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US4020248A Expired / Lapsed US ⏱️ 0.0 years remaining

Primary electrochemical cell capable of high discharge rates

Assignee: Verizon Laboratories Inc
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Filing: 1975-09-18
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Granted: 1977-04-26
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Expires: 1995-09-18
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Abstract

Abstract A primary electrochemical cell is described which is capable of achieving high discharge currents. The primary electrochemical cell incorporates a novel cathode structure. That cathode structure has a cathode current collector which is comprised with a plurality of electrically interconnected layers of a porous metallic material such as a nickel screen. Interposed between the layers of the cathode current collector are layers of globules of a cathode material. This material has a composition of from about 40 to 99 weight percent of carbon black, at least 1 weight percent of a mechanical binder which is inert in the primary electrochemical cell and the remainder is graphite. When such a cathode structure is incorporated into a primary electrochemical cell, two features are obtained which contribute to the high discharge current capability of the cell. Firstly, because a multitude of globules of cathode material are utilized in the cathode structure along with a porous current collector, large channels are maintained throughout the cathode structure thereby greatly facilitating the diffusion of the electrolytic solution of the cell, throughout the cathode structure. Secondly, the conductive cathode current collector extends throughout the cathode structure and is in close contact with all of the cathode material.

Inventors

  • 👤 Franz Goebel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 21:30
CPC Classifications
H; H01; H01M; H01M6/00; H01M6/14; H01M4/00; H01M4/02; H01M4/06; H01M4/64

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 239 words
A primary electrochemical cell which is capable of achieving high discharge currents comprising an outer cell casing, a first terminal on the exterior of the casing, an electrochemical system for a primary electrochemical cell including an anode material connected to the first terminal, a cathode material comprising a plurality of porous, semi-rigid, discrete globules having the following composition: from about 40 to 99 weight percent of carbon black, at least 1 percent of a mechanical binder which is inert in the primary electochemical cell, and the remainder being graphite, said discrete globules being spaced from one another to thereby define spaces therebetween, and an electrolytic solution including a cathode depolarizer that is electrochemically reduced on the surface of the cathode material during discharge of said cell, a porous separator of non-conductive material disposed between the anode material and the cathode material, a second terminal located on the exterior of the casing, means for electrically insulating the second terminal from the first terminal, and a cathode current collector connecting the cathode material to the second terminal, the cathode current collector comprising a plurality of electrically interconnected layers of porous metallic material, the cathode material globules being interposed between the layers of cathode current collector so that the cathode current collector extends throughout the cathode material, the electrolytic solution being diffused throughout the porous separator and the porous cathode current collector through the spaces between the plurality of discrete cathode globules.
Claim 2
Dependent Claim 239 words
A primary electrochemical cell which is capable of achieving high discharge currents comprising an outer cell casing, a first terminal on the exterior of the casing, an electrochemical system for a primary electrochemical cell including an anode material connected to the first terminal, a cathode material comprising a plurality of porous, semi-rigid, discrete globules having the following composition: from about 40 to 99 weight percent of carbon black, at least 1 percent of a mechanical binder which is inert in the primary electochemical cell, and the remainder being graphite, said discrete globules being spaced from one another to thereby define spaces therebetween, and an electrolytic solution including a cathode depolarizer that is electrochemically reduced on the surface of the cathode material during discharge of said cell, a porous separator of non-conductive material disposed between the anode material and the cathode material, a second terminal located on the exterior of the casing, means for electrically insulating the second terminal from the first terminal, and a cathode current collector connecting the cathode material to the second terminal, the cathode current collector comprising a plurality of electrically interconnected layers of porous metallic material, the cathode material globules being interposed between the layers of cathode current collector so that the cathode current collector extends throughout the cathode material, the electrolytic solution being diffused throughout the porous separator and the porous cathode current collector through the spaces between the plurality of discrete cathode globules.
Claim 3
Dependent Claim 26 words
A primary electrochemical cell according to claim 1, wherein the cathode material globules are at least partially compressed between the layers of the cathode current collector.
Claim 4
Dependent Claim 22 words
A primary electrochemical cell according to claim 2, wherein the cathode current collector is an elongated sheet of the porous metallic material.
Claim 5
Dependent Claim 19 words
A primary electrochemical cell according to claim 3, wherein the elongated sheet is rolled to form a cylindrical structure.
Claim 6
Dependent Claim 34 words
A primary electrochemical cell according to claim 2, wherein the cathode current collector is a plurality of sheets of the porous metallic material and further includes means for electrically interconnecting the plurality of sheets.
Claim 7
Dependent Claim 17 words
A primary electrochemical cell according to claim 2, wherein the porous metallic material is a screen-like material.
Claim 8
Dependent Claim 19 words
A primary electrochemical cell according to claim 6, wherein the porous metallic material is a nickel containing screen material.
Claim 9
Dependent Claim 16 words
A primary electrochemical cell according to claim 2, wherein the mechanical binder is a fluorocarbon polymer.
Claim 10
Dependent Claim 37 words
A primary electrochemical cell according to claim 8, wherein the cathode material has the following composition as given in weight percent: ______________________________________ Graphite 0 - 30 Carbon black 65 - 99 Fluorocarbon 1 - 10 polymer ______________________________________
Claim 11
Dependent Claim 16 words
A primary electrochemical cell according to claim 1, wherein the anode material includes an alkali metal.
Claim 12
Dependent Claim 48 words
A primary electrochemical cell according to claim 4, wherein the electrolytic solution includes a solvent which consists essentially of an inorganic oxyhalide of phosphorus or sulfur, and a solute dissolved therein, said oxyhalide solvent being electrochemically reduced on the surface of the cathode during operation of the cell.
Claim 13
Dependent Claim 27 words
A primary electrochemical cell according to claim 11, wherein the solvent is selected from the group consisting of phosphorus oxychloride, thionyl chloride, sulfuryl chloride, and mixtures thereof.
Claim 14
Dependent Claim 13 words
A primary electrochemical cell according to claim 12, wherein the anode is lithium.
Claim 15
Dependent Claim 13 words
A primary electrochemical cell according to claim 1, wherein the anode is lithium.
Claim 16
Dependent Claim 204 words
A primary electrochemical cell which is capable of achieving high discharge currents comprising an outer cell casing, a first terminal on the exterior of the casing, an electrochemical system for a primary electrochemical cell including an anode material connected to the first terminal, a cathode material comprising a plurality of porous, semi-rigid, discrete globules, said discrete globules being spaced from one another to thereby define spaces therebetween, and an electrolytic solution including a cathode depolarizer that is electrochemically reduced on the surface of the cathode material during discharge of said cell, a porous separator of non-conductive material disposed between the anode material and the cathode material, a second terminal located on the exterior of the casing, means for electrically insulating the second terminal from the first terminal, and a cathode current collector connecting the cathode material to the second terminal, the cathode current collector comprising a plurality of electrically interconnected layers of porous metallic material, the cathode material globules being interposed between the layers of cathode current collector so that the cathode current collector extends throughout the cathode material, the electrolytic solution being diffused throughout the porous separator and the porous cathode current collector through the spaces between the plurality of discrete cathode globules.
Claim 17
Dependent Claim 204 words
A primary electrochemical cell which is capable of achieving high discharge currents comprising an outer cell casing, a first terminal on the exterior of the casing, an electrochemical system for a primary electrochemical cell including an anode material connected to the first terminal, a cathode material comprising a plurality of porous, semi-rigid, discrete globules, said discrete globules being spaced from one another to thereby define spaces therebetween, and an electrolytic solution including a cathode depolarizer that is electrochemically reduced on the surface of the cathode material during discharge of said cell, a porous separator of non-conductive material disposed between the anode material and the cathode material, a second terminal located on the exterior of the casing, means for electrically insulating the second terminal from the first terminal, and a cathode current collector connecting the cathode material to the second terminal, the cathode current collector comprising a plurality of electrically interconnected layers of porous metallic material, the cathode material globules being interposed between the layers of cathode current collector so that the cathode current collector extends throughout the cathode material, the electrolytic solution being diffused throughout the porous separator and the porous cathode current collector through the spaces between the plurality of discrete cathode globules.
Claim 18
Dependent Claim 46 words
A primary electrochemical cell according to claim 15 wherein the cathode current collector is an elongated sheet of the porous metallic material rolled to form a cylindrical structure, and the cathode material globules are at least partially compressed between the layers of the cathode current collector.
Claim 19
Dependent Claim 34 words
A primary electrochemical cell according to claim 15 wherein the cathode current collector is a plurality of sheets of the porous metallic material and further includes means for electrically interconnecting the plurality of sheets.
Claim 20
Dependent Claim 35 words
A primary electrochemical cell according to claim 15 wherein the electrolytic solution includes a solvent selected from the group consisting of phosphorus oxychloride, thionyl chloride, sulfuryl chloride, and mixtures thereof, and a solute dissolved therein.
Claim 21
Dependent Claim 14 words
A primary electrochemical cell according to claim 15, wherein the anode material is lithium.

References Cited (Backward Citations)

US3510353A Cited
US3676222A Cited
US3796606A Cited
US3922174A Cited
US3870565A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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