Patent US4010545A successfully refreshed from Google Patents.
US4010545A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Adhesive bonding to teeth of orthodontic brackets and the like
Assignee: Johnson and Johnson
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Filing: 1976-01-09
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Granted: 1977-03-08
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Expires: 1996-01-09
Abstract
Abstract Orthodontic brackets and the like are adhesively secured to teeth by means of a self-curing thixotropic acrylic ester monomer composition wherein the monomer has been made thixotropic through the inclusion of fumed silane treated silica and wherein the acrylic ester monomer or monomers have two or more active acrylic ester groups, the thixotropic compositions prior to curing having a viscosity of about 85,000 cps to 4,385,000 cps. Prior to adhering the orthodontic bracket or other device to the tooth surface, the tooth surface is acid-etched, rinsed and dried. The thixotropic-activated monomer is then applied to the surface of the tooth or to the surface of the orthodontic bracket just prior to placing the bracket on the tooth. The thixotropic acrylic ester monomer is activated prior to application by blending substantially equal proportions of a thixotropic monomer composition containing acrylic ester monomer, fumed silica, and amine activator with a thixotropic monomer composition containing acrylic ester monomer, fumed silica, and peroxide catalyst. The bracket is adhered to the tooth surface through means of the thixotropic monomer mix and left undisturbed while being kept relatively dry until the monomer has hardened. Arch-wires may then be applied to the orthodontic bracket.
Inventors
- 👤 Robert J. Kilian
- 👤 John S. Gallagher
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 09:40
CPC Classifications
A; A61; A61C; A61C7/00; A61C7/12; A61K; A61K6/00; A61K6/40; A61K6/70; A61K6/71; A61K6/76; A61K6/77
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
98 words
The method of adhering an attachment to a tooth surface comprising etching said tooth surface in the area to which said attachment is to be secured, placing said attachment on said etched tooth surface with a small amount of highly viscous thixotropic polyacrylic ester monomer composition between said attachment and said tooth surface, pressing said attachment against said tooth with said thixotropic monomer therebetween to wet the opposing surfaces of said tooth and attachment with said monomer and fill surface voids therebetween and curing said thixotropic monomer composition while said attachment is held on said tooth surface thereby.
Claim 2
Independent Claim
98 words
The method of adhering an attachment to a tooth surface comprising etching said tooth surface in the area to which said attachment is to be secured, placing said attachment on said etched tooth surface with a small amount of highly viscous thixotropic polyacrylic ester monomer composition between said attachment and said tooth surface, pressing said attachment against said tooth with said thixotropic monomer therebetween to wet the opposing surfaces of said tooth and attachment with said monomer and fill surface voids therebetween and curing said thixotropic monomer composition while said attachment is held on said tooth surface thereby.
Claim 3
Dependent Claim
18 words
The method of claim 1 in which said monomer composition has a viscosity of 85,000 to 4,385,000 cps.
Claim 4
Independent Claim
123 words
The method of securing an attachment to a tooth surface comprising etching the tooth surface, mixing a thixotropic acrylic ester monomer composition containing an amine activator with a thixotropic acrylic ester monomer composition containing a peroxide catalyst to prepare an activated thixotropic acrylic ester monomer mix having a viscosity under nonagitated conditions within the range of 85,000 to 4,385,000 cps., placing said attachment on said etched tooth surface with said activated thixotropic mix between the opposed surfaces of said tooth and attachment, pressing said attachment against said tooth surface to assure wetting the tooth and attachment with said monomer composition, and leaving said attachment undisturbed on said tooth surface until the monomer has polymerized to firmly bond said attachment to said tooth surface.
Claim 5
Independent Claim
123 words
The method of securing an attachment to a tooth surface comprising etching the tooth surface, mixing a thixotropic acrylic ester monomer composition containing an amine activator with a thixotropic acrylic ester monomer composition containing a peroxide catalyst to prepare an activated thixotropic acrylic ester monomer mix having a viscosity under nonagitated conditions within the range of 85,000 to 4,385,000 cps., placing said attachment on said etched tooth surface with said activated thixotropic mix between the opposed surfaces of said tooth and attachment, pressing said attachment against said tooth surface to assure wetting the tooth and attachment with said monomer composition, and leaving said attachment undisturbed on said tooth surface until the monomer has polymerized to firmly bond said attachment to said tooth surface.
Claim 6
Dependent Claim
34 words
The method of claim 3 wherein said tooth surface is etched by treating with a solution of phosphoric acid, water rinsed to remove said acid therefrom and then dried before applying said thixotropic mix.
Claim 7
Dependent Claim
97 words
The method of claim 3 wherein said thixotropic mix is prepared by mixing together in substantially equal proportion, a thixotropic composition having a viscosity under nonagitated condition of 85,000 to 4,385,000 cps., consisting essentially of polyacrylic ester monomer, silane treated fumed silica, and a small amount of an amine activator and a thixotropic composition having a viscosity under nonagitated condition of 85,000 to 4,385,000 cps consisting essentially of polyacrylic acid monomer, silane treated fumed silica, and peroxide catalyst, said fumed silica being present in each of said compositions in an amount of 6 to 11% by weight.
Claim 8
Dependent Claim
16 words
The method of claim 5 in which said submicron silica is a silane treated fumed silica.
Claim 9
Dependent Claim
37 words
The method of claim 6 in which the monomer content of both of the thixotropic acrylic ester monomer compositions is made up of the monomers bis-phenol A diglycidyl ether dimethacrylate, bis-phenol A dimethacrylate, and triethylene glycol dimethacrylate.
Claim 10
Dependent Claim
19 words
The method of claim 5 in which said amine activator is N,N-di(2-hydroxyethyl)-p-toluidine and said peroxide catalyst is benzoyl peroxide.
References Cited (Backward Citations)
US3250003A
Cited
US3962267A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-07 | 1980-09-06 | 1981-03-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-07 | 1984-09-06 | 1985-03-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-07 | 1988-09-06 | 1989-03-08 | $7700.00 | Window Closed / Lapsed |