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US4009083A Expired / Lapsed US ⏱️ 0.0 years remaining

Regeneration of liquid desiccants and acid gas absorbing liquid desiccants

Assignee: Dow Chemical Co
•
Filing: 1975-06-23
•
Granted: 1977-02-22
•
Expires: 1995-06-23
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Abstract

Abstract This invention relates to the low temperature regeneration of liquid desiccants and acid gas absorbing liquid desiccants. Both classes of desiccants can be regenerated to separate water and/or water and acid gases to a satifactory degree under the pressure conditions employed at temperatures substantially below the normal boiling point of the dry desiccant or desiccant-water mixture by countercurrently contacting the desiccant to be regenerated in conventional distillation equipment with the vapors of an easily condensable hydrocarbon or hydrocarbon mixture which is substantially immiscible with the regenerated desiccant at the boiling temperature of the hydrocarbon or hydrocarbon mixture employed as a stripping agent.

Inventors

  • 👤 George W. Lyon
  • 👤 Roscoe L. Pearce

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 16:24
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/26; B01D53/263; B01D3/00; B01D3/34; B01D3/343; B01D53/14; B01D53/1425; Y; Y10; Y10S; Y10S159/00; Y10S159/33

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 195 words
In a method of regenerating liquid desiccants or acid gas absorbing liquid desiccants or mixtures thereof, the steps comprising, feeding a rich liquid absorbent into an upper portion of a regeneration column, vaporizing by heat a normally liquid hydrocarbon or mixture of hydrocarbons substantially insoluble in the dried desiccant and in water, which hydrocarbon has a boiling temperature below the upper and above the lower critical solution temperatures of the mixture of the desiccant and the said hydrocarbon under the pressure conditions employed, passing the vapors upwardly through the rich liquid absorbent, said vapors being the sole source of heat added for regeneration of the desiccant, condensing overhead vapors from the regenerator out of direct contact with the rich liquid absorbent, separating liquid hydrocarbon from water, and returning at least a portion of the overhead hydrocarbon condensate to the regeneration column as reflux, passing a two phase liquid mixture from the regenerator into a separator to form a lean desiccant phase and a liquid hydrocarbon phase, passing the hydrocarbon phase into a vaporizer wherein the hydrocarbon phase is heated and vaporized for recycle to the regenerator, and removing the lean desiccant phase from the separator.
Claim 2
Dependent Claim 195 words
In a method of regenerating liquid desiccants or acid gas absorbing liquid desiccants or mixtures thereof, the steps comprising, feeding a rich liquid absorbent into an upper portion of a regeneration column, vaporizing by heat a normally liquid hydrocarbon or mixture of hydrocarbons substantially insoluble in the dried desiccant and in water, which hydrocarbon has a boiling temperature below the upper and above the lower critical solution temperatures of the mixture of the desiccant and the said hydrocarbon under the pressure conditions employed, passing the vapors upwardly through the rich liquid absorbent, said vapors being the sole source of heat added for regeneration of the desiccant, condensing overhead vapors from the regenerator out of direct contact with the rich liquid absorbent, separating liquid hydrocarbon from water, and returning at least a portion of the overhead hydrocarbon condensate to the regeneration column as reflux, passing a two phase liquid mixture from the regenerator into a separator to form a lean desiccant phase and a liquid hydrocarbon phase, passing the hydrocarbon phase into a vaporizer wherein the hydrocarbon phase is heated and vaporized for recycle to the regenerator, and removing the lean desiccant phase from the separator.
Claim 3
Dependent Claim 11 words
The method of claim 1 in which the hydrocarbon is n-octane.
Claim 4
Dependent Claim 13 words
The method of claim 1 in which the hydrocarbon is a light naphtha.
Claim 5
Dependent Claim 13 words
The method of claim 1 in which the hydrocarbon is a heavy naphtha.
Claim 6
Dependent Claim 12 words
The method of claim 1 in which the absorbent is a glycol.
Claim 7
Dependent Claim 11 words
The method of claim 1 in which the absorbent is diglycolamine.
Claim 8
Dependent Claim 11 words
The method of claim 1 in which the absorbent is diethanolamine.
Claim 9
Dependent Claim 44 words
The method of claim 1 in which the hydrocarbon is aliphatic and boils in a range of from about 65° C to about 235° C at atmospheric pressure but not in excess of the decomposition temperature of the least stable compound in the desiccant.
Claim 10
Dependent Claim 12 words
The method of claim 8 in which the absorbent contains N-methyl pyrrolidone.
Claim 11
Dependent Claim 11 words
The method of claim 8 in which the absorbent contains sulfolane.
Claim 12
Dependent Claim 16 words
The method of claim 8 in which the glycol contains from 2 to 12 carbon atoms.
Claim 13
Dependent Claim 12 words
The method of claim 11 in which the glycol is triethylene glycol.
Claim 14
Dependent Claim 20 words
The method of claim 1 in which the hydrocarbon is aromatic having a boiling range of 80° to 235° C.
Claim 15
Dependent Claim 11 words
The method of claim 13 in which the hydrocarbon is xylene.
Claim 16
Dependent Claim 11 words
The method of claim 13 in which the hydrocarbon is toluene.
Claim 17
Dependent Claim 11 words
The method of claim 13 in which the hydrocarbon is benzene.
Claim 18
Dependent Claim 17 words
The method of claim 1 in which the hydrocarbon is a mixture of aliphatic and aromatic hydrocarbons.
Claim 19
Dependent Claim 13 words
The method of claim 17 in which the mixture is n-octane and benzene.
Claim 20
Dependent Claim 29 words
The method of claim 1 in which the absorbent is a mixture of a glycol of 2-12 carbon atoms and an alkanolamine having from 2 to 9 carbon atoms.
Claim 21
Dependent Claim 17 words
The method of claim 19 in which the glycol is triethylene glycol and the alkanolamine is diethanolamine.
Claim 22
Dependent Claim 41 words
The method of claim 19 in which the absorbent undergoing regeneration is an alkanolamine-acid gas mixture, in which the acid gas is at least one of CO 2 , H 2 S, low molecular weight mercaptans, COS, or CS 2 .
Claim 23
Dependent Claim 15 words
The method of claim 21 in which the absorbed acid gas is CO 2 .
Claim 24
Dependent Claim 15 words
The method of claim 21 in which the absorbed acid gas is H 2 S.
Claim 25
Dependent Claim 18 words
The method of claim 1 in which the pressure of regeneration ranges from autogenous to about 350 psia.
Claim 26
Dependent Claim 12 words
The method of claim 24 in which the regeneration pressure is autogenous.

References Cited (Backward Citations)

US2529622A Cited
US2603311A Cited
US3321890A Cited
US3349544A Cited
US3471370A Cited
US3658656A Cited
US3589104A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-02-22 1980-08-23 1981-02-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-02-22 1984-08-23 1985-02-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-02-22 1988-08-23 1989-02-22 $7700.00 Window Closed / Lapsed

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