Abstract Coatings produced from compositions comprising: 40 - 70 percent by weight of cyclized rubber in 60 - 30 percent by weight of a binder mixture wherein the binder mixture comprises: I. about 10 - 50 percent by weight of a non-heat reactive phenol-aldehyde resin; and Ii. about 50 - 90 percent by weight of a copolymer, said copolymer comprising: A. about 50 - 85 percent by weight of an ester of methacrylic acid or acrylic acid with an alcohol having 1 - 10 carbon atoms; B. about 5 - 20 percent by weight of drying oils or drying oil fatty acids containing olefinically unsaturated fatty acids; C. about 5 - 15 percent by weight of an α,β-olefinically unsaturated carboxylic acid having 3 - 5 carbon atoms; D. about 3 - 20 percent by weight of methacrylamide, acrylamide, methylol methacrylamide, methylol acrylamide, an ether of methylol methacrylamide with an alcohol having 1 - 8 carbon atoms, an ether of methylol acrylamide having 1 - 8 carbon atoms or a mixture thereof, and optionally E. up to 20 percent by weight of further copolymerizable olefinically unsaturated compounds.
Coatings on electrically conductive bases produced by connecting said bases as the anode and dipping them into a liquid aqueous coating composition containing: I. about 10 - 50 percent by weight of a non-heat reactive phenol-aldehyde resin; and Ii. about 50 - 90 percent by weight of a copolymer acrylic resin, said copolymer resin containing sufficient water-soluble amine compound to impart anionic polyelectrolyte behavior, said copolymer acrylic resin comprising: a. about 50 - 85 percent by weight of an ester of acrylic acid or methacrylic acid with an alcohol having 1 - 10 carbon atoms; b. about 5 - 20 percent by weight of a compound selected from the group consisting of drying oil or drying oil fatty acids containing olefinically unsaturated acids; c. about 5 - 15 percent by weight of an α,β-olefinically unsaturated carboxylic acid having 3 - 5 carbon atoms; and d. about 3 - 20 percent by weight of an amide selected from the group consisting of acrylamide, methacrylamide, methylol acrylamide, methylol methacrylamide, an ether of methylol acrylamide with an alcohol having 1 - 8 carbon atoms, an ether of methylol methacrylamide with an alcohol having 1 - 8 carbon atoms and mixtures thereof, the improvement comprising, dispersing additionally in said liquid aqueous coating composition a solution of cyclized rubber, the ratio of weight between cyclized rubber and the weight of said coating composition of I and II being from about 40 - 70 percent cyclized rubber to about 30 - 60 percent coating composition of I and II and air drying the electrodeposited coating at a temperature between about room temperature and 85° C, said cyclized rubber having a specific gravity of about 0.97 - 1.02, a melting point of about 135° - 150° C and a viscosity of about 700 - 1050 seconds as measured in a viscosimeter at 50 percent solution of analytical benzene according to German Industrial Standard 53,211.
Claim 2
Dependent Claim
317 words
Coatings on electrically conductive bases produced by connecting said bases as the anode and dipping them into a liquid aqueous coating composition containing: I. about 10 - 50 percent by weight of a non-heat reactive phenol-aldehyde resin; and Ii. about 50 - 90 percent by weight of a copolymer acrylic resin, said copolymer resin containing sufficient water-soluble amine compound to impart anionic polyelectrolyte behavior, said copolymer acrylic resin comprising: a. about 50 - 85 percent by weight of an ester of acrylic acid or methacrylic acid with an alcohol having 1 - 10 carbon atoms; b. about 5 - 20 percent by weight of a compound selected from the group consisting of drying oil or drying oil fatty acids containing olefinically unsaturated acids; c. about 5 - 15 percent by weight of an α,β-olefinically unsaturated carboxylic acid having 3 - 5 carbon atoms; and d. about 3 - 20 percent by weight of an amide selected from the group consisting of acrylamide, methacrylamide, methylol acrylamide, methylol methacrylamide, an ether of methylol acrylamide with an alcohol having 1 - 8 carbon atoms, an ether of methylol methacrylamide with an alcohol having 1 - 8 carbon atoms and mixtures thereof, the improvement comprising, dispersing additionally in said liquid aqueous coating composition a solution of cyclized rubber, the ratio of weight between cyclized rubber and the weight of said coating composition of I and II being from about 40 - 70 percent cyclized rubber to about 30 - 60 percent coating composition of I and II and air drying the electrodeposited coating at a temperature between about room temperature and 85° C, said cyclized rubber having a specific gravity of about 0.97 - 1.02, a melting point of about 135° - 150° C and a viscosity of about 700 - 1050 seconds as measured in a viscosimeter at 50 percent solution of analytical benzene according to German Industrial Standard 53,211.
Claim 3
Dependent Claim
11 words
The coatings of claim 1, air dried at about room temperature.