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US4012315A Expired / Lapsed US ⏱️ 0.0 years remaining

Trap to remove metals utilizing a sulfur modified substrate and electrophoresis

Assignee: Mobil Oil AS
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Filing: 1975-10-31
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Granted: 1977-03-15
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Expires: 1995-10-31
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Abstract

Abstract Sulfur is deposited on a solid substrate. Metal compounds containing sulfur reaction products produced when hydrocarbon streams contaminated with the metals are contacted with the sulfur modified substrate are removed by electrophoresis.

Inventors

  • 👤 Israel J. Heilweil

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 08:42
CPC Classifications
C; C10; C10G; C10G29/00; C10G29/06; C10G25/00; C10G25/003

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 126 words
A method for removing metal contaminants from substantially hydrocarbon streams comprising contacting said substantially hydrocarbon streams with two successive bed sections; said first bed section containing a solid substrate selected from the group consisting of silicas, aluminosilicates, clays, metal oxides, metal sulfides, macroreticular resins, high surface area resins and polymers containing polar groups such as OH, N, SO 3 = and COO - , upon which sulfur particles ranging in size up to an effective diameter of about 0.1 microns are deposited; and said second bed section containing particles comprising at least two of aluminum, cobalt, iron and carbon, whereby sulfur reaction products of said metal contaminants are produced in said first bed section and are plated out on the particles in said second bed section.
Claim 2
Independent Claim 126 words
A method for removing metal contaminants from substantially hydrocarbon streams comprising contacting said substantially hydrocarbon streams with two successive bed sections; said first bed section containing a solid substrate selected from the group consisting of silicas, aluminosilicates, clays, metal oxides, metal sulfides, macroreticular resins, high surface area resins and polymers containing polar groups such as OH, N, SO 3 = and COO - , upon which sulfur particles ranging in size up to an effective diameter of about 0.1 microns are deposited; and said second bed section containing particles comprising at least two of aluminum, cobalt, iron and carbon, whereby sulfur reaction products of said metal contaminants are produced in said first bed section and are plated out on the particles in said second bed section.
Claim 3
Dependent Claim 22 words
A method for removing metal contaminants from liquid streams as claimed in claim 1 wherein said solid substrate is a macroreticular resin.
Claim 4
Dependent Claim 39 words
A method for removing metal contaminants from liquid streams as claimed in claim 1 wherein said particles of said second bed section are formed by electroless deposition of one of said aluminum, cobalt, iron or carbon on the other.
Claim 5
Dependent Claim 20 words
A method for removing metal contaminants from liquid streams as claimed in claim 3 wherein iron is deposited on carbon.
Claim 6
Dependent Claim 30 words
A method of removing metal contaminants from liquid streams as claimed in claim 1 wherein each of said aluminum, cobalt, iron or carbon is in a separate and distinct particle.

References Cited (Backward Citations)

US2540129A Cited
US2781297A Cited
US3011973A Cited
US3933624A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-14 1980-09-13 1981-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-14 1984-09-13 1985-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-14 1988-09-13 1989-03-15 $7700.00 Window Closed / Lapsed

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