Patent US4010147A successfully refreshed from Google Patents.
US4010147A
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US
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Aromatic polymers containing ketone linking groups and process for their preparation
Assignee: Imperial Chemical Industries Ltd
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Filing: 1975-12-22
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Granted: 1977-03-01
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Expires: 1995-12-22
Abstract
Abstract A process for the preparation of aromatic polyketones and copolyketone/sulphones (ketone to sulphone content 75/25 to 100/0 having high molecular weight comprises heating dialkali metal salt of a bisphenol containing ketone linking groups with equimolar or slight molar excess of dihalobenzenoid compound having halogen atoms activated by a ketone or sulphone linking group in the presence of certain diaryl sulphones at 250 DEG to 400 DEG C.
Inventors
- 👤 John Brewster Rose
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 11:59
CPC Classifications
C; C08; C08G; C08G75/00; C08G75/20; C08G75/23; C08G65/00; C08G65/34; C08G65/38; C08G65/40; C08G65/4012; C08G65/4093
Claims Analysis
Total Claims: 2
Claim 1
Independent Claim
227 words
A process for the preparation of aromatic polymers having reduced viscosity of between 0.8 and 3.0, as measured at 25° C on a solution of polymer in concentrated sulphuric acid of density 1.84 g/cm 3 containing 1 g of polymer in 100 cm 3 of solution, which comprises heating at a temperature of 250° to 400° C a monomer mixture comprising 1. 49 to 50% molar of a di(alkali metal) salt of at least one bisphenol of the formula ##STR21## at least 95% of the phenolic OH groups being in the para position, and 2. 51 to 50% molar at least one dihalo compound of the formula ##STR22## where Q is SO 2 or CO, X is F, Cl or Br, n is a positive integer not exceeding 3 and m is 0 or 1, and the molar percentages of said di(alkali metal) salt and said at least one dihalo compound sum to 100%, said di(alkali metal) salt being present as a suspension in a diaryl sulphone having the formula ##STR23## in which Y is a direct link, an oxygen atom or two hydrogen atoms (one attached to each benzene ring) and Z and Z' are selected from hydrogen atoms and phenyl groups and may be the same or different, the proportion of SO 2 to CO groups in the monomer mixture being not greater than 25%.
Claim 2
Dependent Claim
227 words
A process for the preparation of aromatic polymers having reduced viscosity of between 0.8 and 3.0, as measured at 25° C on a solution of polymer in concentrated sulphuric acid of density 1.84 g/cm 3 containing 1 g of polymer in 100 cm 3 of solution, which comprises heating at a temperature of 250° to 400° C a monomer mixture comprising 1. 49 to 50% molar of a di(alkali metal) salt of at least one bisphenol of the formula ##STR21## at least 95% of the phenolic OH groups being in the para position, and 2. 51 to 50% molar at least one dihalo compound of the formula ##STR22## where Q is SO 2 or CO, X is F, Cl or Br, n is a positive integer not exceeding 3 and m is 0 or 1, and the molar percentages of said di(alkali metal) salt and said at least one dihalo compound sum to 100%, said di(alkali metal) salt being present as a suspension in a diaryl sulphone having the formula ##STR23## in which Y is a direct link, an oxygen atom or two hydrogen atoms (one attached to each benzene ring) and Z and Z' are selected from hydrogen atoms and phenyl groups and may be the same or different, the proportion of SO 2 to CO groups in the monomer mixture being not greater than 25%.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-02-29 | 1980-08-30 | 1981-03-01 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-02-29 | 1984-08-30 | 1985-03-01 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-02-29 | 1988-08-30 | 1989-03-01 | $7700.00 | Window Closed / Lapsed |