Patent US4009101A successfully refreshed from Google Patents.
US4009101A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Recycle treatment of waste water from nickel plating
Assignee: KYB Corp
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Filing: 1975-09-15
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Granted: 1977-02-22
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Expires: 1995-09-15
Abstract
Abstract A method for the recycle treatment of nickel plating waste water, in order to efficiently recover the nickel components from waste water which has been used for the washing of nickel plated products in a form re-usable as a nickel plating solution as such, wherein the nickel plating waste water is mixed with an aqueous alkaline component so as to remove, by precipitation in the form of hydroxides, contaminating metal ions other than nickel; the filtrate so obtained is treated through an ion exchange process so as to obtain an aqueous solution of nickel salts containing excess free sulfuric acid, a portion of which is then treated with alkali so as to precipitate nickel hydroxide which is separated in the form of nickel hydroxide through filtration by means of a centrifuge; the nickel hydroxide so obtained is then added to the rest of the aqueous nickel salt solution for neutralization with the free sulfuric acid contained therein to form nickel sulfate; and the free sulfuric acid is then removed so as to obtain a highly concentrated nickel sulfate solution.
Inventors
- 👤 Toshio Hayashi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 22:33
CPC Classifications
C; C25; C25D; C25D21/00; C25D21/16; C25D21/22; C02; C02F; C02F1/00; C02F1/66; C02F2101/00; C02F2101/10; C02F2101/20; C02F2103/00; C02F2103/16
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
235 words
A method of treating acidic nickel plating waste water for recycling to nickel plating baths, comprising the steps of; adding an alkaline substance to a body of nickel plating waste water which includes dissolved nickel and other dissolved metallic components which can be precipitated as hydroxides, so as to increase the pH of said body to a level of about 7.5 at which said other metallic components precipitate as hydroxides but at which substantially all of said nickel remains in solution; separating said waste water from the resulting precipitate; adsorbing nickel from said waste water subsequent to said separation by contacting said waste water with a cation exchange resin maintained at a pH value of about 11.5. desorbing adsorbed nickel from said resin by contacting the resin with sulfuric said thereby obtaining an acidic nickel-containing solution; dividing said solution into a first portion and a second portion; adding an alkali to said first portion to raise the pH value thereof to about 10 for precipitating nickel hydroxide from said first portion; recovering said nickel hydroxide; combining at least part of said recovered nickel hydroxide with said second portion of said solution to react with excess parts of said sulfuric acid so as to reduce the amount of free sulfuric acid in said second portion and form a nickel sulfate solution suitable for recycling to nickel plating baths; and recycling said solution to nickel plating baths.
Claim 2
Independent Claim
235 words
A method of treating acidic nickel plating waste water for recycling to nickel plating baths, comprising the steps of; adding an alkaline substance to a body of nickel plating waste water which includes dissolved nickel and other dissolved metallic components which can be precipitated as hydroxides, so as to increase the pH of said body to a level of about 7.5 at which said other metallic components precipitate as hydroxides but at which substantially all of said nickel remains in solution; separating said waste water from the resulting precipitate; adsorbing nickel from said waste water subsequent to said separation by contacting said waste water with a cation exchange resin maintained at a pH value of about 11.5. desorbing adsorbed nickel from said resin by contacting the resin with sulfuric said thereby obtaining an acidic nickel-containing solution; dividing said solution into a first portion and a second portion; adding an alkali to said first portion to raise the pH value thereof to about 10 for precipitating nickel hydroxide from said first portion; recovering said nickel hydroxide; combining at least part of said recovered nickel hydroxide with said second portion of said solution to react with excess parts of said sulfuric acid so as to reduce the amount of free sulfuric acid in said second portion and form a nickel sulfate solution suitable for recycling to nickel plating baths; and recycling said solution to nickel plating baths.
Claim 3
Dependent Claim
16 words
A method as defined in claim 1, wherein said separation and said recovery each comprise filtration.
Claim 4
Dependent Claim
129 words
A method as defined in claim 1, said resin comprising an H type cation exchange resin, and said adsorption and desorption respectively comprising passing said waste water and said sulfuric acid over said resin in a predetermined flow direction; and wherein regeneration of said resin is substantially completed subsequent to said desorption by passing a first quantity of water over said resin in said predetermined flow direction so as to remove nickel remaining in said resin, subsequently passing an alkaline solution over said resin in said predetermined flow direction so as to raise the pH value of said resin to about 12, and thereafter passing a second quantity of water over said resin countercurrently to said predetermined flow direction so as to remove excess alkalinity remaining in said resin.
Claim 5
Dependent Claim
59 words
A method as defined in claim 3, said first quantity of water having a volume which is less than about 5 times the volume of said resin and said second quantity of water having a volume which approximately equals the volume of said resin; and wherein said resin is stirred during passage of said second quantity of water thereover.
Claim 6
Independent Claim
242 words
A method of treating acidic nickel plating waste water for recycling to nickel plating baths, comprising the steps of; adding an alkaline substance to a body of nickel plating waste water which includes dissolved nickel and other dissolved metallic components which can be precipitated as hydroxides so as to increase the ph of said body to a level of about 7.5 at which said other metallic components precipitate while substantially all of said nickel remains in solution; separating the nickel containing waste water from the resulting precipitate; dividing the nickel containing waste water into a first portion and a second portion subsequent to said separation; adsorbing nickel from said first portion of said waste water by contacting said first portion of said waste water with a cation exchange resin maintained at a pH value of about 11.5; desorbing adsorbed nickel from said resin by contacting the resin with sulfuric acid thereby obtaining an acid nickel-containing solution; treating said second portion with alkali for precipitating nickel hydroxide from said second adding an alkali to said second portion to raise the pH value thereof to about 10 for; recovering said nickel hydroxide; combining at least part of said nickel hydroxide with said solution to react with excess sulfuric acid in said solution so as to reduce the amount of free sulfuric acid therein and form a nickel sulfate solution suitable for recycling to nickel plating baths; and recycling said solution to nickel plating baths.
Claim 7
Independent Claim
242 words
A method of treating acidic nickel plating waste water for recycling to nickel plating baths, comprising the steps of; adding an alkaline substance to a body of nickel plating waste water which includes dissolved nickel and other dissolved metallic components which can be precipitated as hydroxides so as to increase the ph of said body to a level of about 7.5 at which said other metallic components precipitate while substantially all of said nickel remains in solution; separating the nickel containing waste water from the resulting precipitate; dividing the nickel containing waste water into a first portion and a second portion subsequent to said separation; adsorbing nickel from said first portion of said waste water by contacting said first portion of said waste water with a cation exchange resin maintained at a pH value of about 11.5; desorbing adsorbed nickel from said resin by contacting the resin with sulfuric acid thereby obtaining an acid nickel-containing solution; treating said second portion with alkali for precipitating nickel hydroxide from said second adding an alkali to said second portion to raise the pH value thereof to about 10 for; recovering said nickel hydroxide; combining at least part of said nickel hydroxide with said solution to react with excess sulfuric acid in said solution so as to reduce the amount of free sulfuric acid therein and form a nickel sulfate solution suitable for recycling to nickel plating baths; and recycling said solution to nickel plating baths.
Claim 8
Dependent Claim
16 words
A method as defined in claim 5, wherein said separation and said recovery each comprise filtration.
Claim 9
Dependent Claim
131 words
A method as defined in claim 5, said resin comprising an H type resin, and said adsorption and desorption respectively comprising passing said first portion of said waste water and said sulfuric acid over said resin in a predetermined flow direction; and wherein regeneration of said resin is substantially completed subsequent to said desorption by passing a first quantity of water over said resin in said predetermined flow direction so as to remove nickel remaining in said resin, subsequently passing an alkaline solution over said resin in said predetermined flow direction so as to raise the pH value of said resin to about 12, and thereafter passing a second quantity of water over said resin countercurrently to said predetermined flow direction so as to remove excess alkalinity remaining in said resin.
Claim 10
Dependent Claim
59 words
A method as defined in claim 7, said first quantity of water having a volume which is less than about 5 times the volume of said resin and said second quantity of water having a volume which approximately equals the volume of said resin; and wherein said resin is stirred during passage of said second quantity of water thereover.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-02-22 | 1980-08-23 | 1981-02-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-02-22 | 1984-08-23 | 1985-02-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-02-22 | 1988-08-23 | 1989-02-22 | $7700.00 | Window Closed / Lapsed |