Abstract This disclosure describes the process for producing an apparently amorphous porous boron carbide having a mean particle size less than 1 micron in diameter, effective pore sizes on the order of 30 Angstrom units, and surface areas on the order of 100 m 2 /gr and greater. The process involves the gaseous phase reaction of acetylene (C 2 H 2 ) with diborane (B 2 H 6 ). The reaction is produced in a closed chamber initiated by an appropriate igniting device, such as a hot wire. This disclosure defines an optimum ratio of four parts diborane to one part acetylene and it describes the operating conditions under which the reaction occurs and the variation in physical properties and yield resulting from changes of ratio of the constituents. It also describes modification of the present batch process to a continuous production process. Typical uses for the material in its basic or altered form are described, such as a catalyst for gas-solid reactions, as a catalyst-supporting substrate for certain transition metals and other catalytic materials, as a gelling agent or grease thickener, as a thermal neutron absorber, either neat or in admixture with oils, etc., as a high temperature insulation material and as a fluidized bed heat exchange medium.
A process of producing a boron carbide powder comprising the steps of: providing a gaseous mixture of diborane and acetylene at a temperature less than 80° C to inhibit undesired side reactions and decomposition of the gases; igniting the relatively low temperature gaseous mixture for producing a flame front; promoting a relative movement between said flame front and said gaseous mixture for consuming the mixture in a flame reaction whereby said boron carbide powder is produced; and recovering a reaction product of boron carbide powder.
Claim 2
Dependent Claim
85 words
A process of producing a boron carbide powder comprising the steps of: providing a gaseous mixture of diborane and acetylene at a temperature less than 80° C to inhibit undesired side reactions and decomposition of the gases; igniting the relatively low temperature gaseous mixture for producing a flame front; promoting a relative movement between said flame front and said gaseous mixture for consuming the mixture in a flame reaction whereby said boron carbide powder is produced; and recovering a reaction product of boron carbide powder.
Claim 3
Dependent Claim
23 words
The process of claim 1 wherein the ratio of gaseous mixture of diborane and acetylene is in the range of 1:1 to 20:1.
Claim 4
Dependent Claim
19 words
The process of claim 1 wherein the ratio of the gaseous mixture of diborane and acetylene is about 4:1.
Claim 5
Dependent Claim
14 words
The process of claim 1 wherein the reactant gases comprise diborane, acetylene and hydrogen.
Claim 6
Dependent Claim
81 words
A boron carbide powder of a porous nature with a surface area in excess of 100 m 2 per gram and with a mean pore size of about 30 Angstrom units and a mean particle diameter of less than one micron, said powder being produced by a gaseous phase reaction of a boron hydride and acetylene and being amorphous to the extent that it has no apparent crystalline properties under X-ray spectroscopy and electron microscopy at magnifications up to 10,000 diameters.
Claim 7
Dependent Claim
81 words
A boron carbide powder of a porous nature with a surface area in excess of 100 m 2 per gram and with a mean pore size of about 30 Angstrom units and a mean particle diameter of less than one micron, said powder being produced by a gaseous phase reaction of a boron hydride and acetylene and being amorphous to the extent that it has no apparent crystalline properties under X-ray spectroscopy and electron microscopy at magnifications up to 10,000 diameters.