Photosensitive material containing an organic polyhalogen compound and a dye precursor and the use thereof

Claim 2

A photographic process wherein a visible image is formed in a recording material, which contains in intimate admixture an image-forming system consisting essentially of: 1. at least one ultra-violet radiation-sensitive organic polyhalogen compound corresponding to the following general formula: ##STR21## wherein: each of A, B, X and Y are halogen atoms of the group of chlorine, bromine, or iodine, or wherein one of said groups A, B, X or Y represents an alkyl group, an aryl group or an aroyl group and the other groups chlorine, bromine, or iodine, and 2.

Claim 3

a dye precursor compound corresponding to the following general formula: ##STR22## wherein: R 1 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group being an ether group R 6 --O-- in which R 6 represents a hydrocarbon group, or (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus, R 2 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group, being an ether group R 6 --O--, in which R 6 represents a hydrocarbon group, (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus, or (3) a ##STR23## group in which Z represents the necessary atoms to close a 5-membered nitrogen containing heterocyclic nucleus, R 3 represents (1) a --XH or --X--R 7 group, in which X is oxygen and R 7 is an alkyl group, or (2) a ##STR24## group wherein each of R 8 and R 9 (same or different) represents hydrogen or an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group or R 8 and R 9 together represent the necessary atoms to close a 5- or 6-membered nitrogen-containing heterocyclic nucleus, each of R 4 and R 5 (same or different) represents hydrogen, a C 1 --C 5 alkyl group, a cycloalkyl group, an aralkyl group or an aryl group, n is 0 or 1, and m is 0, said visible image being formed (A) by the step of: information-wise exposing the recording material to activating electromagnetic radiation of a dose sufficient to bring about a directly visible image, or (B) by the steps of: information-wise exposing the recording material to activating electromagnetic radiation of a dose sufficient to bring about a latent or barely visible image, the image portions of which have a spectral sensitivity in a wavelength range outside the inherent sensitivity range of the ultraviolet radiation-sensitive polyhalogen compound, and overall exposing the image-wise exposed recording material to light within the wavelength range for which the initially exposed portions are made more sensitive than the initially non-exposed portions, thereby bringing about the formation of a visible image corresponding with the initially information-wise exposed portions, or (C) by the steps of: overall exposing the recording material to electromagnetic radiation of a dose sufficient to bring about in the recording material an increase in spectral sensitivity in a wavelength range outside the inherent sensitivity range of the ultra-violet radiation-sensitive polyhalogen compound, and information-wise exposing the thus overall exposed recording material within the wavelength range for which the overall exposed

Claim 4

a dye precursor compound corresponding to the following general formula: ##STR22## wherein: R 1 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group being an ether group R 6 --O-- in which R 6 represents a hydrocarbon group, or (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus, R 2 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group, being an ether group R 6 --O--, in which R 6 represents a hydrocarbon group, (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus, or (3) a ##STR23## group in which Z represents the necessary atoms to close a 5-membered nitrogen containing heterocyclic nucleus, R 3 represents (1) a --XH or --X--R 7 group, in which X is oxygen and R 7 is an alkyl group, or (2) a ##STR24## group wherein each of R 8 and R 9 (same or different) represents hydrogen or an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group or R 8 and R 9 together represent the necessary atoms to close a 5- or 6-membered nitrogen-containing heterocyclic nucleus, each of R 4 and R 5 (same or different) represents hydrogen, a C 1 --C 5 alkyl group, a cycloalkyl group, an aralkyl group or an aryl group, n is 0 or 1, and m is 0, said visible image being formed (A) by the step of: information-wise exposing the recording material to activating electromagnetic radiation of a dose sufficient to bring about a directly visible image, or (B) by the steps of: information-wise exposing the recording material to activating electromagnetic radiation of a dose sufficient to bring about a latent or barely visible image, the image portions of which have a spectral sensitivity in a wavelength range outside the inherent sensitivity range of the ultraviolet radiation-sensitive polyhalogen compound, and overall exposing the image-wise exposed recording material to light within the wavelength range for which the initially exposed portions are made more sensitive than the initially non-exposed portions, thereby bringing about the formation of a visible image corresponding with the initially information-wise exposed portions, or (C) by the steps of: overall exposing the recording material to electromagnetic radiation of a dose sufficient to bring about in the recording material an increase in spectral sensitivity in a wavelength range outside the inherent sensitivity range of the ultra-violet radiation-sensitive polyhalogen compound, and information-wise exposing the thus overall exposed recording material within the wavelength range for which the overall exposed

Claim 5

portions of the recording material are made more sensitive. 2. A photographic process according to claim 1, wherein the recording material after the formation of a visible image is overall heated to bring about image stabilisation.

Claim 6

A photographic process according to claim 1, wherein R 1 and/or R 2 represent a methoxy substituted phenyl group.

Claim 7

A photographic process according to claim 1, wherein R 1 and/or R 2 (same or different) represent an indolyl, pyrryl, thienyl, furyl carbazolyl or indolizinyl group including such groups in substituted form.

Claim 8

A photographic process according to claim 1, wherein R 3 represents a N-piperidinyl or N-morpholinyl group.

Claim 9

A process according to claim 1, wherein said ultraviolet radiation-sensitive compound is carbon tetrabromide or iodoform.

Claim 10

A process according to claim 1, wherein in the recording material a mixture of carbon tetrabromide and iodoform is used.

Claim 11

A process according to claim 1, wherein in the recording material in combination with said mixture as anti-fogging agent a triaryl compound of a group V element and/or a sterically hindered phenol is used.

Claim 12

A process according to claim 1, wherein the mixture is used in one or more binding agents, selected from the group of polymers and copolymers comprising styrene, vinyl acetate, acrylonitrile, acrylic acid ester, methacrylic acid ester, N-vinylcarbazole or butadiene units, a hydrophobic cellulose derivative, a phenoxy resin or a polycondensate of the polyester type including a polycarbonate resin.

Claim 13

A process according to claim 1, wherein the exposure is a direct exposure.

Claim 14

A photosensitive recording material that is capable of producing directly a visible image as a result of an image-wise exposure to activating electromagnetic radiation and which contains in intimate admixture an image-forming system consisting essentially of: 1. at least one ultra-violet radiation-sensitive organic polyhalogen compound corresponding to the following general formula: ##STR25## wherein: each of A, B, X, and Y are halogen atoms of the group of chlorine, bromine, or iodine, or wherein one of said groups A, B, X or Y represents an alkyl group, an aryl group or an aroyl group and the other groups chlorine, bromine, or iodine, and

Claim 15

A photosensitive recording material that is capable of producing directly a visible image as a result of an image-wise exposure to activating electromagnetic radiation and which contains in intimate admixture an image-forming system consisting essentially of: 1. at least one ultra-violet radiation-sensitive organic polyhalogen compound corresponding to the following general formula: ##STR25## wherein: each of A, B, X, and Y are halogen atoms of the group of chlorine, bromine, or iodine, or wherein one of said groups A, B, X or Y represents an alkyl group, an aryl group or an aroyl group and the other groups chlorine, bromine, or iodine, and

Claim 16

a dye precursor compound corresponding to the following general formula: ##STR26## wherein: R 1 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group being an ether group R 6 --O-- in which R 6 represents a hydrocarbon group or (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus, R 2 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group, being an ether group R 6 --O--, in which R 6 represents a hydrocarbon group, (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus or (3) a ##STR27## group in which Z represents the necessary atoms to close a 5-membered nitrogen-containing heterocyclic nucleus, R 3 represents (1) a --XH or --X--R 7 group, in which X is oxygen and R 7 is an alkyl group, (2) a ##STR28## group wherein each of R 8 and R 9 (same or different) represents hydrogen or an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group or R 8 and R 9 together represent the necessary atoms to close a 5- or 6-membered nitrogen-containing heterocyclic nucleus, each of R 4 and R 5 (same or different) represents hydrogen, a C 1 --C 5 alkyl group, a cycloalkyl group, an aralkyl group or an aryl group, n is 0 or 1, and m is 0.

Claim 17

a dye precursor compound corresponding to the following general formula: ##STR26## wherein: R 1 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group being an ether group R 6 --O-- in which R 6 represents a hydrocarbon group or (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus, R 2 represents (1) a substituted aryl group, at least one substituent of the substituted aryl group, being an ether group R 6 --O--, in which R 6 represents a hydrocarbon group, (2) a heterocyclic group containing a 5-membered nitrogen-containing heterocyclic nucleus or (3) a ##STR27## group in which Z represents the necessary atoms to close a 5-membered nitrogen-containing heterocyclic nucleus, R 3 represents (1) a --XH or --X--R 7 group, in which X is oxygen and R 7 is an alkyl group, (2) a ##STR28## group wherein each of R 8 and R 9 (same or different) represents hydrogen or an alkyl group, a cycloalkyl group, an aralkyl group, or an aryl group or R 8 and R 9 together represent the necessary atoms to close a 5- or 6-membered nitrogen-containing heterocyclic nucleus, each of R 4 and R 5 (same or different) represents hydrogen, a C 1 --C 5 alkyl group, a cycloalkyl group, an aralkyl group or an aryl group, n is 0 or 1, and m is 0.

Claim 18

A photosensitive recording material according to claim 11, wherein R 1 and/or R 2 represent a methoxy-substituted phenyl group.

Claim 19

A photosensitive recording material according to claim 11, wherein R 1 and/or R 2 (same or different) represent an indolyl, a pyrryl, a thienyl, a furyl, a carbazolyl or an indolizinyl group.

Claim 20

A photosensitive recording material according to claim 11, wherein R 3 is a N-piperidinyl group or a N-morpholinyl group.

Claim 21

A photosensitive recording material according to claim 11, wherein said ultraviolet radiation-sensitive compound is carbon tetrabromide or iodoform.

Claim 22

A photosensitive recording material according to claim 11, wherein the recording material contains a mixture of carbon tetrabromide and iodoform.

Claim 23

A photosensitive recording material according to claim 11, wherein the mixture is present in a binder layer.

Claim 24

A photosensitive recording material according to claim 17, wherein said material contains in a layer said mixture and poly-N-vinylcarbazole or a copolymer containing N-vinyl carbazole units as sole binding agent.

Claim 25

A photosensitive recording material according to claim 11, containing as antifogging agent a triaryl compound of a group V element and/or a sterically hindered phenol.