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US4005472A Expired / Lapsed US ⏱️ 0.0 years remaining

Method for gold plating of metallic layers on semiconductive devices

Assignee: National Semiconductor Corp
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Filing: 1975-05-19
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Granted: 1977-01-25
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Expires: 1995-05-19
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Abstract

Abstract An integrated circuit semiconductive device has a plurality of copper gang bonding bumps formed on the upper surface thereof. The bumps rise substantially above the surface of the semiconductive device and serve to make electrical connection to a pattern of intraconnect metallization formed on the semiconductive device for making electrical contact to various regions within the semiconductive body of the integrated circuit. The gang bonding bumps are to be thermal compression bonded to metallic leads by an automatic bonding machine. As a final step to the processing of the semiconductive wafers, containing the individual semiconductive devices, the wafers are immersed in an immersion gold plating solution for plating an antioxidant protective coating of gold of a thickness less than 6000 angstroms onto the copper gang bonding bumps to prevent oxidation thereof either before or during the gang bonding step. The thickness of such gold antioxidant coating permitting thermal compression bonding therethrough to the underlying metal layer.

Inventors

  • 👤 James M. Harris
  • 👤 William M. Gouin

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-28 15:12
CPC Classifications
H; H10; H10W; H10W72/00; H10W72/01; H10W72/012; H10P; H10P14/00; H10P14/40; H10P14/46; H10W72/20; H10W72/251; H10W72/90; H10W72/951; H10W72/952

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 215 words
In a method for gold plating of an integrated circuit semiconductive device, of the type which includes a plurality of exposed copper thermal compression gang bonding bumps rising above the passivated surface of the semiconductive device and being connected at their bases to an underlying pattern of interconnect metallization, for providing an antioxidant coating of gold on the exposed copper gang bonding bumps without plating of gold nonmetallic portions of the device, the steps of: applying as a final plating step an immersion gold plating solution to both the exposed copper gang bonding bumps and nonmetallic surface portions of the semiconductive device for plating out of the immersion gold plating solution by a process of oxidation-reduction reaction using the differences inherent in the electropotentials of the gold and the copper of the gang bonding bumps to be plated as the driving force for selectively plating the gold directly onto the copper gang bonding bumps; and maintaining the copper gang bumps in contact with the immersion plating solution only so long as to plate gold onto the copper gang bonding bumps to a thickness less than 6000 angstroms so that the thickness of the gold plating is compatible with thermal compression gang bonding of the copper bumps through the gold plating layer to other lead structures.
Claim 2
Dependent Claim 215 words
In a method for gold plating of an integrated circuit semiconductive device, of the type which includes a plurality of exposed copper thermal compression gang bonding bumps rising above the passivated surface of the semiconductive device and being connected at their bases to an underlying pattern of interconnect metallization, for providing an antioxidant coating of gold on the exposed copper gang bonding bumps without plating of gold nonmetallic portions of the device, the steps of: applying as a final plating step an immersion gold plating solution to both the exposed copper gang bonding bumps and nonmetallic surface portions of the semiconductive device for plating out of the immersion gold plating solution by a process of oxidation-reduction reaction using the differences inherent in the electropotentials of the gold and the copper of the gang bonding bumps to be plated as the driving force for selectively plating the gold directly onto the copper gang bonding bumps; and maintaining the copper gang bumps in contact with the immersion plating solution only so long as to plate gold onto the copper gang bonding bumps to a thickness less than 6000 angstroms so that the thickness of the gold plating is compatible with thermal compression gang bonding of the copper bumps through the gold plating layer to other lead structures.
Claim 3
Dependent Claim 20 words
The method of claim 1 wherein the intraconnect pattern of metallization is covered over by an electrically insulative passivation layer.
Claim 4
Dependent Claim 30 words
The method of claim 1 including the step of, cleaning the exposed copper gang bonding bumps of the semiconductive device with an acid bath prior to immersion gold plating thereof.
Claim 5
Dependent Claim 19 words
The method of claim 3 wherein the acid bath comprises an aqueous solution of phosphoric acid and nitric acid.
Claim 6
Dependent Claim 10 words
The product made according to the method of claim 1.
Claim 7
Dependent Claim 10 words
The product made according to the method of claim 3.

References Cited (Backward Citations)

CA698473A Cited
US3099576A Cited
US3162512A Cited
US3214292A Cited
US3523038A Cited
US3436818A Cited
US3461357A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-25 1980-07-26 1981-01-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-01-25 1984-07-26 1985-01-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-01-25 1988-07-26 1989-01-25 $7700.00 Window Closed / Lapsed

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