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US4020230A Expired / Lapsed US ⏱️ 0.0 years remaining

Microporous polyethylene hollow fibers and process of preparing them

Assignee: Dow Chemical Co
•
Filing: 1975-10-03
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Granted: 1977-04-26
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Expires: 1995-10-03
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Abstract

Abstract Normally hydrophobic, polyethylene hollow fibers having contiguous microporosity are prepared by extruding a heated solution of a polyethylene and an ester from a hollow fiber spinnerette, simultaneously cooling and drawing the forming fibers to a ratio of up to 40 to 1, drawing the gelled fibers to an overall ratio of from about 1.5/1 to 800/1 and then removing the ester. The maximum pore radius ranges up to about 50A, and the fibers have gas permeabilities approaching 10 - 2 cc (STP) per cm 2 per second per cm. Hg. transmembrane pressure differential. A significant increase in permeability over polyethylene hollow fibers made according to the teachings of the prior art is achieved.

Inventors

  • 👤 Robert D. Mahoney
  • 👤 Stephen E. Schneider

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 23:31
CPC Classifications
D; D01; D01D; D01D5/00; D01D5/24; B; B01; B01D; B01D67/00; B01D67/0002; B01D67/0023; B01D67/0025; B01D67/0027; B01D67/003; B01D69/00; B01D69/08; B01D71/00; B01D71/06; B01D71/26; B01D71/261; Y; Y10; Y10T; Y10T428/00; Y10T428/29; Y10T428/2913; Y10T428/2973; Y10T428/2975

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 40 words
A microporous hollow fiber in which the porosity is contiguous, the O 2 gas permeability is at least 2×10.sup. -5 cc (STP) per cm 2 per second per cm Hg. transmembrane pressure differential and said fiber consists essentially of polyethylene.
Claim 2
Dependent Claim 40 words
A microporous hollow fiber in which the porosity is contiguous, the O 2 gas permeability is at least 2×10.sup. -5 cc (STP) per cm 2 per second per cm Hg. transmembrane pressure differential and said fiber consists essentially of polyethylene.
Claim 3
Dependent Claim 30 words
A fiber of claim 1 having an oxygen gas permeability of at least 1×10.sup. -3 cc per cm 2 of membrane area per second per cm Hg. transmembrane pressure differential.
Claim 4
Dependent Claim 19 words
A fiber of claim 2 having an oxygen gas permeability, as therein defined, of at least 2×10.sup. -3 .
Claim 5
Dependent Claim 20 words
A fiber as in claim 1, of which 10 weight percent or less is derived from olefins other than ethylene.

References Cited (Backward Citations)

US3423491A Cited
US3798185A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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