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Multifilament superconductors

Assignee: United States Department of the Navy
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Filing: 1975-12-23
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Granted: 1977-01-11
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Expires: 1995-12-23
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Abstract

Abstract A multifilament composite superconductor which comprises (1) a matrix sheath selected from the group consisting of a copper-gallium (Cu-Ga) alloy with a gallium content from 0.4 to 22 at.%, a copper-tin (Cu-Sn) alloy with a tin content from 1 to 11 at. %, and a copper-silicon (Cu-Si) alloy with a silicon content from 0.5 to 14 at. %; (2) multiple filaments embedded in said encasing matrix sheath and selected from the class consisting of a vanadium -gallium (V-Ga) alloy with a gallium content from 0.4 at. % to 12.5 at. %, a niobium-tin (Nb-Sn) alloy with a tin content from 0.1 at. % to 12.0 at. %, and vanadium-silicon (V-Si) alloy with a silicon content from 0.5 to 10 at. %; and (3) a continuous interfacial layer between said matrix and each filament of an A-15 compound selected from the class consisting of V3Ga, Nb3Sn, and V3Si. A method for producing said multifilament composite superconductors by mechanical deformation of a multifilament coaxial cylinder consisting of filaments and matrix sheath which comprises a homogenization anneal of the filaments and the matrix rod before assembly thereof, a series of reductions followed by anneals, and a solid stage reaction between the filaments and matrix in vacuum or an inert atmosphere and at a temperature from about 475 DEG to 700 DEG C for the production of V3Ga and V3Si and at a temperature from about 525 DEG to about 850 DEG C for the production of Nb3Sn.

Inventors

  • 👤 David G. Howe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 15:20
CPC Classifications
H; H10; H10N; H10N60/00; H10N60/01; H10N60/0184; H10N60/20; Y; Y10; Y10S; Y10S505/00; Y10S505/80; Y10S505/812; Y10S505/813; Y10S505/815; Y10S505/825; Y10S505/917; Y10S505/918; Y10S505/919; Y10S505/921; Y10T; Y10T29/00; Y10T29/49; Y10T29/49002; Y10T29/49014

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 147 words
A composite superconductor which comprises: multifilaments of an alloy selected from the group consisting of a vanadium-gallium alloy with a gallium content from 0.4 at. % to 12.5 at. %, a niobium-tin alloy with a tin content from 0.1 to 12 at. % and a vanadium-silicon alloy with a silicon content of 0.5-10 at. %; a matrix sheath of an alloy selected from the group consisting of a copper-gallium alloy with a gallium content from about 0.4 to about 22 at. %, a copper-tin alloy with a tin content from about 1 to about 11 at. %, a copper-silicon alloy with a silicon content from about 0.5 to 14 at. %, so that the matrix alloy has the same metal solute as the core alloy; and an intermediate layer of an A-15 compound produced by a solid state reaction between said core rod and said matrix sheath.
Claim 2
Dependent Claim 147 words
A composite superconductor which comprises: multifilaments of an alloy selected from the group consisting of a vanadium-gallium alloy with a gallium content from 0.4 at. % to 12.5 at. %, a niobium-tin alloy with a tin content from 0.1 to 12 at. % and a vanadium-silicon alloy with a silicon content of 0.5-10 at. %; a matrix sheath of an alloy selected from the group consisting of a copper-gallium alloy with a gallium content from about 0.4 to about 22 at. %, a copper-tin alloy with a tin content from about 1 to about 11 at. %, a copper-silicon alloy with a silicon content from about 0.5 to 14 at. %, so that the matrix alloy has the same metal solute as the core alloy; and an intermediate layer of an A-15 compound produced by a solid state reaction between said core rod and said matrix sheath.
Claim 3
Dependent Claim 110 words
The composite superconductor of claim 1, wherein; said filament alloy is are selected from the group consisting of a vanadium-gallium alloy with a gallium content from 4 at. % to 8.0 at. %, a niobium-tin alloy with a tin content from 0.5 to 5 at %, and vanadium-silicon alloy with a silicon content from 0.4 to 6 at. %, and said matrix sheath alloy is selected from the group consisting of copper-gallium alloy with a gallium content from 1.5 to 18.0 at. %, a copper-tin alloy with a tin content from 7 to 9 at. %, and a copper-silicon alloy with a silicon content from 7 to 11 at. %.
Claim 4
Dependent Claim 45 words
The composite superconductor of claim 1, wherein; said filament alloy is a vanadium-gallium alloy with a gallium content from 4 at. % to 8 at. %, and said matrix sheath alloy is a copper-gallium alloy with a gallium content from 15 to 18 at. %.
Claim 5
Dependent Claim 19 words
The composite superconductor of claim 3, wherein the thickness of said intermetallic layer is from 0.4 to 3 microns.
Claim 6
Dependent Claim 19 words
The composite superconductor of claim 3, wherein the thickness of said intermetallic layer is from 0.4 to 1.5 microns.
Claim 7
Independent Claim 424 words
A method for fabricating a composite superconductor which comprises: homogenization-annealing filament rods of an alloy selected from the class consisting of a vanadium-gallium (V--Ga) alloy with a gallium content from 0.4 at. % to 12.5 at. %, a niobium-tin (Nb--Sn) alloy with a tin content from 0.1 at. % to 12.0 at. %, and a vanadium-silicon (V--Si) alloy with a silicon content from 0.5 at. % to 10 at. % and a matrix sheath rod of an alloy selected from the class consisting of a copper-gallium (Cu--Ga) alloy with a gallium content from 0.4 at. % to 22 at. %, a copper-tin (Cu-Sn) alloy with a tin content from 1 at. % to 11 at. % and a copper-silicon (Cu-Si) alloy with a silicon content from 0.5 at. % to 14 at. %, reducing said rods by mechanical technique, boring said matrix rod to form a multicavity matrix sheath, forming an end plug having axial grooves about its periphery, annealing said filament rods from about 2 to about 16 hours at a temperature from about 750° C to about 850° C if V--Ga or V--Si is selected, and at a temperature from about 1050° C to about 1150° C if Nb--Sn is selected, annealing said matrix sheath at a temperature from about 500° to about 800° C for at least about 1 hour, etching said filament rods with an etching solution, placing said filament rods within said matrix sheath whereby a binary multicavity composite of an alloy combination selected from the class consisting of (V--Ga)-(Cu--Ga), (V--Si)-(Cu--Si), and (Nb--Sn)-(Cu--Sn) is formed having an annular air space between said matrix sheath and said filament rods, placing said end plug into said matrix sheath, subjecting said composite to a vacuum, sealing said composite while under a vacuum, reducing the diameter of said composite by 20%, annealing said composite at a temperature from about 500° to about 525° C for at least 1 hour, reducing the diameter of said composite by 20%, annealing said composite at a temperature from about 500° to about 525° C for at least one hour, reducing the diameter of said composite by 20%, annealing said composite at a temperature from about 550° to about 575° C for at least 1 hour, repeating the previous reduction steps until the desired diameter of the composite is obtained, and heating said composite at about 475° to about 700° C if said composite is V--Ga, Cu--Ga or V--Si, Cu--Si, whereas if said composite is Nb--Sn, Cu--Sn, the temperature is to be about 525° to about 850° C.
Claim 8
Independent Claim 424 words
A method for fabricating a composite superconductor which comprises: homogenization-annealing filament rods of an alloy selected from the class consisting of a vanadium-gallium (V--Ga) alloy with a gallium content from 0.4 at. % to 12.5 at. %, a niobium-tin (Nb--Sn) alloy with a tin content from 0.1 at. % to 12.0 at. %, and a vanadium-silicon (V--Si) alloy with a silicon content from 0.5 at. % to 10 at. % and a matrix sheath rod of an alloy selected from the class consisting of a copper-gallium (Cu--Ga) alloy with a gallium content from 0.4 at. % to 22 at. %, a copper-tin (Cu-Sn) alloy with a tin content from 1 at. % to 11 at. % and a copper-silicon (Cu-Si) alloy with a silicon content from 0.5 at. % to 14 at. %, reducing said rods by mechanical technique, boring said matrix rod to form a multicavity matrix sheath, forming an end plug having axial grooves about its periphery, annealing said filament rods from about 2 to about 16 hours at a temperature from about 750° C to about 850° C if V--Ga or V--Si is selected, and at a temperature from about 1050° C to about 1150° C if Nb--Sn is selected, annealing said matrix sheath at a temperature from about 500° to about 800° C for at least about 1 hour, etching said filament rods with an etching solution, placing said filament rods within said matrix sheath whereby a binary multicavity composite of an alloy combination selected from the class consisting of (V--Ga)-(Cu--Ga), (V--Si)-(Cu--Si), and (Nb--Sn)-(Cu--Sn) is formed having an annular air space between said matrix sheath and said filament rods, placing said end plug into said matrix sheath, subjecting said composite to a vacuum, sealing said composite while under a vacuum, reducing the diameter of said composite by 20%, annealing said composite at a temperature from about 500° to about 525° C for at least 1 hour, reducing the diameter of said composite by 20%, annealing said composite at a temperature from about 500° to about 525° C for at least one hour, reducing the diameter of said composite by 20%, annealing said composite at a temperature from about 550° to about 575° C for at least 1 hour, repeating the previous reduction steps until the desired diameter of the composite is obtained, and heating said composite at about 475° to about 700° C if said composite is V--Ga, Cu--Ga or V--Si, Cu--Si, whereas if said composite is Nb--Sn, Cu--Sn, the temperature is to be about 525° to about 850° C.
Claim 9
Dependent Claim 47 words
The method of claim 6, wherein said composite is heated, to produce said intermetallic layer, at a temperature form 500° to 625° C if said composite is V--Ga, Cu--Ga or V--Si, Cu--Si, and at a temperature from 550° to 800° C if said composite is Nb--Sn, Cu--Sn.
Claim 10
Dependent Claim 47 words
The method of claim 6, wherein said composite is heated, to produce said intermetallic layer, at a temperature from 500° to 575° C if said composite is V--Ga, Cu--Ga or V--Si, Cu--Si, and at a temperature from 550° to 775° C if said composite is Nb--Sn, Cu--Sn.

References Cited (Backward Citations)

US3910802A Cited
US3926684A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-11 1980-07-12 1981-01-11 $2000.00 Window Closed / Lapsed
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