymer is anionic or non-ionic, the amount of said sodium bis(C 11 -C 15 alkyl) sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated octyl or nonyl phenol ranging from about 1.5% to about 2.5%, by weight, said weight being based on the total weight of A, B, C and D.
Claim 2
Dependent Claim
306 words
A freeze-thaw stable, self-inverting, non-creaming water-in-oil emulsion containing a dispersion therein of finely-divided polymer particles, said emulsion comprising: A. an aqueous phase ranging from about 70% to about 95%, by weight, based on the total weight of A and B, which is comprised of: 1. a water-soluble acrylamide polymer containing from about 0% to about 35%, by weight of the polymer, of a copolymerizable monomer of an acrylic acid or (methacrylamidopropyl)trimethylammonium chloride, the acrylic acid in said polymer, if any, being from about 50% to about 100% neutralized, and having a concentration from about 27% to about 68%, by weight, based on the total weight of A, and 2. water in an amount ranging from about 32% to about 73%, by weight, based on the total weight of A, B. a liquid hydrocarbon oil in an amount ranging from about 5% to about 30%, by weight, based on the total weight of A and B, C. a water-in-oil emulsifying agent disposed between said aqueous phase and said liquid hydrocarbon at a concentration of about 0.1% to about 15.0%, by weight, based on the total weight of A, B and C and D. an inverting surfactant mixture comprising sodium bis(2-ethylhexyl) sulfosuccinate and a sodium bis(C 11 -C 15 alkyl) sulfosuccinate or an ethoxylated octyl or nonyl phenol, the amount of said sodium bis(2-ethylhexyl) sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said polymer is cationic, and from about 2.8% to about 7.0%, by weight, when said polymer is anionic or non-ionic, the amount of said sodium bis(C 11 -C 15 alkyl) sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated octyl or nonyl phenol ranging from about 1.5% to about 2.5%, by weight, said weight being based on the total weight of A, B, C and D.
Claim 3
Dependent Claim
18 words
An emulsion according to claim 1 wherein said polymer comprises about 70% acrylamide and about 30% acrylic acid.
Claim 4
Dependent Claim
18 words
An emulsion according to claim 1 wherein said polymer comprises about 75% acrylamide and about 25% (methacrylamidopropyl)trimethylammonium chloride.
Claim 5
Dependent Claim
18 words
An emulsion according to claim 1 wherein said polymer comprises about 97% acrylamide and about 3% acrylic acid.
Claim 6
Dependent Claim
11 words
An emulsion according to claim 1 wherein said polymer is polyacrylamide.
Claim 7
Dependent Claim
17 words
An emulsion according to claim 1 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and sodium bis(tridecyl)sulfosuccinate.
Claim 8
Dependent Claim
33 words
An emulsion according to claim 1 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl) sulfosuccinate and the reaction product of about one mole of nonyl phenol with about 6 moles of ethylene oxide.
Claim 9
Dependent Claim
32 words
An emulsion according to claim 1 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and the reaction product of about one mole of ocyl phenol with about 7.5 moles of ethylene oxide.
Claim 10
Dependent Claim
181 words
A method of preparing the freeze-thaw stable emulsion of claim 1 which comprises: A. forming a water-in-oil emulsion of 1. from about 70% to about 95%, by weight, based on the total weight of 1 and 2, of a solution of a. a mixture of acrylamide and from about 0% to about 35%, by weight, based on the total weight of the mixture, of a copolymerizable monomer of an acrylic acid or (methacrylamidopropyl)trimethylammonium chloride, the acrylic acid, if any, being from about 50.75% neutralized, having a concentration from about 27% and about 68%, by weight, based on the total weight of a and b, and b. water, in an amount ranging from about 32%, to about 73%, by weight, based on the total weight of a and b, 2. a liquid hydrocarbon oil in an amount ranging from about 5% to about 30%, by weight, based on the total weight of 1 and 2, 3. a water-in-oil emulsifying agent in a concentration of about 0.1% to about 15.0%, by weight, based on the total weight of 1, 2 and 3, and
Claim 11
Dependent Claim
156 words
a free radical initiator comprising sodium metabisulfite and a hydroperoxide, B. polymerizing said monomers under free-radical polymerizing conditions to form a water-in-oil emulsion which contains dispersed therein finely divided particles of a polymer of said acrylamide, and C. adding to said oil-in-water emulsion an inverting surfactant mixture comprising sodium bis(2-ethylhexyl)sulfosuccinate and a sodium bis(C 11 -C 15 alkyl)sulfosuccinate or an ethoxylated nonyl or octyl phenol, the amount of said sodium bis(2-ethylhexyl)sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said comonomer is cationic, and from about 2.8% to about 7.0%, by weight, when said comonomer is anionic or non-ionic or is absent, the amount of said sodium bis(C 11-C 15 alkyl)sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated nonyl or octyl phenyl ranging from about 1.5% to about 2.5%, by weight, said weights being based on the total weight of said 1, 2, 3 and C.
Claim 12
Dependent Claim
156 words
a free radical initiator comprising sodium metabisulfite and a hydroperoxide, B. polymerizing said monomers under free-radical polymerizing conditions to form a water-in-oil emulsion which contains dispersed therein finely divided particles of a polymer of said acrylamide, and C. adding to said oil-in-water emulsion an inverting surfactant mixture comprising sodium bis(2-ethylhexyl)sulfosuccinate and a sodium bis(C 11 -C 15 alkyl)sulfosuccinate or an ethoxylated nonyl or octyl phenol, the amount of said sodium bis(2-ethylhexyl)sulfosuccinate ranging from about 0.25% to about 1.5%, by weight, when said comonomer is cationic, and from about 2.8% to about 7.0%, by weight, when said comonomer is anionic or non-ionic or is absent, the amount of said sodium bis(C 11-C 15 alkyl)sulfosuccinate ranging from about 0.2% to about 0.6%, by weight, and the amount of said ethoxylated nonyl or octyl phenyl ranging from about 1.5% to about 2.5%, by weight, said weights being based on the total weight of said 1, 2, 3 and C.
Claim 13
Dependent Claim
21 words
A method according to claim 9 wherein said monomer mixture comprises about 70% acrylamide and about 30% of an acrylic acid.
Claim 14
Dependent Claim
20 words
A method according to claim 9 wherein said monomer mixture comprises about 75% acrylamide and about 25% of (methacrylamidopropyl)trimethylammonium chloride.
Claim 15
Dependent Claim
19 words
A method according to claim 9 wherein said monomer mixture comprises about 97% acrylamide and about 3% acrylic acid.
Claim 16
Dependent Claim
11 words
A method according to claim 9 wherein said monomer comprises acrylamide.
Claim 17
Dependent Claim
17 words
A method according to claim 9 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and sodium bis(tridecyl)sulfosuccinate.
Claim 18
Dependent Claim
32 words
A method according to claim 9 wherein said inverting surfactant mixture comprises sodium bis(2-ethylhexyl)sulfosuccinate and the reaction product of about one mole of nonyl phenol and about 6 moles of ethylene oxide.
Claim 19
Dependent Claim
32 words
A method according to claim 9 wherein said inverting surfactant mixture comrpises sodium bis(2-ethylhexyl)sulfosuccinate and the reaction product of about one mole of octyl phenol and about 7.5 moles of ethylene oxide.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-09 | 1980-11-08 | 1981-05-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-09 | 1984-11-08 | 1985-05-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-09 | 1988-11-08 | 1989-05-10 | $7700.00 | Window Closed / Lapsed |