Patent US4017436A successfully refreshed from Google Patents.
US4017436A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Thermoplastic resin composition
Assignee: Sumitomo Chemical Co Ltd
•
Filing: 1975-09-02
•
Granted: 1977-04-12
•
Expires: 1995-09-02
Abstract
Abstract A resin composition consisting essentially of a styrene-butadiene block copolymer resin, a liquid polybutadiene resin or its modification product, and a tackifier. This resin composition is transparent, excellent in mechanical properties, particularly elongation, impact strength and elastic recovery, and is also improved in film-forming ability and tackiness.
Inventors
- 👤 Minoru Tabana
- 👤 Tatsuyuki Mitsuno
- 👤 Hiroshi Maki
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 04:06
CPC Classifications
C; C08; C08L; C08L53/00; C08L53/02; C08L63/00; C08L63/08
Claims Analysis
Total Claims: 9
Claim 1
Independent Claim
286 words
A resin composition consisting essentially of a. a styrene-butadiene block copolymer resin represented by the formula, A.sub.1 -- B.sub.1 -- C -- B.sub.2 -- A.sub.2 wherein A 1 and A 2 are non-elastomeric blocks comprising a styrene polymer chain; B 1 and B 2 are elastomeric blocks comprising a random copolymer chain in which styrene and butadiene have uniformly been distributed; C is an elastomeric block comprising a butadiene homopolymer chain or a styrene-butadiene copolymer chain; the proportion of the sum of A 1 and A 2 in the block copolymer is 40 to 80 weight %; the proportion of the sum of B 1 and B 2 in the block copolymer is 10 to 60 weight %; the proportion of C in the block copolymer is 0 to 25 weight % and is always smaller than the proportion of the sum of B 1 and B 2 ; the weight ratio of A 1 to A 2 is in the range from 2:8 to 8:2; the weight ratio of B 1 to B 2 is in the range from 0:10 to 10:0; the weight ratio of styrene to butadiene in B 1 and B 2 is in the range from 10:90 to 75:25; and the weight ratio of styrene to butadiene in C is in the range from 0:100 to 10:90, b. a resin selected from the group consisting of a liquid polybutadiene, a liquid butadiene-styrene copolymer, a maleic anhydride-modified liquid polybutadiene and an epoxidation-modified liquid polybutadiene, and c. a tackifier, wherein the contents of (a) the styrene-butadiene block copolymer, (b) the resin, and (c) the tackifier are 70 to 94 weight %, 3 to 15 weight % and 3 to 15 weight %, respectively.
Claim 2
Dependent Claim
286 words
A resin composition consisting essentially of a. a styrene-butadiene block copolymer resin represented by the formula, A.sub.1 -- B.sub.1 -- C -- B.sub.2 -- A.sub.2 wherein A 1 and A 2 are non-elastomeric blocks comprising a styrene polymer chain; B 1 and B 2 are elastomeric blocks comprising a random copolymer chain in which styrene and butadiene have uniformly been distributed; C is an elastomeric block comprising a butadiene homopolymer chain or a styrene-butadiene copolymer chain; the proportion of the sum of A 1 and A 2 in the block copolymer is 40 to 80 weight %; the proportion of the sum of B 1 and B 2 in the block copolymer is 10 to 60 weight %; the proportion of C in the block copolymer is 0 to 25 weight % and is always smaller than the proportion of the sum of B 1 and B 2 ; the weight ratio of A 1 to A 2 is in the range from 2:8 to 8:2; the weight ratio of B 1 to B 2 is in the range from 0:10 to 10:0; the weight ratio of styrene to butadiene in B 1 and B 2 is in the range from 10:90 to 75:25; and the weight ratio of styrene to butadiene in C is in the range from 0:100 to 10:90, b. a resin selected from the group consisting of a liquid polybutadiene, a liquid butadiene-styrene copolymer, a maleic anhydride-modified liquid polybutadiene and an epoxidation-modified liquid polybutadiene, and c. a tackifier, wherein the contents of (a) the styrene-butadiene block copolymer, (b) the resin, and (c) the tackifier are 70 to 94 weight %, 3 to 15 weight % and 3 to 15 weight %, respectively.
Claim 3
Dependent Claim
50 words
A composition according to claim 1, wherein the styrene-butadiene block coplymer resin has a total styrene content of 65 to 90 weight %, a total butadiene content of 10 to 35 weight %, and an intrinsic viscosity of 0.35 to 1.8 dl/g as measured in toluene solvent at 30° C.
Claim 4
Dependent Claim
28 words
A composition according to claim 1, wherein said resin is a liquid butadiene homopolymer or a liquid butadiene-styrene copolymer having an average molecular weight of 300 to 10,000.
Claim 5
Dependent Claim
40 words
A composition according to claim 1, wherein the maleic anhydride-modified product is a product which is obtained by modifying a butadiene homopolymer having an average molecular weight of 250 to 5,000 with 20 weight % or less of maleic anhydride.
Claim 6
Dependent Claim
45 words
A composition according to claim 1, wherein the epoxidation-modified product is a product which is obtained by epoxidizing a butadiene homopolymer having an average molecular weight of 250 to 5,000 with an organic peracid and has an oxirane-oxygen content of 0.5 to 20 weight %.
Claim 7
Dependent Claim
15 words
A composition according to claim 5, wherein the organic peracid is performic or peracetic acid.
Claim 8
Dependent Claim
27 words
A composition according to claim 1, wherein the tackifier is a rosin type resin, a terpene type resin, a petroleum type hydrocarbon resin or a cumarone-indene resin.
Claim 9
Dependent Claim
32 words
A composition according to claim 1 which has been incorporated with, as a plasticizer, at least one member selected from the group consisting of phthalic acid esters and aliphatic dibasic acid esters.
References Cited (Backward Citations)
US3239478A
Cited
US3329734A
Cited
FR1541288A
Cited
FR1574484A
Cited
US3789090A
Cited
US3852373A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-04-11 | 1980-10-11 | 1981-04-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-04-11 | 1984-10-11 | 1985-04-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-04-11 | 1988-10-11 | 1989-04-12 | $7700.00 | Window Closed / Lapsed |