Patent US4002702A successfully refreshed from Google Patents.
US4002702A
Expired / Lapsed
US
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Novel method for manufacturing plastisol resins
Assignee: Stauffer Chemical Co
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Filing: 1974-09-18
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Granted: 1977-01-11
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Expires: 1994-09-18
Abstract
Abstract There are disclosed novel particulate forms of emulsion or dispersion resins for use in plastisols and organosols as well as an improved process for their preparation. This process comprises blending a dispersion resin latex with a nucleating resin which may be in the form of either a wet cake or a dry powder and then, preferably, spray drying the resulting blend. The novel blends of this invention are characterized by substantial improvements in many of their physical and rheological properties while the process used for their preparation has many advantages over the procedures presently utilized for preparing such mixtures including improved material handling, substantial savings in time and the achievement of more efficient drying. The resins of this invention lend themselves to bulk handling in most types of conventional bulk handling equipment.
Inventors
- 👤 Leroy B. Kuhn
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 21:36
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/12; C08J3/122; C08J2327/00; C08J2327/02; C08J2327/04; C08J2327/06; C08L; C08L2205/00; C08L2205/02; C08L27/00; C08L27/02; C08L27/04; C08L27/06
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
255 words
A process for preparing blends of emulsion and nucleating resins suitable for use in preparing plastisols and organosols, said process comprising the steps of: a. admixing an aqueous latex comprising a continuous aqueous phase in which there are dispersed a plurality of particles of a vinyl chloride emulsion resin having an average diameter in the range of from about 0.1 to about 3.0 microns and a relative viscosity of from about 1.5 to about 3.5, as determined at 25° C. with a 1.0%, by weight, solution of the resin in cyclohexanone, with a plurality of particles of a vinyl chloride nucleating resin, said vinyl chloride nucleating resin particles having an average unit particle diameter in the range of from about 5 to about 60 microns, said nucleating resin particles being admixed with said emulsion resin particles while said nucleating resin particles have a moisture content of from about substantially zero to about 50%, by weight; the wet blend resulting from step (a) having a total resin solids content in the range of from about 30 to about 75%, by weight, of which from about 30 to about 99%, by weight, is emulsion resin particles and from about 70 to about 1%, by weight, is nucleating resin particles; and b. spray drying the wet blend of dispersion and extender resin particles resulting from step (a) under non-coagulating conditions at a temperature sufficiently low that the particles are not permanently bound when added to a plasticizer, to obtain said blend in the form of a dry powder.
Claim 2
Dependent Claim
255 words
A process for preparing blends of emulsion and nucleating resins suitable for use in preparing plastisols and organosols, said process comprising the steps of: a. admixing an aqueous latex comprising a continuous aqueous phase in which there are dispersed a plurality of particles of a vinyl chloride emulsion resin having an average diameter in the range of from about 0.1 to about 3.0 microns and a relative viscosity of from about 1.5 to about 3.5, as determined at 25° C. with a 1.0%, by weight, solution of the resin in cyclohexanone, with a plurality of particles of a vinyl chloride nucleating resin, said vinyl chloride nucleating resin particles having an average unit particle diameter in the range of from about 5 to about 60 microns, said nucleating resin particles being admixed with said emulsion resin particles while said nucleating resin particles have a moisture content of from about substantially zero to about 50%, by weight; the wet blend resulting from step (a) having a total resin solids content in the range of from about 30 to about 75%, by weight, of which from about 30 to about 99%, by weight, is emulsion resin particles and from about 70 to about 1%, by weight, is nucleating resin particles; and b. spray drying the wet blend of dispersion and extender resin particles resulting from step (a) under non-coagulating conditions at a temperature sufficiently low that the particles are not permanently bound when added to a plasticizer, to obtain said blend in the form of a dry powder.
Claim 3
Dependent Claim
37 words
The process of claim 1, wherein the nucleating resin is a suspension resin having a relative viscosity of from about 1.5 to about 3.5 and an average particle size of from about 5 to about 60 microns.
Claim 4
Dependent Claim
18 words
The process of claim 2, wherein the average diameter of said emulsion resin particles is about one micron.
Claim 5
Dependent Claim
18 words
The process of claim 2, wherein the average diameter of said suspension resin particles is about 30 microns.
Claim 6
Dependent Claim
17 words
The process of claim 2, wherein the relative viscosity of said emulsion resin particles is about 2.5.
Claim 7
Dependent Claim
17 words
The process of claim 2, wherein the relative viscosity of said suspension resin particles is about 2.5.
Claim 8
Dependent Claim
23 words
The process of claim 2, wherein the total resin solids of the wet blend resulting from step (a) is about 60%, by weight.
Claim 9
Dependent Claim
40 words
The process of claim 2, wherein the mixture of emulsion and suspension resin particles in the wet blend resulting from step (a) contains about 60%, by weight, of dispersion resin particles and about 40%, by weight, of suspension resin particles.
Claim 10
Dependent Claim
37 words
The process of claim 2, wherein step (b) is carried out by drying the wet blend resulting from step (a) in a spray dryer and maintaining an air outlet temperature of from about 90° to 130° F.
Claim 11
Dependent Claim
15 words
The process of claim 1, wherein said emulsion resin particles comprise particles of polyvinyl chloride.
Claim 12
Dependent Claim
15 words
The process of claim 2, wherein said suspension resin particles comprises particles of polyvinyl chloride.
Claim 13
Dependent Claim
26 words
The process of claim 1, wherein the nucleating resin is an agglomerated vinyl chloride emulsion resin said nucleating agent being readily dispersible in plasticizer without grinding.
Claim 14
Dependent Claim
29 words
The process of claim 12, wherein the vinyl chloride emulsion resin which comprises the nucleating resin is essentially the same as that employed in the vinyl chloride emulsion latex.
Claim 15
Dependent Claim
29 words
The process of claim 1, wherein the aqueous latex is post stabilized prior to use through the incorporation of from about 0.1 to about 5% of a non-ionic surfactant.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-01-11 | 1980-07-12 | 1981-01-11 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-01-11 | 1984-07-12 | 1985-01-11 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-01-11 | 1988-07-12 | 1989-01-11 | $7700.00 | Window Closed / Lapsed |