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US4012343A Expired / Lapsed US ⏱️ 0.0 years remaining

Crosslinked olefin polymer having improved flame retardance

Assignee: Dow Chemical Co
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Filing: 1974-09-09
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Granted: 1977-03-15
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Expires: 1994-09-09
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Abstract

Abstract Markedly improved flame retardance is imparted to crosslinked olefin polymers containing halogenated organic moiety by incorporating therein elemental red phosphorus. The resulting flame retardant compositions are particularly useful in fabrication of crosslinked olefin polymer foams.

Inventors

  • 👤 Charles F. Raley, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 07:37
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/0014; C08K; C08K3/00; C08K3/02; C08K5/00; C08K5/0008; C08K5/0066; C08K5/02; C08K5/04; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/06; C08L23/08; C08L23/0846; C08L23/0853; C08L91/00; C08L91/06; C08J2357/00; C08L2201/00; C08L2201/02; Y; Y10; Y10S; Y10S260/00; Y10S260/24

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 164 words
In an olefin polymer composition containing a halogenated organic moiety which is active chlorinated organic compound, active brominated organic compound, passive brominated organic compound or hexachlorocyclopentadiene, dimerized hexachlorocyclopentadiene, hexachloroendomethylene tetrahydrophthalic acid or a derivative thereof and having the halogen concentration from about 5 to about 95 weight percent based on said moiety, the olefin polymer being selected from the group consisting of homopolymers and copolymers of aliphatic hydrocarbon monoolefins having no more than 12 carbon atoms, substituted α-monoolefins wherein the substituent is carboxylic acid, alkyl or haloalkyl ester of carboxylic acid wherein alkyl or haloalkyl has from 1 to 12 carbon atoms, acyl having from 1 to 12 carbon atoms, carboxylate having from 1 to 12 carbon atoms, alkoxyl having from 1 to 12 carbon atoms, and aryloxy having 6 to 12 carbon atoms, the improvement wherein the olefin polymer is crosslinked to at least its gel point and contains a flame retarding amount of elemental phosphorus having a specific gravity greater than 2.0.
Claim 2
Dependent Claim 164 words
In an olefin polymer composition containing a halogenated organic moiety which is active chlorinated organic compound, active brominated organic compound, passive brominated organic compound or hexachlorocyclopentadiene, dimerized hexachlorocyclopentadiene, hexachloroendomethylene tetrahydrophthalic acid or a derivative thereof and having the halogen concentration from about 5 to about 95 weight percent based on said moiety, the olefin polymer being selected from the group consisting of homopolymers and copolymers of aliphatic hydrocarbon monoolefins having no more than 12 carbon atoms, substituted α-monoolefins wherein the substituent is carboxylic acid, alkyl or haloalkyl ester of carboxylic acid wherein alkyl or haloalkyl has from 1 to 12 carbon atoms, acyl having from 1 to 12 carbon atoms, carboxylate having from 1 to 12 carbon atoms, alkoxyl having from 1 to 12 carbon atoms, and aryloxy having 6 to 12 carbon atoms, the improvement wherein the olefin polymer is crosslinked to at least its gel point and contains a flame retarding amount of elemental phosphorus having a specific gravity greater than 2.0.
Claim 3
Dependent Claim 21 words
The improvement according to claim 1 which contains a self-extinguishing amount of elemental phosphorus having a specific gravity greater than 2.0.
Claim 4
Dependent Claim 41 words
The improvement according to claim 1 wherein the concentration of phosphorus is from about 0.5 to about 20 parts by weight per 100 parts of polymer and the atomic ratio of phosphorus to halogen is from about 4:1 to about 1:6.
Claim 5
Dependent Claim 33 words
The improvement according to claim 1 wherein the halogenated organic moiety is chlorinated paraffin wax, the chlorine concentration being from about 25 to about 97 weight percent based on the halogenated organic moiety.
Claim 6
Dependent Claim 57 words
The improvement according to claim 1 wherein the concentration of phosphorus is from about 1 to about 10 parts, the atomic ratio of phosphorus to halogen is from about 2:1 to about 1:3 and the sum of amount of phosphorus and amount of halogenated moiety is at least 5 parts based on 100 weight parts of polymer.
Claim 7
Dependent Claim 12 words
The improvement of claim 1 wherein the olefin polymer composition is foamed.
Claim 8
Dependent Claim 32 words
The improvement according to claim 1 wherein the olefin polymer is an aliphatic hydrocarbon α-monoolefin polymer and the halogenated organic moiety is hexachlorocyclopentadiene, dimerized hexachlorocyclopentadiene, hexachloroendomethylene tetrahydrophthalic acid or a derivative thereof.
Claim 9
Dependent Claim 17 words
The improvement according to claim 1 wherein the olefin polymer is an ethylene/vinyl acetate copolymer or polyethylene.
Claim 10
Dependent Claim 19 words
The improvement according to claim 7 wherein the α-monoolefin polymer is polyethylene and the halogenated organic moiety is hexabromocyclododecane.
Claim 11
Dependent Claim 39 words
The improvement according to claim 3 wherein the olefin polymer is polyethylene and the halogenated organic moiety is a passive brominated organic compound selected from the group consisting of decabromo diphenyl oxide, 2,3,3-tribromoallyl 2,4,6-tribromophenyl ether, 1-(2,4,5-tribromophenyl)-1-(2,4,6-tribromophenoxy)ethane, pentaerythrityltetrabromide and bis(2,3,3-tribromoallyl)maleate.
Claim 12
Dependent Claim 27 words
The improvement of claim 1 wherein the olefin polymer is crosslinked by exposing said polymer to ionizing irradiation at a dosage from about 0.1 to 10 megarad.
Claim 13
Dependent Claim 80 words
The process for preparing a fire retardant, crosslinked olefin polymer foam which comprises subjecting a sheet of an olefin polymer containing a halogenated organic moiety, a flame retarding amount of elemental phosphorus having a specific gravity greater than 2 and a foaming amount of a foaming agent to a dosage of ionizing radiation in the range from about 0.2 to about 6 megarad and thereafter floating the sheet on a heated salt bath while irradiating the sheet with heat rays.
Claim 14
Dependent Claim 80 words
The process for preparing a fire retardant, crosslinked olefin polymer foam which comprises subjecting a sheet of an olefin polymer containing a halogenated organic moiety, a flame retarding amount of elemental phosphorus having a specific gravity greater than 2 and a foaming amount of a foaming agent to a dosage of ionizing radiation in the range from about 0.2 to about 6 megarad and thereafter floating the sheet on a heated salt bath while irradiating the sheet with heat rays.
Claim 15
Dependent Claim 16 words
The improvement of claim 1 wherein the olefin polymer is crosslinked using a chemical crosslinking agent.
Claim 16
Dependent Claim 12 words
An improved olefin polymer composition prepared by the process of claim 12.

References Cited (Backward Citations)

GB1028553A Cited
US3330783A Cited
US3341480A Cited
US3373135A Cited
US3551379A Cited
US3650300A Cited
US3597385A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-14 1980-09-13 1981-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-14 1984-09-13 1985-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-14 1988-09-13 1989-03-15 $7700.00 Window Closed / Lapsed

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