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US4005241A Expired / Lapsed US ⏱️ 0.0 years remaining

Metal plated polymeric article

Assignee: Monsanto Co
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Filing: 1975-02-07
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Granted: 1977-01-25
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Expires: 1995-02-07
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Abstract

Abstract This invention relates to a metal plated polymeric article, and method for the preparation thereof. The polymeric material used to form the article comprises a polyblend of a styrene polymer blended with a grafted chloroprene rubber and an inorganic compound. The grafted chloroprene provides the styrene polymer with high impact strength and serves as a source of labile halogen for flame retardancy. The inorganic compound catalyzes the evolution of halogen providing fire retardant properties to the metal plated polymeric polyblend article.

Inventors

  • 👤 Francis J. O'Neill

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 08:34
CPC Classifications
C; C23; C23C; C23C18/00; C23C18/16; C23C18/18; C23C18/20; C08; C08K; C08K3/00; C08K3/18; C08K3/20; C08K3/22; C08L; C08L25/00; C08L25/02; C08L25/04; C08L25/08; C08L25/12; C08L33/00; C08L33/18; C23C18/2006; C23C18/2046; C23C18/2073; C23C18/208; C08L51/00; C08L51/04; Y; Y10; Y10S; Y10S428/00; Y10S428/92; Y10S428/921; Y10S525/00; Y10S525/942; Y10T; Y10T428/00; Y10T428/26; Y10T428/263; Y10T428/264; Y10T428/31504; Y10T428/31678; Y10T428/31692; Y10T428/31696; Y10T428/31699

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 319 words
A metal plated article of manufacture which exhibits low smoke evolution under flaming conditions which article comprises a molded thermoplastic article having a metal plated exterior surface wherein the metal plating is approximately 2 mils thick and wherein the metal used is selected from the group consisting of nickel, copper and chromium and wherein the thermoplastic article is molded from a polyblend composition comprising: A. a polymer of a monovinylidene aromatic monomer and an ethylenically unsaturated nitrile monomer wherein the ethylenically unsaturated nitrile monomer moiety constitutes from 20% to about 70% by weight of the polymer; B. from 15 to 40% by weight, based on the total weight of the polyblend, of a crosslinked polychloroprene rubber having a Mooney viscosity of at least 200 (MS-21/2 min., 212° F.), which is grafted with: 1. at least one monovinylidene aromatic monomer; and 2. an ethylenically unsaturated nitrile monomer; wherein the ethylenically unsaturated nitrile monomer moiety constitutes from 20% to about 70% by weight of the grafted polymer; wherein the percent graft of aromatic monomer and nitrile monomer onto the polychloroprene rubber is in the range of from 10 to 100% by weight, based on the weight of the polychloroprene rubber; C. from 5 to 10% by weight, based on the total weight of the polyblend of an inorganic compound selected from the group consisting of Sb 2 O 3 , Bi 2 O 3 , MoO 3 , SnO 2 , WO 3 , and mixtures of the same; and D. from 0.5 to 5.0% by weight of a butadiene rubber said butadiene rubber being grafted with 1. at least one monovinylidene aromatic monomer, and 2. an ethylenically unsaturated nitrile monomer, wherein the total amount of polymer formed from the vinylidene aromatic monomer and the unsaturated nitrile monomer in the polyblend composition is in the range of from 45 to 84% by weight, based on the total weight of the polyblend.
Claim 2
Dependent Claim 319 words
A metal plated article of manufacture which exhibits low smoke evolution under flaming conditions which article comprises a molded thermoplastic article having a metal plated exterior surface wherein the metal plating is approximately 2 mils thick and wherein the metal used is selected from the group consisting of nickel, copper and chromium and wherein the thermoplastic article is molded from a polyblend composition comprising: A. a polymer of a monovinylidene aromatic monomer and an ethylenically unsaturated nitrile monomer wherein the ethylenically unsaturated nitrile monomer moiety constitutes from 20% to about 70% by weight of the polymer; B. from 15 to 40% by weight, based on the total weight of the polyblend, of a crosslinked polychloroprene rubber having a Mooney viscosity of at least 200 (MS-21/2 min., 212° F.), which is grafted with: 1. at least one monovinylidene aromatic monomer; and 2. an ethylenically unsaturated nitrile monomer; wherein the ethylenically unsaturated nitrile monomer moiety constitutes from 20% to about 70% by weight of the grafted polymer; wherein the percent graft of aromatic monomer and nitrile monomer onto the polychloroprene rubber is in the range of from 10 to 100% by weight, based on the weight of the polychloroprene rubber; C. from 5 to 10% by weight, based on the total weight of the polyblend of an inorganic compound selected from the group consisting of Sb 2 O 3 , Bi 2 O 3 , MoO 3 , SnO 2 , WO 3 , and mixtures of the same; and D. from 0.5 to 5.0% by weight of a butadiene rubber said butadiene rubber being grafted with 1. at least one monovinylidene aromatic monomer, and 2. an ethylenically unsaturated nitrile monomer, wherein the total amount of polymer formed from the vinylidene aromatic monomer and the unsaturated nitrile monomer in the polyblend composition is in the range of from 45 to 84% by weight, based on the total weight of the polyblend.
Claim 3
Dependent Claim 33 words
The article of claim 1 wherein at least one said monovinylidene aromatic monomer is selected from the group consisting of styrene, alphamethylstyrene, monochlorostyrene, monobromostyrene, aralkylstyrenes, alphaalkylstyrenes, alphahalostyrenes, arhalostyrenes and mixtures of the same.
Claim 4
Dependent Claim 25 words
The article of claim 1 wherein said ethylenically unsaturated nitrile is selected from the group consisting of acrylonitrile, methacrylonitrile, ethacrylonitrile and mixtures of the same.
Claim 5
Dependent Claim 19 words
The article of claim 1 which contains from 5 to 10% by weight of Sb 2 O 3 .
Claim 6
Dependent Claim 49 words
The article of claim 1 wherein said polyblend having interpolymerized therewith from 1 to 25% by weight of a monomer selected from the group consisting of acrylic acid, methyl acrylate, ethyl acrylate, butyl acrylatne, 2-ethylhexyl acrylate, methacrylic acid, methyl methacrylate, ethyl methacrylate, butyl methacrylate, 2-ethylhexyl methacrylate and mixtures thereof.

References Cited (Backward Citations)

US3563783A Cited
US3561995A Cited
US3669714A Cited
US3650803A Cited
US3830889A Cited
US3903037A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-25 1980-07-26 1981-01-25 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-01-25 1984-07-26 1985-01-25 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-01-25 1988-07-26 1989-01-25 $7700.00 Window Closed / Lapsed

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