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US4001741A Expired / Lapsed US ⏱️ 0.0 years remaining

Low working temperature reed glasses

Assignee: Schott AG
•
Filing: 1976-01-28
•
Granted: 1977-01-04
•
Expires: 1996-01-28
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Abstract

Abstract A glass having a softening temperature (E W ) between 596° and 634° C. and a working temperature (V A ) between 792° and 863° C., said glass being produced from a melt having a composition expressed in percentages by weight as follows: ______________________________________ SiO 2 50.9 to 60.4, B 2 O 3 1.5 to 11.5, Al 2 O 3 2.5 to 5.3, Li 2 O 0.75 to 3.0, Na 2 O 6.0 to 15.0, K 2 O 0 to 3.8, Li 2 O + Na 2 O 8.0 to 17.3, Li 2 O + Na 2 O + K 2 O 11.0 to 19.7, CaO 0 to 1.5, BaO 0 to 12.9, ZnO 0 to 7.3, PbO 0 to 17.5, BaO + PbO 7.0 to 17.8, Fe 3 O 4 3.3 to 5.0, F 2 0 to 0.7, Sb 2 O 3 0.05 to 0.1, Sugar 0.05 to 0.1. ______________________________________

Inventors

  • 👤 Otto Lindig
  • 👤 Werner Sack

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 07:04
CPC Classifications
C; C03; C03C; C03C4/00; C03C3/00; C03C3/04; C03C3/076; C03C3/089; C03C3/091; C03C3/093; C03C3/102; C03C4/08; C03C4/082; C03C8/00; C03C8/24

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 169 words
A glass having a thermal expansion coefficient (α) of 80.1 to 110.2 × 10 - 7 /° C. (20° -300° C), a transformation temperature (Tg) of between 428 and 488° C., a density (D) of 2.70 to 2.84 g/cc, a softening temperature (E W ) between 596° and 634° C. and a working temperature (V A ) between 792° and 863° C., said glass being produced from a melt having a composition expressed in percentages by weight as follows: ______________________________________ SiO.sub.2 50.9 to 60.4, B.sub.2 O.sub.3 1.5 to 11.5, Al.sub.2 O.sub.3 2.5 to 5.3, Li.sub.2 O 0.75 to 3.0, Na.sub.2 O 6.0 to 15.0, K.sub.2 O 0 to 3.8, Li.sub.2 O + Na.sub.2 O 8.0 to 17.3, Li.sub.2 O + Na.sub.2 O + K.sub.2 O 11.0 to 19.7, CaO 0 to 1.5, BaO 0 to 12.9, ZnO 0 to 7.3, PbO 0 to 17.5, BaO + PbO 7.0 to 17.8, Fe.sub.3 O.sub.4 3.3 to 5.0, F.sub.2 0 to 0.7, Sb.sub.2 O.sub.3 0.05 to 0.1, Sugar 0.05 to 0.1. ______________________________________
Claim 2
Dependent Claim 169 words
A glass having a thermal expansion coefficient (α) of 80.1 to 110.2 × 10 - 7 /° C. (20° -300° C), a transformation temperature (Tg) of between 428 and 488° C., a density (D) of 2.70 to 2.84 g/cc, a softening temperature (E W ) between 596° and 634° C. and a working temperature (V A ) between 792° and 863° C., said glass being produced from a melt having a composition expressed in percentages by weight as follows: ______________________________________ SiO.sub.2 50.9 to 60.4, B.sub.2 O.sub.3 1.5 to 11.5, Al.sub.2 O.sub.3 2.5 to 5.3, Li.sub.2 O 0.75 to 3.0, Na.sub.2 O 6.0 to 15.0, K.sub.2 O 0 to 3.8, Li.sub.2 O + Na.sub.2 O 8.0 to 17.3, Li.sub.2 O + Na.sub.2 O + K.sub.2 O 11.0 to 19.7, CaO 0 to 1.5, BaO 0 to 12.9, ZnO 0 to 7.3, PbO 0 to 17.5, BaO + PbO 7.0 to 17.8, Fe.sub.3 O.sub.4 3.3 to 5.0, F.sub.2 0 to 0.7, Sb.sub.2 O.sub.3 0.05 to 0.1, Sugar 0.05 to 0.1. ______________________________________
Claim 3
Dependent Claim 70 words
A glass according to claim 1, which is substantially lead oxide and fluorine-free and in which the percentages by weight of the following constituents of the melt are as follows: ______________________________________ Na.sub.2 O 8.0 to 15.0, Li.sub.2 O + Na.sub.2 O 11.0 to 14.1, Li.sub.2 O + Na.sub.2 O + K.sub.2 O 15.0 to 19.7, BaO 7.0 to 12.9, ZnO 0 to 6.5, BaO + ZnO 13.5 to 17.0. ______________________________________
Claim 4
Dependent Claim 64 words
A glass according to claim 1, in particular for use in conjunction with a magnetic alloy containing 48.5% Fe/48.5% Co/3% V, said glass being produced from a melt having substantially the following percentage composition by weight: ______________________________________ SiO.sub.2 56.5, B.sub.2 O.sub.3 7.2, Al.sub.2 O.sub.3 4.0, Li.sub.2 O 2.0, Na.sub.2 O 9.0, PbO 12.8, BaO 5.0, Fe.sub.3 O.sub.4 3.5, Sb.sub.2 O.sub.3 0.1, Sugar 0.05. ______________________________________
Claim 5
Dependent Claim 64 words
A glass according to claim 2, in particular for use in conjunction with a magnetic alloy containing 48.5% Fe/48.5% Co/3% V, said glass being produced from a melt having substantially the following percentage composition by weight: ______________________________________ SiO.sub.2 56.0, B.sub.2 O.sub.3 8.0, Al.sub.2 O.sub.3 4.0, Li.sub.2 O 3.0, Na.sub.2 O 8.0, BaO 12.2, ZnO 4.8, Fe.sub.3 O.sub.4 4.0, Sb.sub.2 O.sub.3 0.1, Sugar 0.05. ______________________________________
Claim 6
Dependent Claim 66 words
A glass according to claim 1, in particular for use in conjunction with a magnetic alloy containing 29.2% Fe/55.0% Co/11.8% Ni/1% Al/3% Ti, said glass being produced from a melt having substantially the following percentage composition by weight: ______________________________________ SiO.sub.2 58.0, B.sub.2 O.sub.3 6.7, Al.sub.2 O.sub.3 5.0, Li.sub.2 O 2.0, Na.sub.2 O 12.1, PbO 7.1, BaO 5.8, Fe.sub.3 O.sub.4 3.3, Sb.sub.2 O.sub.3 0.1, Sugar 0.05. ______________________________________
Claim 7
Dependent Claim 64 words
A glass according to claim 2, in particular for use in conjunction with a magnetic alloy containing 29.2% Fe/55.0% Co/11.8% Ni/1% Al/3% Ti, said glass being produced from a melt having substantially the following percentage composition by weight: ______________________________________ SiO.sub.2 58.0, B.sub.2 O.sub.3 6.7, Al.sub.2 O.sub.3 5.0, Li.sub.2 O 3.0, Na.sub.2 O 11.1, BaO 12.9, Fe.sub.3 O.sub.4 3.3, Sb.sub.2 O.sub.3 0.1, Sugar 0.05. ______________________________________
Claim 8
Dependent Claim 69 words
A glass according to claim 2, in particular for use in conjunction with a magnetic alloy containing 12% Fe/3% Nb/up to 0.3% Ta/approx. 85% Co, said glass being produced from a melt having substantially the following percentage composition by weight: ______________________________________ SiO.sub.2 57.6, B.sub.2 O.sub.3 3.5, Al.sub.2 O.sub.3 5.3, Li.sub.2 O 1.5, Na.sub.2 O 15.0, K.sub.2 O 3.2, BaO 10.0, Fe.sub.3 O.sub.4 3.8, Sb.sub.2 O.sub.3 0.1, Sugar 0.05. ______________________________________
Claim 9
Dependent Claim 20 words
In a reed switch comprising a magnetic alloy bonded to glass, the improvement comprising employing the glass of claim 1.
Claim 10
Dependent Claim 20 words
In a residual switch comprising a magnetic alloy bonded to glass, the improvement comprising employing the glass of claim 3.
Claim 11
Dependent Claim 20 words
In a residual switch comprising a magnetic alloy bonded to glass, the improvement comprising employing the glass of claim 4.
Claim 12
Dependent Claim 20 words
In a residual switch comprising a magnetic alloy bonded to glass, the improvement comprising employing the glass of claim 5.
Claim 13
Dependent Claim 20 words
In a residual switch comprising a magnetic alloy bonded to glass, the improvement comprising employing the glass of claim 6.
Claim 14
Dependent Claim 20 words
In a residual switch comprising a magnetic alloy bonded to glass, the improvement comprising employing the class of claim 7.
Claim 15
Dependent Claim 107 words
A glass according to claim 1, said glass being produced from a melt having a composition expressed in percentages by weight as follows: ______________________________________ SiO.sub.2 56 to 60.4 B.sub.2 O.sub.3 1.5 to 7.0 Al.sub.2 O.sub.3 4.0 to 5.3 Li.sub.2 O 1.7 to 2.5 Na.sub.2 O 9.5 to 15.0 K.sub.2 O 0 to 1.5 Li.sub.2 O + Na.sub.2 O 11.2 to 17.3 Li.sub.2 O + Na.sub.2 O + K.sub.2 O 12.0 to 19.0 CaO 0 BaO 4.5 to 12.9 ZnO 0 PbO 0 to 12.0 BaO + PbO 11.3 to 16.8 Fe.sub.3 O.sub.4 3.5 to 4.0 F.sub.2 0 Sb.sub.2 O.sub.3 0.05 to 0.1 Sugar 0.05 to 0.1 ______________________________________
Claim 16
Dependent Claim 20 words
In a residual switch comprising a magnetic alloy bonded to glass, the improvement comprising employing the glass of claim 14.

References Cited (Backward Citations)

US3672919A Cited
US3876437A Cited
US3814612A Cited
US3949335A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-01-04 1980-07-05 1981-01-04 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-01-04 1984-07-05 1985-01-04 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-01-04 1988-07-05 1989-01-04 $7700.00 Window Closed / Lapsed

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