Fire-retardant polyurethane

Claim 2

The process of producing a polyurethane that comprises reacting an halogenated polyether or polyester polyol, an organic polyisocyanate, 2,3-dibromo-2-butenediol-1,4, and a phosphorus-containing compound selected from the formulae: ##STR9## and mixtures thereof; wherein each of a and b has a value of 0 to 2 inclusive; c is an integer of from 1 to 3 and the sum of a, b, and c is 3; each of R and R 1 is an alkyl, alkoxy, aryloxy, alkaryl, alkaryloxy, aralkyl, aryloxyalkoxy, or aralkoxy radical wherein each of said alkyl moieties is unsubstituted or hydroxy-substituted; and each of any aryl portion of said radical is an unsubstituted, or hydroxy- or chlorine-substituted aromatic hydrocarbon; R 2 is an alkyl, hydroxyalkyl, or unsubstituted aromatic hydrocarbon radical; R 3 is an alkyl or hydroxyalkyl radical; d has a value of from 0 to 2 inclusive; e is an integer of from 1 to 3 inclusive; and the sum of d and e is not in excess of 3; R 4 is an alkyl, aryl, alkaryl, aralkyl or aryloxyalkyl group wherein any aryl portion of said group is an unsubstituted, or chlorine- or hydroxy-substituted aromatic hydrocarbon; R 5 is an alkyl, alkylene, aryl or arylene radical; and each of said aryl and arylene radicals is an unsubstituted or chlorine- or hydroxy-substituted aromatic hydrocarbon moiety; and R 6 is an alkyl, aryl, alkaryl, aralkyl or aryloxyalkyl group wherein any aryl moiety present is an unsubstituted, hydroxy-substituted or chlorine substituted aromatic hydrocarbon moiety; and wherein said 2,3-dibromo-2-butenediol-1,4 and said phosphorus-containing compound are present in an amount sufficient to provide a final polymer containing weight percents of bromine (Br) and phosphorus (P) defined by the equation: P + Br/10 ≅ 0.1 to 1.0 and wherein P has a value of not less than 0.05 weight percent and Br has a value not less than 0.5 weight percent.

Claim 3

The process of claim 1 wherein said 2,3-dibromo-2-butenediol-1,4 and said phosphorus-containing compound are present in an amount sufficient to provide a final polymer containing not in excess of 0.95 weight percent of phosphorus (P) and not in excess of 9.5 weight percent of bromine (Br).

Claim 4

The process of claim 2 wherein P has a value of 0.14 weight percent and Br has a value of about 2.2 weight percent.

Claim 5

The process of claim 1 wherein said phosphorus-containing compound has the structural formula: ##STR10##

Claim 6

The process of claim 1 wherein said phosphorus-containing compound has the structural formula: ##STR11##

Claim 7

The process of claim 1 wherein said phosphorus-containing compound has the structural formula: ##STR12##

Claim 8

The process of claim 1 wherein said phosphorus-containing compound has the structural formula: ##STR13##

Claim 9

The process of claim 1 wherein said phosphorus-containing compound has the structural formula: ##STR14##

Claim 10

The process of claim 1 wherein said reaction takes place in the presence of a blowing agent and catalyst to produce a cellular polyurethane foam.

Claim 11

A polyurethane produced by reaction of an unhalogenated polyether polyol, an organic polyisocyanate, 2,3-dibromo-2-butenediol-1,4, and a phosphourus-containing compound selected from the formulea: ##STR15## and mixtures thereof; wherein each of a and b has a value of 0 to 2 inclusive; c is an integer of from 1 to 3 and the sum of a, b, and c is 3; each of R and R 1 is an alkyl, alkoxy, aryloxy, alkaryl, alkaryloxy, aralkyl, arloxyalkoxy, or aralkoxy radical wherein each of said alkyl moieties is unsubstituted or hydroxy-substituted; and each of any aryl portion of said radical is an unsubstituted, or hydroxy- or chlorine-substituted aromatic hydrocarbon; R 2 is an alkyl, hydroxyalkyl, or unsubstituted aromatic hydrocarbon radical; R 3 is an alkyl or hydroxy-alkyl radical; d has a value of from 0 to 2 inclusive; e is an integer of from 1 to 3 inclusive; and the sum of d and e is not in excess of 3; R 4 is an alkyl, aryl, alkaryl, aralkyl or aryloxyalkyl group, wherein any aryl portion of said group is an unsubstituted, or chlorine- or hydroxy-substituted aromatic hydrocarbon; R 5 is an alkyl, alkylene, aryl or arylene radical; and each of said aryl and arylene radicals is an unsubstituted or chlorine- or hydroxy-substituted aromatic hydrocarbon moiety; and R 6 is an alkyl, aryl, alkaryl, aralkyl or aryloxyalkyl group wherein any aryl moiety present is an unsubstituted, hydroxy-substituted or chlorine-substituted aromatic hydrocarbon moiety; and wherein said 2,3-dibromo-2-butenediol-1,4 and said phosphorus-containing compound are present in an amount sufficient to provide by weight percent of the final product a sum total of bromine (Br) and phosphorus (P), defined by the equation: P + Br/10 ≅ 0.1 to 1.0 and wherein phosphorus (P) has a value of not less than 0.05 weight percent and bromine (Br) has a value of not less than 0.5 weight percent.

Claim 12

A polyurethane produced by reaction of an unhalogenated polyether polyol, an organic polyisocyanate, 2,3-dibromo-2-butenediol-1,4, and a phosphourus-containing compound selected from the formulea: ##STR15## and mixtures thereof; wherein each of a and b has a value of 0 to 2 inclusive; c is an integer of from 1 to 3 and the sum of a, b, and c is 3; each of R and R 1 is an alkyl, alkoxy, aryloxy, alkaryl, alkaryloxy, aralkyl, arloxyalkoxy, or aralkoxy radical wherein each of said alkyl moieties is unsubstituted or hydroxy-substituted; and each of any aryl portion of said radical is an unsubstituted, or hydroxy- or chlorine-substituted aromatic hydrocarbon; R 2 is an alkyl, hydroxyalkyl, or unsubstituted aromatic hydrocarbon radical; R 3 is an alkyl or hydroxy-alkyl radical; d has a value of from 0 to 2 inclusive; e is an integer of from 1 to 3 inclusive; and the sum of d and e is not in excess of 3; R 4 is an alkyl, aryl, alkaryl, aralkyl or aryloxyalkyl group, wherein any aryl portion of said group is an unsubstituted, or chlorine- or hydroxy-substituted aromatic hydrocarbon; R 5 is an alkyl, alkylene, aryl or arylene radical; and each of said aryl and arylene radicals is an unsubstituted or chlorine- or hydroxy-substituted aromatic hydrocarbon moiety; and R 6 is an alkyl, aryl, alkaryl, aralkyl or aryloxyalkyl group wherein any aryl moiety present is an unsubstituted, hydroxy-substituted or chlorine-substituted aromatic hydrocarbon moiety; and wherein said 2,3-dibromo-2-butenediol-1,4 and said phosphorus-containing compound are present in an amount sufficient to provide by weight percent of the final product a sum total of bromine (Br) and phosphorus (P), defined by the equation: P + Br/10 ≅ 0.1 to 1.0 and wherein phosphorus (P) has a value of not less than 0.05 weight percent and bromine (Br) has a value of not less than 0.5 weight percent.

Claim 13

A polyurethane as claimed in claim 10 wherein said 2,3-dibromo-2-butenediol-1,4 and said phosphorus-containing compound are present in an amount sufficient to provide a final product comprising not in excess of 0.95 weight percent of phosphorus (P) and not in excess of 9.5 weight percent of bromine (Br).

Claim 14

A polyurethane as claimed in claim 11 wherein P has a value of 0.14 weight percent and Br has a value of about 2.2 weight percent.

Claim 15

A polyurethane as claimed in claim 10 wherein said phosphorus-containing compound has the structural formula: ##STR16##

Claim 16

A polyurethane as claimed in claim 10 wherein said phosphorus-containing compound has the structural formula: ##STR17##

Claim 17

A polyurethane as claimed in claim 10 wherein said phosphorus-containing compound has the structural formula: ##STR18##

Claim 18

A polyurethane as claimed in claim 10 wherein said phosphorus-containing compound has the structural formula: ##STR19##

Claim 19

A polyurethane as claimed in claim 10 wherein said phosphorus-containing compound has the structural formula: ##STR20##

Claim 20

A polyurethane as claimed in claim 10 wherein said polyurethane is a cured, flexible, stable polyester or polyether urethane foam.

Claim 21

A polyurethane foam as claimed in claim 18 wherein said foam is a cured, stable, fire-retardant, high-resilience polyether urethane foam having a sag factor of at least 2.2.

Claim 22

A high-resilience polyether urethane foam as claimed in claim 19 having a sag factor of from about 2.4 to 3.1.

Claim 23

A high-resilience polyether urethane foam as claimed in claim 20 wherein said polyether polyol is a linear polyether triol.

Claim 24

A high-resilience polyether urethane foam as claimed in claim 21 wherein said polyether is a poly (oxypropoylene) triol having a molecular weight of at least 4000.

Claim 25

The high-resilience foam as claimed in claim 22 wherein said poly(oxypropylene) triol has a molecular weight of from about 4,000 to about 7,000.