Patent US2489178A successfully refreshed from Google Patents.
Patent US4018809A successfully refreshed from Google Patents.
US4018809A
Expired / Lapsed
US
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Solutions of new antimony complexes
Assignee: Plumley and Tyner
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Filing: 1975-09-12
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Granted: 1977-04-19
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Expires: 1995-09-12
Abstract
Abstract The invention relates to a process for the production of solutions of substantially water-insoluble complex antimony compounds in polar organic solvents by esterifying an alpha -hydroxy polycarboxylic acid with a polyol, reacting an excess of the esterification product with an antimony oxide in a polar organic solvent and reacting the free carboxylic groups with a monoisocyanate.
Inventors
- 👤 Eduard Radlmann
- 👤 Heinz Schaffner
- 👤 Gunter Lorenz
- 👤 Gunther Nischk
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 17:28
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/90; C07F9/902; C08; C08K; C08K5/00; C08K5/59
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
207 words
A process for the production of a solution of a substantially water-insoluble complex antimony compound in a polar organic solvent which comprises esterifying an α-hydroxy polycarboxylic acid with a polyol in a molar ratio of the carboxyl groups to the hydroxyl groups in the polyol of at least 2 : 1 and in the presence of an acid transesterification catalyst; reacting an excess of the esterification product with an antimony oxide in a polar organic solvent at a temperature in the range of from 100° to 200° C to form a clear solution still containing free carboxyl groups; and adding a monoisocyanate to the solution at a temperature below 100° C in such a quantity that the free carboxyl groups are converted into the corresponding amide groups the monoisocyanate corresponding to the general formula R.sub.1 -N=C=O in which R 1 is a straight-chain or branched alkyl group having from 1 to 20 carbon atoms, or ##STR3## in which R 2 , R 3 , R 4 , R 5 and R 6 may be the same as or different from one another and may represent a member selected from the group consisting of hydrogen, an alkyl having from 1 to 5 carbon atoms, fluorine, chlorine or bromine.
Claim 2
Dependent Claim
207 words
A process for the production of a solution of a substantially water-insoluble complex antimony compound in a polar organic solvent which comprises esterifying an α-hydroxy polycarboxylic acid with a polyol in a molar ratio of the carboxyl groups to the hydroxyl groups in the polyol of at least 2 : 1 and in the presence of an acid transesterification catalyst; reacting an excess of the esterification product with an antimony oxide in a polar organic solvent at a temperature in the range of from 100° to 200° C to form a clear solution still containing free carboxyl groups; and adding a monoisocyanate to the solution at a temperature below 100° C in such a quantity that the free carboxyl groups are converted into the corresponding amide groups the monoisocyanate corresponding to the general formula R.sub.1 -N=C=O in which R 1 is a straight-chain or branched alkyl group having from 1 to 20 carbon atoms, or ##STR3## in which R 2 , R 3 , R 4 , R 5 and R 6 may be the same as or different from one another and may represent a member selected from the group consisting of hydrogen, an alkyl having from 1 to 5 carbon atoms, fluorine, chlorine or bromine.
Claim 3
Dependent Claim
28 words
The process of claim 1, wherein said polar organic solvent is a member selected from the group consisting of dimethyl formamide, dimethyl acetamide, N-methyl pyrrolidone and dimethyl sulphoxide.
Claim 4
Dependent Claim
12 words
The process of claim 1, wherein said antimony oxide is antimony trioxide.
Claim 5
Dependent Claim
16 words
The process of claim 1, wherein said α-hydroxy polycarboxylic acid is tartaric acid or citric acid.
Claim 6
Dependent Claim
45 words
The process of claim 1, wherein said polyol is a compound corresponding to the formula R (OH) n , in which R is a straight-chain or branched aliphatic group having from 2 to 20 carbon atoms and n is a number from 2 to 6.
Claim 7
Dependent Claim
31 words
The process of claim 1, wherein said esterification of said α-hydroxy polycarboxylic acid with said polyol is carried out at a temperature in the range of from 100° to 180° C.
Claim 8
Dependent Claim
31 words
The process of claim 1, wherein the molar excess of the carboxyl groups in the esterification product relative to the antimony amounts to between 2 : 1 and 4 : 1.
Claim 9
Dependent Claim
18 words
A solution of a complex antimony compound in a polar organic solvent when produced according to claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-04-18 | 1980-10-18 | 1981-04-19 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-04-18 | 1984-10-18 | 1985-04-19 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-04-18 | 1988-10-18 | 1989-04-19 | $7700.00 | Window Closed / Lapsed |