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US4022718A Expired / Lapsed US ⏱️ 0.0 years remaining

High resilience fire retardant urethane foam

Assignee: ISP Investments LLC
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Filing: 1974-03-06
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Granted: 1977-05-10
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Expires: 1994-03-06
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Abstract

Abstract High resilience cold cured polyether urethane foam incorporating 2,3-dibromo-2-butenediol-1,4, as a chain extender and fire retardant component.

Inventors

  • 👤 Robert Victor Russo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 04:09
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/675; C08G18/677; C08G18/6775; Y; Y10; Y10S; Y10S521/00; Y10S521/904

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 125 words
In the process of producing a cold cured, stable, fire retardant, high resilience polyether urethane foam having a sag factor of at least 2.2 by reaction of an unhalogenated polyether polyol and, as an organic isocyanate reactant, tolylene diisocyanate or polymethylene polyphenyl polyisocyanate of the formula: ##STR2## wherein n is an integer predominantly of from 0 to 1 inclusive, or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate, in the presence of a blowing agent and catalyst; the improvement that comprises incorporating therein as a chain-extending agent and additional reactant, 2,3-dibromo-2-butenediol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of reactant isocyanate.
Claim 2
Dependent Claim 125 words
In the process of producing a cold cured, stable, fire retardant, high resilience polyether urethane foam having a sag factor of at least 2.2 by reaction of an unhalogenated polyether polyol and, as an organic isocyanate reactant, tolylene diisocyanate or polymethylene polyphenyl polyisocyanate of the formula: ##STR2## wherein n is an integer predominantly of from 0 to 1 inclusive, or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate, in the presence of a blowing agent and catalyst; the improvement that comprises incorporating therein as a chain-extending agent and additional reactant, 2,3-dibromo-2-butenediol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of reactant isocyanate.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein said organic polyisocyanate component is a mixture of polymethylene polyphenyl polyisocyanate and tolylene diisocyanate.
Claim 4
Dependent Claim 31 words
The process of claim 2 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 5
Dependent Claim 31 words
The process of claim 3 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1.5 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 6
Dependent Claim 10 words
The process of claim 3 wherein said polyisocyanate is undistilled.
Claim 7
Dependent Claim 38 words
The process of claim 3 wherein said polyisocyanate is a mixture comprising in excess of 50 percent by weight of trimer, in excess of 40 percent by weight of dimer and less than 5 percent of higher polymers.
Claim 8
Dependent Claim 11 words
The process of claim 3 wherein said tolylene diisocyanate is undistilled.
Claim 9
Dependent Claim 40 words
The process of claim 3 wherein said 2,3-dibromo-2-butenediol-1,4 is incorporated in the production of said foam in an amount sufficient to provide a bromine content in said foam of from at least about 1.5 percent by weight of said foam.
Claim 10
Dependent Claim 26 words
The process of claim 8 wherein the bromine content of said foam is within the range of about 1.5 percent to about 22 percent by weight.
Claim 11
Dependent Claim 27 words
The process of claim 9 wherein the bromine content provided is within the range of about 10 percent to about 18 percent by weight of said foam.
Claim 12
Dependent Claim 119 words
A cold cured, high resilience fire-retardant polyether urethane foam having a sag factor of at least 2.2 and a bromine content of at least 1.5 percent by weight prepared by reacting an unhalogenated polyol; as an organic isocyanate reactant, tolylene diisocyanate or a polymethylene polyphenyl polyisocyanate of the formula: ##STR3## wherein n is an integer predominantly of 0 to 1 inclusive; or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate; and as a chain-extending agent, 2,3-dibromo-2-butene-diol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent, in the presence of a blowing agent and catalyst; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of isocyanate reactant.
Claim 13
Dependent Claim 119 words
A cold cured, high resilience fire-retardant polyether urethane foam having a sag factor of at least 2.2 and a bromine content of at least 1.5 percent by weight prepared by reacting an unhalogenated polyol; as an organic isocyanate reactant, tolylene diisocyanate or a polymethylene polyphenyl polyisocyanate of the formula: ##STR3## wherein n is an integer predominantly of 0 to 1 inclusive; or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate; and as a chain-extending agent, 2,3-dibromo-2-butene-diol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent, in the presence of a blowing agent and catalyst; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of isocyanate reactant.
Claim 14
Dependent Claim 17 words
A high resilience polyether urethane foam as claimed in claim 11 wherein said polyisocyanate is 4,4'-diphenylmethane diisocyanate.
Claim 15
Dependent Claim 25 words
A high resilience polyether urethane foam as claimed in claim 11 wherein said aromatic diisocyanate is an undistilled mixture of 2,4-tolylene diisocyanate and 2,6-tolylene diisocyanate.
Claim 16
Dependent Claim 17 words
A high resilience polyether urethane foam as claimed in claim 12 wherein said 4,4'-di-phenylmethane diisocyanate is undistilled.
Claim 17
Dependent Claim 27 words
A high resilience polyether urethane foam as claimed in claim 11 wherein said polyisocyanate is a mixture of undistilled 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate and undistilled 4,4'-diphenylmethane diisocyanate.
Claim 18
Dependent Claim 21 words
The high resilience polyether urethane foam as claimed in claim 11 hereof wherein said polyether polyol is a linear polyether triol.
Claim 19
Dependent Claim 26 words
A high resilience polyether urethane foam as claimed in claim 16 wherein said polyether is a poly (oxypropylene)triol having a molecular weight of at least 4000.
Claim 20
Dependent Claim 26 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 11 wherein said isocyanate reactant is a mixture of polymethylene polyphenyl polyisocyanate and tolylene diisocyanate.
Claim 21
Dependent Claim 38 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 18 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 22
Dependent Claim 38 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1.5 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 23
Dependent Claim 38 words
A high resilience polyether urethane foam as claimed in claim 19 having a sag factor of from about 2.4 to 3.1 wherein the bromine content of said foam is from about 1.5 percent to 10 percent by weight.
Claim 24
Dependent Claim 19 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said polyisocyanate is an undistilled mixture.
Claim 25
Dependent Claim 43 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said polyisocyanate mixture comprises in excess of 50 percent by weight of trimer, in excess of 40 percent by weight of dimer and less than 5 percent of higher polymers.
Claim 26
Dependent Claim 18 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said tolylene diisocyanate is undistilled.

References Cited (Backward Citations)

GB1305036A Cited
US3723392A Cited
US3803064A Cited
US3764546A Cited
US3812047A Cited
US3933690A Cited
US3779953A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-09 1980-11-08 1981-05-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-09 1984-11-08 1985-05-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-09 1988-11-08 1989-05-10 $7700.00 Window Closed / Lapsed

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