US4008192A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Polyisocyanates blocked with hydroxamic acid esters or acyl hydroxamates
Assignee: Akzo NV
•
Filing: 1975-11-28
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Granted: 1977-02-15
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Expires: 1995-11-28
Abstract
Abstract A thermosetting coating composition contains a polyisocyanate blocked with a hydroxamic acid ester or an acyl hydroxamate. The polyisocyanate in the coating composition may be activated by dissociation of the blocking agent and polyisocyanate at a lower temperature than the blocked polyisocyanate of conventional coating compositions.
Inventors
- 👤 Willem Jacobus Mijs
- 👤 Johan Bernard Reesink
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 06:34
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/70; C08G18/72; C08G18/80; C08G18/8061; C08G18/807; C08G18/28; C08G18/40; C08G18/54; C08G18/62; C08G18/6216; C08G18/622; C08G18/6225; C08G18/6229; C08G18/81; C08G18/8141; C08G18/815; C08G18/8158
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
31 words
A process for the preparation of thermosetting coating compositions comprising incorporating in a polymer having free hydroxyl groups an organic polyisocyanate blocked with a hydroxamic acid ester or an acyl hydroxamate.
Claim 2
Dependent Claim
31 words
A process for the preparation of thermosetting coating compositions comprising incorporating in a polymer having free hydroxyl groups an organic polyisocyanate blocked with a hydroxamic acid ester or an acyl hydroxamate.
Claim 3
Dependent Claim
41 words
The process of claim 1 wherein the polyisocyanate is blocked with a compound which corresponds to the structural formula ##STR2## where n=0 or 1 and R 1 and R 2 each represent a hydrocarbon group containing 1 to 20 carbon atoms.
Claim 4
Dependent Claim
19 words
The process of claim 2, wherein R 1 represents an alkenyl group containing no more than 6 carbon atoms.
Claim 5
Dependent Claim
14 words
The process of claim 2 wherein n=0 and R 2 is a benzyl group.
Claim 6
Dependent Claim
14 words
The process of claim 2 wherein n=1 and R 2 is a phenyl group.
Claim 7
Dependent Claim
16 words
The process of claim 2 wherein R 2 is an alkenyl group or an aralkenyl group.
Claim 8
Dependent Claim
23 words
The process of claim 3 wherein the coating composition contains a radical initiator which is active at a temperature below about 130° C.
Claim 9
Dependent Claim
16 words
The process of claim 1 wherein the polyisocyanate contains only aliphatically or cycloaliphatically bonded isocyanate groups.
Claim 10
Dependent Claim
20 words
The process of claim 8 wherein the polyisocyanate consists essentially of tri(isocyanatohexyl)-biuret formed by reaction of hexamethylene diisocyanate with water.
Claim 11
Dependent Claim
20 words
The process of claim 1 wherein the coating composition contains an alcohol having a molecular weight of less than 200.
Claim 12
Dependent Claim
17 words
The process of claim 1 wherein the coating composition contains a catalytic amount of a zinc compound.
Claim 13
Dependent Claim
37 words
The process of claim 11 wherein the amount of zinc included in the coating composition is about 0.1 to 0.2 molar equivalents of the number of free OH groups or blocked isocyanate groups present in the coating.
Claim 14
Dependent Claim
22 words
The process of claim 11 wherein the zinc compound is a salt of an organic acid containing 2 to 20 carbon atoms.
Claim 15
Dependent Claim
14 words
The process of claim 2 wherein n=0 and R 2 is an allyl group.
Claim 16
Dependent Claim
8 words
The product of the process of claim 1.
References Cited (Backward Citations)
US2882260A
Cited
US3499852A
Cited
US3694389A
Cited
US3748315A
Cited
US3926875A
Cited
US3867347A
Cited
US3931117A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-02-15 | 1980-08-16 | 1981-02-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-02-15 | 1984-08-16 | 1985-02-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-02-15 | 1988-08-16 | 1989-02-15 | $7700.00 | Window Closed / Lapsed |