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US4008140A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrodeposited coatings

Assignee: Glasurit Werke M Winkelmann GmbH
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Filing: 1973-08-20
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Granted: 1977-02-15
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Expires: 1993-08-20
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Abstract

Abstract Coatings produced from compositions comprising: 40 - 70 percent by weight of cyclized rubber in 60 - 30 percent by weight of a binder mixture wherein the binder mixture comprises: I. about 10 - 50 percent by weight of a non-heat reactive phenol-aldehyde resin; and Ii. about 50 - 90 percent by weight of a copolymer, said copolymer comprising: A. about 50 - 85 percent by weight of an ester of methacrylic acid or acrylic acid with an alcohol having 1 - 10 carbon atoms; B. about 5 - 20 percent by weight of drying oils or drying oil fatty acids containing olefinically unsaturated fatty acids; C. about 5 - 15 percent by weight of an α,β-olefinically unsaturated carboxylic acid having 3 - 5 carbon atoms; D. about 3 - 20 percent by weight of methacrylamide, acrylamide, methylol methacrylamide, methylol acrylamide, an ether of methylol methacrylamide with an alcohol having 1 - 8 carbon atoms, an ether of methylol acrylamide having 1 - 8 carbon atoms or a mixture thereof, and optionally E. up to 20 percent by weight of further copolymerizable olefinically unsaturated compounds.

Inventors

  • 👤 Peter Fritsche

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 20:34
CPC Classifications
C; C09; C09D; C09D5/00; C09D5/44; C09D5/4473; C09D133/00; C09D133/04; C09D133/06; C09D133/062; C09D133/064; C08; C08L; C08L15/00; C08L61/00; C08L61/04; C08L61/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31699

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 317 words
Coatings on electrically conductive bases produced by connecting said bases as the anode and dipping them into a liquid aqueous coating composition containing: I. about 10 - 50 percent by weight of a non-heat reactive phenol-aldehyde resin; and Ii. about 50 - 90 percent by weight of a copolymer acrylic resin, said copolymer resin containing sufficient water-soluble amine compound to impart anionic polyelectrolyte behavior, said copolymer acrylic resin comprising: a. about 50 - 85 percent by weight of an ester of acrylic acid or methacrylic acid with an alcohol having 1 - 10 carbon atoms; b. about 5 - 20 percent by weight of a compound selected from the group consisting of drying oil or drying oil fatty acids containing olefinically unsaturated acids; c. about 5 - 15 percent by weight of an α,β-olefinically unsaturated carboxylic acid having 3 - 5 carbon atoms; and d. about 3 - 20 percent by weight of an amide selected from the group consisting of acrylamide, methacrylamide, methylol acrylamide, methylol methacrylamide, an ether of methylol acrylamide with an alcohol having 1 - 8 carbon atoms, an ether of methylol methacrylamide with an alcohol having 1 - 8 carbon atoms and mixtures thereof, the improvement comprising, dispersing additionally in said liquid aqueous coating composition a solution of cyclized rubber, the ratio of weight between cyclized rubber and the weight of said coating composition of I and II being from about 40 - 70 percent cyclized rubber to about 30 - 60 percent coating composition of I and II and air drying the electrodeposited coating at a temperature between about room temperature and 85° C, said cyclized rubber having a specific gravity of about 0.97 - 1.02, a melting point of about 135° - 150° C and a viscosity of about 700 - 1050 seconds as measured in a viscosimeter at 50 percent solution of analytical benzene according to German Industrial Standard 53,211.
Claim 2
Dependent Claim 317 words
Coatings on electrically conductive bases produced by connecting said bases as the anode and dipping them into a liquid aqueous coating composition containing: I. about 10 - 50 percent by weight of a non-heat reactive phenol-aldehyde resin; and Ii. about 50 - 90 percent by weight of a copolymer acrylic resin, said copolymer resin containing sufficient water-soluble amine compound to impart anionic polyelectrolyte behavior, said copolymer acrylic resin comprising: a. about 50 - 85 percent by weight of an ester of acrylic acid or methacrylic acid with an alcohol having 1 - 10 carbon atoms; b. about 5 - 20 percent by weight of a compound selected from the group consisting of drying oil or drying oil fatty acids containing olefinically unsaturated acids; c. about 5 - 15 percent by weight of an α,β-olefinically unsaturated carboxylic acid having 3 - 5 carbon atoms; and d. about 3 - 20 percent by weight of an amide selected from the group consisting of acrylamide, methacrylamide, methylol acrylamide, methylol methacrylamide, an ether of methylol acrylamide with an alcohol having 1 - 8 carbon atoms, an ether of methylol methacrylamide with an alcohol having 1 - 8 carbon atoms and mixtures thereof, the improvement comprising, dispersing additionally in said liquid aqueous coating composition a solution of cyclized rubber, the ratio of weight between cyclized rubber and the weight of said coating composition of I and II being from about 40 - 70 percent cyclized rubber to about 30 - 60 percent coating composition of I and II and air drying the electrodeposited coating at a temperature between about room temperature and 85° C, said cyclized rubber having a specific gravity of about 0.97 - 1.02, a melting point of about 135° - 150° C and a viscosity of about 700 - 1050 seconds as measured in a viscosimeter at 50 percent solution of analytical benzene according to German Industrial Standard 53,211.
Claim 3
Dependent Claim 11 words
The coatings of claim 1, air dried at about room temperature.

References Cited (Backward Citations)

US3455805A Cited
US3677984A Cited
US3679618A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-02-15 1980-08-16 1981-02-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-02-15 1984-08-16 1985-02-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-02-15 1988-08-16 1989-02-15 $7700.00 Window Closed / Lapsed

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