US4022718A
Expired / Lapsed
US
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High resilience fire retardant urethane foam
Assignee: ISP Investments LLC
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Filing: 1974-03-06
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Granted: 1977-05-10
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Expires: 1994-03-06
Abstract
Abstract High resilience cold cured polyether urethane foam incorporating 2,3-dibromo-2-butenediol-1,4, as a chain extender and fire retardant component.
Inventors
- 👤 Robert Victor Russo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 03:49
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/67; C08G18/675; C08G18/677; C08G18/6775; Y; Y10; Y10S; Y10S521/00; Y10S521/904
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
125 words
In the process of producing a cold cured, stable, fire retardant, high resilience polyether urethane foam having a sag factor of at least 2.2 by reaction of an unhalogenated polyether polyol and, as an organic isocyanate reactant, tolylene diisocyanate or polymethylene polyphenyl polyisocyanate of the formula: ##STR2## wherein n is an integer predominantly of from 0 to 1 inclusive, or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate, in the presence of a blowing agent and catalyst; the improvement that comprises incorporating therein as a chain-extending agent and additional reactant, 2,3-dibromo-2-butenediol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of reactant isocyanate.
Claim 2
Dependent Claim
125 words
In the process of producing a cold cured, stable, fire retardant, high resilience polyether urethane foam having a sag factor of at least 2.2 by reaction of an unhalogenated polyether polyol and, as an organic isocyanate reactant, tolylene diisocyanate or polymethylene polyphenyl polyisocyanate of the formula: ##STR2## wherein n is an integer predominantly of from 0 to 1 inclusive, or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate, in the presence of a blowing agent and catalyst; the improvement that comprises incorporating therein as a chain-extending agent and additional reactant, 2,3-dibromo-2-butenediol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of reactant isocyanate.
Claim 3
Dependent Claim
20 words
The process of claim 1 wherein said organic polyisocyanate component is a mixture of polymethylene polyphenyl polyisocyanate and tolylene diisocyanate.
Claim 4
Dependent Claim
31 words
The process of claim 2 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 5
Dependent Claim
31 words
The process of claim 3 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1.5 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 6
Dependent Claim
10 words
The process of claim 3 wherein said polyisocyanate is undistilled.
Claim 7
Dependent Claim
38 words
The process of claim 3 wherein said polyisocyanate is a mixture comprising in excess of 50 percent by weight of trimer, in excess of 40 percent by weight of dimer and less than 5 percent of higher polymers.
Claim 8
Dependent Claim
11 words
The process of claim 3 wherein said tolylene diisocyanate is undistilled.
Claim 9
Dependent Claim
40 words
The process of claim 3 wherein said 2,3-dibromo-2-butenediol-1,4 is incorporated in the production of said foam in an amount sufficient to provide a bromine content in said foam of from at least about 1.5 percent by weight of said foam.
Claim 10
Dependent Claim
26 words
The process of claim 8 wherein the bromine content of said foam is within the range of about 1.5 percent to about 22 percent by weight.
Claim 11
Dependent Claim
27 words
The process of claim 9 wherein the bromine content provided is within the range of about 10 percent to about 18 percent by weight of said foam.
Claim 12
Dependent Claim
119 words
A cold cured, high resilience fire-retardant polyether urethane foam having a sag factor of at least 2.2 and a bromine content of at least 1.5 percent by weight prepared by reacting an unhalogenated polyol; as an organic isocyanate reactant, tolylene diisocyanate or a polymethylene polyphenyl polyisocyanate of the formula: ##STR3## wherein n is an integer predominantly of 0 to 1 inclusive; or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate; and as a chain-extending agent, 2,3-dibromo-2-butene-diol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent, in the presence of a blowing agent and catalyst; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of isocyanate reactant.
Claim 13
Dependent Claim
119 words
A cold cured, high resilience fire-retardant polyether urethane foam having a sag factor of at least 2.2 and a bromine content of at least 1.5 percent by weight prepared by reacting an unhalogenated polyol; as an organic isocyanate reactant, tolylene diisocyanate or a polymethylene polyphenyl polyisocyanate of the formula: ##STR3## wherein n is an integer predominantly of 0 to 1 inclusive; or mixtures of said tolylene diisocyanate and said polymethylene polyphenyl polyisocyanate; and as a chain-extending agent, 2,3-dibromo-2-butene-diol-1,4 in an amount by weight of said unhalogenated polyol of 3 to 9 percent, in the presence of a blowing agent and catalyst; the resulting polyether urethane foam containing less than 5 percent of polymerized isocyanurate by weight of isocyanate reactant.
Claim 14
Dependent Claim
17 words
A high resilience polyether urethane foam as claimed in claim 11 wherein said polyisocyanate is 4,4'-diphenylmethane diisocyanate.
Claim 15
Dependent Claim
25 words
A high resilience polyether urethane foam as claimed in claim 11 wherein said aromatic diisocyanate is an undistilled mixture of 2,4-tolylene diisocyanate and 2,6-tolylene diisocyanate.
Claim 16
Dependent Claim
17 words
A high resilience polyether urethane foam as claimed in claim 12 wherein said 4,4'-di-phenylmethane diisocyanate is undistilled.
Claim 17
Dependent Claim
27 words
A high resilience polyether urethane foam as claimed in claim 11 wherein said polyisocyanate is a mixture of undistilled 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate and undistilled 4,4'-diphenylmethane diisocyanate.
Claim 18
Dependent Claim
21 words
The high resilience polyether urethane foam as claimed in claim 11 hereof wherein said polyether polyol is a linear polyether triol.
Claim 19
Dependent Claim
26 words
A high resilience polyether urethane foam as claimed in claim 16 wherein said polyether is a poly (oxypropylene)triol having a molecular weight of at least 4000.
Claim 20
Dependent Claim
26 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 11 wherein said isocyanate reactant is a mixture of polymethylene polyphenyl polyisocyanate and tolylene diisocyanate.
Claim 21
Dependent Claim
38 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 18 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 22
Dependent Claim
38 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said polymethylene polyphenyl polyisocyanate is present within a ratio by weight of 1.5 to 2 parts thereof to each 1 part of said tolylene diisocyanate.
Claim 23
Dependent Claim
38 words
A high resilience polyether urethane foam as claimed in claim 19 having a sag factor of from about 2.4 to 3.1 wherein the bromine content of said foam is from about 1.5 percent to 10 percent by weight.
Claim 24
Dependent Claim
19 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said polyisocyanate is an undistilled mixture.
Claim 25
Dependent Claim
43 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said polyisocyanate mixture comprises in excess of 50 percent by weight of trimer, in excess of 40 percent by weight of dimer and less than 5 percent of higher polymers.
Claim 26
Dependent Claim
18 words
A high resilience fire-retardant polyether urethane foam as claimed in claim 19 wherein said tolylene diisocyanate is undistilled.
References Cited (Backward Citations)
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US3803064A
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US3764546A
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-09 | 1980-11-08 | 1981-05-10 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-09 | 1984-11-08 | 1985-05-10 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-09 | 1988-11-08 | 1989-05-10 | $7700.00 | Window Closed / Lapsed |