Process for the extractive purification of phosphoric acid containing cationic impurities

Claim 1

A process for purifying an aqueous phosphoric acid containing cationic impurities using extraction techniques which comprises: a. adding to said aqueous phosphoric acid an organic solvent miscible in all proportions with phosphoric acid and water selected from the group consisting of an aliphatic alcohol and ketone, the weight ratio of said organic solvent to the weight ratio of P 2 O 5 in said aqueous phosphoric acid being in the range of from 1:1 to 20:1 b. removing any solids residue; c. countercurrently contacting the resulting mixture of step (a) with a concentrated solution of an inorganic multivalent cationic salt selected from the group consisting of aluminum, calcium, magnesium and zinc cationic salts, said inorganic multivalent cationic salt being soluble in water and not tending to form insoluble precipitates during such introduction, the volumetric ratio of said concentrated solution to the volume of said mixture being in the range of from 10:1 to 1:250 thereby forming a liquid aqueous inorganic salt phase including said cationic impurities and a liquid phosphoric acid-organic solvent phase; d. separating said organic solvent phase from said inorganic salt phase; e. repeating steps (c) and (d); and f. recovering phosphoric acid from the organic solvent phase by distillation.