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US4021403A Expired / Lapsed US ⏱️ 0.0 years remaining

Flame resistant thermosetting resin composition and metal clad laminate composed of the thermosetting resin composition

Assignee: Maruzen Petrochemical Co Ltd
•
Filing: 1975-02-07
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Granted: 1977-05-03
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Expires: 1995-02-07
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Abstract

Abstract A thermosetting resin composition having excellent flame resistance and thermal stability comprising an epoxy resin and a halogenated polyhydroxstyrene and a metal clad laminate comprising at least one planar base material having impregnated therein the above-described flame resistant thermosetting resin composition and at least one metal foil laminated thereon.

Inventors

  • 👤 Hiroshi Fujiwara
  • 👤 Hiroshi Suzuki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 13:30
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/04; B32B15/12; C; C08; C08L; C08L25/00; C08L25/18; B32B13/00; B32B13/04; B32B13/06; B32B15/14; C08L63/00; B32B2260/00; B32B2260/02; B32B2260/021; B32B2260/028; B32B2260/04; B32B2260/046; B32B2262/00; B32B2262/10; B32B2262/101; B32B2307/00; B32B2307/30; B32B2307/306; B32B2307/3065; Y; Y10; Y10S; Y10S260/00; Y10S260/24; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31518; Y10T428/31522

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 85 words
A flame resistant thermosetting resin composition comprising an epoxy resin comprising an epoxy compound having at least two epoxy groups per molecule and a halogenated polyhydroxystyrene or a mixture of a halogenated polyhydroxystyrene and polyhydroxystyrene, wherein said halogenated polyhydroxystyrene has a mean degree of polymerization of from about 2 to 10,000 and the equivalent ratio of the number of hydroxyl groups in said halogenated polyhydroxystyrene and polyhydroxystyrene to the number of epoxy groups in said epoxy resin is in the range of 0.3 to 10.
Claim 2
Dependent Claim 85 words
A flame resistant thermosetting resin composition comprising an epoxy resin comprising an epoxy compound having at least two epoxy groups per molecule and a halogenated polyhydroxystyrene or a mixture of a halogenated polyhydroxystyrene and polyhydroxystyrene, wherein said halogenated polyhydroxystyrene has a mean degree of polymerization of from about 2 to 10,000 and the equivalent ratio of the number of hydroxyl groups in said halogenated polyhydroxystyrene and polyhydroxystyrene to the number of epoxy groups in said epoxy resin is in the range of 0.3 to 10.
Claim 3
Dependent Claim 26 words
The flame resistant thermosetting resin composition as claimed in claim 1, wherein said halogenated polyhydroxystyrene has a halogen content of about 15 to 70% by weight.
Claim 4
Dependent Claim 19 words
The flame resistant thermosetting resin composition as claimed in claim 1, wherein said halogenated polyhydroxystyrene is a brominated polyhydroxystyrene.
Claim 5
Dependent Claim 78 words
The flame resistant thermosetting resin composition as claimed in claim l, wherein said epoxy resin is a bisphenol type epoxy resin, a novolac type epoxy resin, a resole type epoxy resin, a polyphenol type epoxy resin, a polyhydroxybenzene type epoxy resin, a polyglycol type epoxy resin, an aromatic carboxylic acid type epoxy resin, an aliphatic carboxylic acid type epoxy resin, an alicyclic epoxy resin, a nitrogen-containing epoxy resin, a diene type epoxy resin, or a metal-containing epoxy resin.
Claim 6
Dependent Claim 19 words
The flame resistant thermosetting resin composition as claimed in claim 1, wherein said composition further contains a hardening accelerator.
Claim 7
Dependent Claim 24 words
The flame resistant thermosetting resin composition as claimed in claim 5, wherein said hardening accelerator is dimethylaminobenzaldehyde, dimethylbenzylamine, triethanolamine, diethylenetriamine, urea, dicyandiamide, or dimethylformamide.
Claim 8
Dependent Claim 19 words
The flame resistant thermosetting resin composition as claimed in claim 1, wherein said ratio is equivalent 0.5 to 5.
Claim 9
Dependent Claim 35 words
The flame resistant thermosetting resin composition as claimed in claim 1, further comprising a plasticizer in an amount of from 0.5 to 20 weight % based on the weight of the resin in the composition.
Claim 10
Dependent Claim 31 words
The flame resistant thermosetting resin composition as claimed in claim 1, further comprising a reinforcing agent in an amount of from 20 to 900 parts per hundred of the resin composition.
Claim 11
Dependent Claim 29 words
The flame resistant thermosetting resin composition as claimed in claim 1, further comprising a filler in an amount of less than 900 parts per hundred of the resin composition.
Claim 12
Dependent Claim 26 words
The flame resistant thermosetting resin composition as claimed in claim 1, further comprising a hardening accelerator selected from the group consisting of tertiary amines or polyamines.
Claim 13
Dependent Claim 29 words
The flame resistant thermosetting resin composition as claimed in claim 1, wherein said halogenated polyhydroxystyrene is a brominated polyhydroxystyrene having a halogen content of 30 to 60% by weight.
Claim 14
Dependent Claim 35 words
The flame resistant thermosetting resin composition as claimed in claim 1, wherein said halogenated polyhydroxystyrene is a brominated polyhydroxystyrene in which less than about 30 mole percent of the bromine has been replaced by chlorine.
Claim 15
Dependent Claim 22 words
The flame resistant thermosetting resin composition as claimed in claim 1, wherein said mean degree of polymerization is from 10 to 150.

References Cited (Backward Citations)

US3050476A Cited
US3884992A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-02 1980-11-01 1981-05-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-02 1984-11-01 1985-05-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-02 1988-11-01 1989-05-03 $7700.00 Window Closed / Lapsed

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