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US4021505A Expired / Lapsed US ⏱️ 0.0 years remaining

Mar-resistant coating composition of reaction product of hydroxy-terminated urethane and melamine resin

Assignee: Wyeth Holdings LLC
•
Filing: 1975-03-20
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Granted: 1977-05-03
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Expires: 1995-03-20
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Abstract

Abstract Compositions of matter consisting of urethane prepolymers having terminal hydroxy groups and produced from a diol of a molecular weight of 200-3,000, an organic diisocyanate and a polyhydric alcohol having 2-6 hydroxyl groups which are admixed with alkylated melamine/formaldehyde materials in the presence of an acid catalyst, are disclosed.

Inventors

  • 👤 Samuel S. Wang

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 20:52
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/08; C08G18/10; C09; C09D; C09D175/00; C09D175/04; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/3154; Y10T428/31551; Y10T428/31855; Y10T428/31859; Y10T428/31862; Y10T428/31935; Y10T428/31938; Y10T428/31942

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 150 words
A coating composition consisting essentially of a mixture of (1), (2) and (3), in which the ratio of (1) to (2) ranges from about 5:1 to about 1:1, respectively, and (1) is a saturated urethane prepolymer having terminal hydroxy groups which is the reaction product of materials consisting essentially of a mixture of (a) and (b), at a molar ratio of 1:2, respectively, in which (a) is an isocyanate-terminated urethane which is the reaction product of a mixture consisting essentially of (I) and (II), at a molar ratio of 1:2, respectively, in which (I) is a saturated diol having a molecular weight of from about 200 to about 3000, and (II) is a saturated organic diisocyanate, and (b) is a monomeric, sterically bulky, polyhydric alcohol containing 2-6 hydroxyl groups and being free of oxyalkylene units, (2) is a polyalkyl ether of a polymethylol melamine, and (3) is an acid catalyst.
Claim 2
Dependent Claim 150 words
A coating composition consisting essentially of a mixture of (1), (2) and (3), in which the ratio of (1) to (2) ranges from about 5:1 to about 1:1, respectively, and (1) is a saturated urethane prepolymer having terminal hydroxy groups which is the reaction product of materials consisting essentially of a mixture of (a) and (b), at a molar ratio of 1:2, respectively, in which (a) is an isocyanate-terminated urethane which is the reaction product of a mixture consisting essentially of (I) and (II), at a molar ratio of 1:2, respectively, in which (I) is a saturated diol having a molecular weight of from about 200 to about 3000, and (II) is a saturated organic diisocyanate, and (b) is a monomeric, sterically bulky, polyhydric alcohol containing 2-6 hydroxyl groups and being free of oxyalkylene units, (2) is a polyalkyl ether of a polymethylol melamine, and (3) is an acid catalyst.
Claim 3
Dependent Claim 13 words
A composition according to claim 1 wherein said (I) is a polyalkyleneether glycol.
Claim 4
Dependent Claim 13 words
A composition according to claim 1 wherein said (II) is methylene bis(cyclohexane isocyanate).
Claim 5
Dependent Claim 12 words
A composition according to claim 1 wherein said (b) is 1,4-cyclohexane dimethanol.
Claim 6
Dependent Claim 14 words
A composition according to claim 1 wherein said (I) is a polytetramethylene ether glycol.
Claim 7
Dependent Claim 114 words
A process for the sequential production of the composition of claim 1 which consists of (1) first reacting (a) One molar portion of a saturated diol having a molecular weight of from about 200 to about 3,000 with (b) Two molar portions of a saturated organic diisocyanate to produce an isocyanate-terminated urethane, (2) then reacting (c) One molar portion of said urethane with (d) Two molar portions of a monomeric, sterically bulky, polyhydric alcohol containing 2 - 6 hydroxyl groups and being free of oxyalkylene groups to produce a saturated urethane prepolymer having terminal hydroxy groups and (3) mixing said prepolymer with (e) A polyalkylether of a polymethylol melamine and (f) An acid catalyst.
Claim 8
Dependent Claim 13 words
A method according to claim 6 wherein said (a) is a polyalkyleneether glycol.
Claim 9
Dependent Claim 13 words
A method according to claim 6 wherein said (b) is methylene bis(cyclohexane isocyanate).
Claim 10
Dependent Claim 12 words
A method according to claim 6 wherein said (c) is 1,4-cyclohexane dimethanol.
Claim 11
Dependent Claim 14 words
A method according to claim 6 wherein said (a) is a polytetramethylene ether glycol.

References Cited (Backward Citations)

US3384606A Cited
US3542718A Cited
US3626023A Cited
US3912790A Cited
US3804810A Cited
US3785861A Cited
US3759873A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-02 1980-11-01 1981-05-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-02 1984-11-01 1985-05-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-02 1988-11-01 1989-05-03 $7700.00 Window Closed / Lapsed

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