Patent US4010147A successfully refreshed from Google Patents.
← Back to Patent Explorer
US4010147A Expired / Lapsed US ⏱️ 0.0 years remaining

Aromatic polymers containing ketone linking groups and process for their preparation

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1975-12-22
•
Granted: 1977-03-01
•
Expires: 1995-12-22
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A process for the preparation of aromatic polyketones and copolyketone/sulphones (ketone to sulphone content 75/25 to 100/0 having high molecular weight comprises heating dialkali metal salt of a bisphenol containing ketone linking groups with equimolar or slight molar excess of dihalobenzenoid compound having halogen atoms activated by a ketone or sulphone linking group in the presence of certain diaryl sulphones at 250 DEG to 400 DEG C.

Inventors

  • 👤 John Brewster Rose

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 11:59
CPC Classifications
C; C08; C08G; C08G75/00; C08G75/20; C08G75/23; C08G65/00; C08G65/34; C08G65/38; C08G65/40; C08G65/4012; C08G65/4093

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 227 words
A process for the preparation of aromatic polymers having reduced viscosity of between 0.8 and 3.0, as measured at 25° C on a solution of polymer in concentrated sulphuric acid of density 1.84 g/cm 3 containing 1 g of polymer in 100 cm 3 of solution, which comprises heating at a temperature of 250° to 400° C a monomer mixture comprising 1. 49 to 50% molar of a di(alkali metal) salt of at least one bisphenol of the formula ##STR21## at least 95% of the phenolic OH groups being in the para position, and 2. 51 to 50% molar at least one dihalo compound of the formula ##STR22## where Q is SO 2 or CO, X is F, Cl or Br, n is a positive integer not exceeding 3 and m is 0 or 1, and the molar percentages of said di(alkali metal) salt and said at least one dihalo compound sum to 100%, said di(alkali metal) salt being present as a suspension in a diaryl sulphone having the formula ##STR23## in which Y is a direct link, an oxygen atom or two hydrogen atoms (one attached to each benzene ring) and Z and Z' are selected from hydrogen atoms and phenyl groups and may be the same or different, the proportion of SO 2 to CO groups in the monomer mixture being not greater than 25%.
Claim 2
Dependent Claim 227 words
A process for the preparation of aromatic polymers having reduced viscosity of between 0.8 and 3.0, as measured at 25° C on a solution of polymer in concentrated sulphuric acid of density 1.84 g/cm 3 containing 1 g of polymer in 100 cm 3 of solution, which comprises heating at a temperature of 250° to 400° C a monomer mixture comprising 1. 49 to 50% molar of a di(alkali metal) salt of at least one bisphenol of the formula ##STR21## at least 95% of the phenolic OH groups being in the para position, and 2. 51 to 50% molar at least one dihalo compound of the formula ##STR22## where Q is SO 2 or CO, X is F, Cl or Br, n is a positive integer not exceeding 3 and m is 0 or 1, and the molar percentages of said di(alkali metal) salt and said at least one dihalo compound sum to 100%, said di(alkali metal) salt being present as a suspension in a diaryl sulphone having the formula ##STR23## in which Y is a direct link, an oxygen atom or two hydrogen atoms (one attached to each benzene ring) and Z and Z' are selected from hydrogen atoms and phenyl groups and may be the same or different, the proportion of SO 2 to CO groups in the monomer mixture being not greater than 25%.

References Cited (Backward Citations)

GB971227A Cited
GB1016245A Cited
GB1078234A Cited
GB1164817A Cited
GB1153527A Cited
US3442857A Cited
GB1177183A Cited
US3764583A Cited
US3795660A Cited
US3794615A Cited
US3787363A Cited
US3928295A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-02-29 1980-08-30 1981-03-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-02-29 1984-08-30 1985-03-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-02-29 1988-08-30 1989-03-01 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag