Abstract An improved curable epoxy resin composition of a vicinalpolyepoxide and an effective amount of a novel polyether thiourea curing agent is disclosed. The improved curable epoxy resins which are useful as coatings, castings, sealants, and adhesives show improved tensile shear strength, flexural strength, and ultimate elongation. The novel polyether thiourea curing agents of the instant invention are characterized by terminal primary amino groups and are formed by reaction of polyoxyalkylenepolyamines with thiourea, thiourea forming compounds or carbon disulfide. A preferred curing agent includes a mixture of a novel polyether thiourea formed by reaction of a polyoxypropylenepolyamine having a molecular weight of from about 200-2000 and an effective amount of carbon disulfide; and another known epoxy resin curing agent such as a polyoxyalkylenepolyamine in ratios of from about 5:1 to 1:5 by weight.
A curable epoxy resin composition consisting essentially of: a vicinal polyepoxide; and an effective amount of a polyether thiourea curing agent having terminal primary amino groups and being formed by the reaction of a compound selected from a group consisting of thiourea, thiourea forming compounds and carbon disulfide with a polyoxyalkylenepolyamine of the formula ##STR18## wherein X is a hydrogen or methyl radical, Z is a hydrocarbon radical having 2 to 5 carbon atoms forming from 2 to 4 external ether linkages, n is a number from 1 to about 15 and r is a number from 2 to 4 wherein the molar ratio of said compound to said polyoxyalkylenepolyamine is from 0.20 to 0.83, wherein X is a hydrogen the molecular weight is approximately 650 and wherein X is a methyl radical the molecular weight is from about 200 to 2,000.
Claim 2
Dependent Claim
142 words
A curable epoxy resin composition consisting essentially of: a vicinal polyepoxide; and an effective amount of a polyether thiourea curing agent having terminal primary amino groups and being formed by the reaction of a compound selected from a group consisting of thiourea, thiourea forming compounds and carbon disulfide with a polyoxyalkylenepolyamine of the formula ##STR18## wherein X is a hydrogen or methyl radical, Z is a hydrocarbon radical having 2 to 5 carbon atoms forming from 2 to 4 external ether linkages, n is a number from 1 to about 15 and r is a number from 2 to 4 wherein the molar ratio of said compound to said polyoxyalkylenepolyamine is from 0.20 to 0.83, wherein X is a hydrogen the molecular weight is approximately 650 and wherein X is a methyl radical the molecular weight is from about 200 to 2,000.
Claim 3
Dependent Claim
38 words
The curable epoxy resin composition of claim 1 wherein said polyether thiourea curing agent is employed in combination with an effective amount of a co-curing agent selected from a group consisting of aliphatic polyamines, aromatic polyamines and polyoxyalkylenepolyamines.
Claim 4
Dependent Claim
35 words
The curable epoxy resin composition of claim 2 wherein said co-curing agent is a polyoxyalkylenepolyamine and is present in an amount of from about 5:1 to 1:5 by weight of said polyether thiourea curing agent.
Claim 5
Dependent Claim
22 words
The curable epoxy resin of claim 1 wherein the molar ratio of said compound to said polyoxyalkylenepolyamine is from 0.20 to 0.6.