Patent US4004995A successfully refreshed from Google Patents.
US4004995A
Expired / Lapsed
US
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Process for removing nitrogen oxides and sulfur dioxide from effluent gases
Assignee: Ebara Corp
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Filing: 1974-02-28
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Granted: 1977-01-25
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Expires: 1994-02-28
Abstract
Abstract Removal of gaseous pollutants such as nitrogen oxides and sulfur dioxide from effluent gases can be carried out advantageously from an industrial viewpoint by effecting irradiation of said gases under specifically selected conditions. High dose rate electron beam irradiation at a dose rate in the region of 10 5 rad/sec or higher is, unexpectedly, remarkably effective and efficient for said purpose. Irradiation under increased pressure is also preferable. Wash of gases after irradiation or effecting irradiation in the presence of water vapor is effective especially for the removal of nitrogen oxides. Further, by carrying out the process in two-steps in which nitrogen oxides are removed from such gases almost completely by irradiation with the minimum dose of electron beams before sulfur dioxide is removed from the thus treated gases by conventional desulfurization means, the process can be carried out very economically. Thus, it has become industrially feasible to treat the effluent gases with irradiation, for the removal of nitrogen oxides and sulfur dioxide before releasing them into the atmosphere.
Inventors
- 👤 Sueo Machi
- 👤 Keita Kawamura
- 👤 Shingi Aoki
- 👤 Waichiro Kawakami
- 👤 Shoji Hashimoto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 19:45
CPC Classifications
F; F01; F01N; F01N3/00; B; B01; B01D; B01D53/00; B01D53/34; B01D53/46; B01D53/60; Y; Y02; Y02A; Y02A50/00; Y02A50/20; Y02T; Y02T10/00; Y02T10/10; Y02T10/12
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
100 words
A process for removing NO x and SO 2 from effluent gases, comprising increasing the pressure of the effluent gases containing NO x and SO 2 in a reaction chamber to a pressure in the range of from more than atmospheric pressure to about 2 atmospheres and at the same time irradiating the pressurized gases with an ionizing radiation from a radiation source which is placed near or in said reaction chamber, thereby converting gaseous pollutants, NO x and SO 2 , to mist and solid particles, and then collecting the particles thus produced by a mist and dust collector.
Claim 2
Dependent Claim
100 words
A process for removing NO x and SO 2 from effluent gases, comprising increasing the pressure of the effluent gases containing NO x and SO 2 in a reaction chamber to a pressure in the range of from more than atmospheric pressure to about 2 atmospheres and at the same time irradiating the pressurized gases with an ionizing radiation from a radiation source which is placed near or in said reaction chamber, thereby converting gaseous pollutants, NO x and SO 2 , to mist and solid particles, and then collecting the particles thus produced by a mist and dust collector.
Claim 3
Dependent Claim
45 words
The process of claim 1 in which the irradiation is carried out with electron beams from an accelerator placed near the reaction chamber at a dose rate of about 10 5 rad/sec or higher to give a total dose of about 1 megarad or more.
Claim 4
Dependent Claim
21 words
The process of claim 2 wherein the pressure of the gases in the reaction chamber is increased to about 2 atmospheres.
Claim 5
Dependent Claim
100 words
A process for removing NO x from effluent gases, comprising delivering the effluent gases containing NO x to a reaction chamber inlet, moving said gases through the reaction chamber and at the same time irradiating the gases, including at least 1% by volume of oxygen, with an ionizing radiation from a radiation source placed near said reaction chamber, thereby converting gaseous NO x to mist and/or solid particles, delivering the irradiated gases with the particles thus produced to a washing tower, and there washing the gases with water and/or alkaline solution, and then releasing the washed gases into the atmosphere.
Claim 6
Dependent Claim
100 words
A process for removing NO x from effluent gases, comprising delivering the effluent gases containing NO x to a reaction chamber inlet, moving said gases through the reaction chamber and at the same time irradiating the gases, including at least 1% by volume of oxygen, with an ionizing radiation from a radiation source placed near said reaction chamber, thereby converting gaseous NO x to mist and/or solid particles, delivering the irradiated gases with the particles thus produced to a washing tower, and there washing the gases with water and/or alkaline solution, and then releasing the washed gases into the atmosphere.
Claim 7
Dependent Claim
45 words
The process of claim 4 in which the irradiation is carried out with electron beams from an accelerator placed near the reaction chamber at a dose rate of about 10 5 rad/sec or higher to give a total dose of about 1 megarad or more.
Claim 8
Dependent Claim
21 words
The process of claim 4, wherein the pressure of the gases in the reaction chamber is increased to about 2 atmospheres.
Claim 9
Dependent Claim
74 words
A process for removing NO x from effluent gases, comprising delivering the effluent gases containing NO x and at least an equivalent amount of moisture to a reaction chamber inlet, moving said gases through the reaction chamber and at the same time irradiating the gases with an ionizing radiation thereby converting gaseous pollutant, NO x , to mist and/or solid particles, and then collecting the particles thus produced by a mist and dust collector.
Claim 10
Dependent Claim
74 words
A process for removing NO x from effluent gases, comprising delivering the effluent gases containing NO x and at least an equivalent amount of moisture to a reaction chamber inlet, moving said gases through the reaction chamber and at the same time irradiating the gases with an ionizing radiation thereby converting gaseous pollutant, NO x , to mist and/or solid particles, and then collecting the particles thus produced by a mist and dust collector.
Claim 11
Dependent Claim
45 words
The process of claim 7 in which the irradiation is carried out with electron beams from an accelerator placed near the reaction chamber at a dose rate of about 10 5 rad/sec or higher to give a total dose of about 1 megarad or more.
Claim 12
Dependent Claim
21 words
The process of claim 7, wherein the pressure of the gases in the reaction chamber is increased to about 2 atmospheres.
Claim 13
Dependent Claim
146 words
A two-step process for removing NO x and SO 2 from effluent gases, comprising delivering said effluent gases containing NO x and SO 2 to a reaction chamber inlet, moving said effluent gases through said reaction chamber and irradiating them with an ionizing radiation from a radiation source which is placed near or in said reaction chamber thereby converting substantially all of the gaseous NO x to mist and/or fine solid particles. delivering the thus irradiated gases containing mist and/or fine solid particles as well as the remaining gaseous SO 2 to a collecting apparatus and there separating said mist and/or fine solid particles from the gases, delivering the thus-treated gases containing substantial amounts of gaseous SO 2 to a means for desulfurization which does not depend on irradiation, and there removing the remaining SO 2 , and releasing the thus purified gases into the atmosphere.
Claim 14
Dependent Claim
146 words
A two-step process for removing NO x and SO 2 from effluent gases, comprising delivering said effluent gases containing NO x and SO 2 to a reaction chamber inlet, moving said effluent gases through said reaction chamber and irradiating them with an ionizing radiation from a radiation source which is placed near or in said reaction chamber thereby converting substantially all of the gaseous NO x to mist and/or fine solid particles. delivering the thus irradiated gases containing mist and/or fine solid particles as well as the remaining gaseous SO 2 to a collecting apparatus and there separating said mist and/or fine solid particles from the gases, delivering the thus-treated gases containing substantial amounts of gaseous SO 2 to a means for desulfurization which does not depend on irradiation, and there removing the remaining SO 2 , and releasing the thus purified gases into the atmosphere.
Claim 15
Dependent Claim
48 words
The process of claim 10 in which the irradiation is carried out with electron beams from an electron beam accelerator placed near the reaction chamber, and at a dose rate of about 10 5 rad/sec or higher to give a total dose of about 1 megarad or more.
Claim 16
Dependent Claim
21 words
The process of claim 10, wherein the pressure of the gases in the reaction chamber is increased to about 2 atmospheres.
References Cited (Backward Citations)
GB237257A
Cited
GB308721A
Cited
US3034853A
Cited
US3198721A
Cited
US3389971A
Cited
US3754074A
Cited
US3565777A
Cited
US3653185A
Cited
US3674435A
Cited
US3790660A
Cited
US3715187A
Cited
US3869362A
Cited
US3869362B1
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-25 | 1980-07-26 | 1981-01-25 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-25 | 1984-07-26 | 1985-01-25 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-25 | 1988-07-26 | 1989-01-25 | $7700.00 | Window Closed / Lapsed |