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US4013587A
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Process for the manufacture of spherical alumina-containing particles
Assignee: Kali Chemie AG
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Filing: 1976-02-03
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Granted: 1977-03-22
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Expires: 1996-02-03
Abstract
Abstract Disclosed is process for the preparation of alumina-containing particles, comprising the steps of (a) mixing an aluminum oxide hydrosol containing a hydrate of alumina or activated alumina and an additive component selected from a high molecular weight natural organic material which is insoluble in aqueous solution up to a temperature of 50 DEG C. and carbon with a solution of hydrolyzable base to form a mixture; (b) introducing the mixture in dispersed form into a water-immiscible liquid having a temperature of from about 60 to 100 DEG C., whereby gel particles are formed; (c) aging the gel particles in the liquid at the temperature and subsequently in an aqueous ammonia solution; (d) recovering the aged particles; and (e) calcining the recovered particles.
Inventors
- 👤 Hermann Fischer
- 👤 Hubert Schindler
- 👤 Winfried Kuhrt
- 👤 Guenter Weidenbach
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 17:38
CPC Classifications
B; B01; B01J; B01J21/00; B01J21/02; B01J21/04; B01J2/00; B01J2/02; B01J2/06; B01J2/08; B01J35/00; B01J35/50; B01J35/51; B01J37/00; B01J37/0009; B01J37/0018; B01J37/0072
Claims Analysis
Total Claims: 20
Claim 1
Independent Claim
107 words
A process for the preparation of alumina-containing particles, comprising the steps of: a. mixing an aluminum oxide hydrosol containing a hydrate of alumina or activated alumina and an additive component of wood flour, starch, carbon black or carbon powder with a solution of a hydrolyzable base to form a mixture; b. introducing said mixture in dispersed form into a water-immiscible liquid having a temperature of from about 60° to 100° C., whereby gel particles are formed; c. aging said gel particles in said liquid at said temperature and subsequently in an aqueous ammonia solution; d. recovering said aged particles; and e. drying and calcining said recovered particles.
Claim 2
Dependent Claim
107 words
A process for the preparation of alumina-containing particles, comprising the steps of: a. mixing an aluminum oxide hydrosol containing a hydrate of alumina or activated alumina and an additive component of wood flour, starch, carbon black or carbon powder with a solution of a hydrolyzable base to form a mixture; b. introducing said mixture in dispersed form into a water-immiscible liquid having a temperature of from about 60° to 100° C., whereby gel particles are formed; c. aging said gel particles in said liquid at said temperature and subsequently in an aqueous ammonia solution; d. recovering said aged particles; and e. drying and calcining said recovered particles.
Claim 3
Dependent Claim
20 words
The process of claim 1, wherein said recovery step comprises washing said particles with water and drying said washed particles.
Claim 4
Dependent Claim
17 words
The process of claim 1, wherein said aluminum oxide hydrosol further contains a low density silica-containing substance.
Claim 5
Dependent Claim
23 words
The process of claim 1, wherein said additive component comprises wood flour or starch having a particle size of up to about 100μ.
Claim 6
Dependent Claim
23 words
The process of claim 1, wherein said additive component comprises carbon black having a particle size of up to about 100 m μ.
Claim 7
Dependent Claim
32 words
The process of claim 1, wherein said additive component is present in an amount sufficient to provide from about 3 to 35% by weight based upon the weight of the calcined particles.
Claim 8
Dependent Claim
14 words
The process of claim 6, wherein said amount is between about 5 and 25%.
Claim 9
Dependent Claim
49 words
The process of claim 1, wherein said particles are dried at a temperature of from about 120° C. to 200° C. and are calcined first at a temperature of between about 250° C. to 400° C. and then at a temperature of between about 600° C. and 1000° C.
Claim 10
Dependent Claim
39 words
The process of claim 1, wherein said aluminum oxide in said hydrosol is present in an amount sufficient to provide from about 15 to 35% by weight Al 2 O 3 based upon the mass of the calcined particles.
Claim 11
Dependent Claim
25 words
The process of claim 9, wherein said aluminum oxide in said hydrosol provides from about 20 to 30% of said Al 2 O 3 .
Claim 12
Dependent Claim
25 words
The process of claim 1, wherein the hydrate of alumina or the activated alumina has an average particle diameter of up to about 10 μ.
Claim 13
Dependent Claim
36 words
The process of claim 1, wherein the hydrate of alumina or the activated alumina is present in said hydrosol in an amount sufficient to provide from about 65 to 85% by weight of the calcined particles.
Claim 14
Dependent Claim
16 words
The process of claim 12, wherein said amount is from about 70 to 80% by weight.
Claim 15
Dependent Claim
33 words
The process of claim 3, wherein said silica-containing substance is present in an amount sufficient to provide a SiO 2 content of from about 10 to 40% by weight of the calcined particles.
Claim 16
Dependent Claim
13 words
The process of claim 3, wherein said silica-containing substance comprises a pyrogenic silica.
Claim 17
Dependent Claim
21 words
The process of claim 2, wherein said aluminum oxide hydrosol further contains a difficulty-soluble compound of at least one catalytically-active metal.
Claim 18
Dependent Claim
14 words
The process of claim 16, wherein said catalytically active metal comprises copper and chromium.
Claim 19
Dependent Claim
40 words
The process of claim 17, wherein said compounds of copper and chromium are present in an amount sufficient to provide a content of from about 3 to 15% by weight based upon the calcined particles each of copper-2-oxide and chromium-3-oxide.
Claim 20
Dependent Claim
20 words
The process of claim 18, wherein said copper-2-oxide and chromium-3-oxide content are each from about 7 to 10% by weight.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-21 | 1980-09-20 | 1981-03-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-21 | 1984-09-20 | 1985-03-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-21 | 1988-09-20 | 1989-03-22 | $7700.00 | Window Closed / Lapsed |