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US4000206A
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Process for the production of benzene, cyclohexane and motor fuel from a C6 hydrocarbon stream
Assignee: Phillips Petroleum Co
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Filing: 1975-10-16
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Granted: 1976-12-28
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Expires: 1995-10-16
Abstract
Abstract A C 6 hydrocarbon stream is converted to benzene, cyclohexane and a motor fuel blending stock by a combination of steps comprising fractionation, hydrogenation and isomerization of the fractions boiling in the isohexanes range and above the n-hexane range, and reforming of the fraction boiling in the n-hexane range and separately recovering a motor fuel blending stock, cyclohexane and benzene as products of the process.
Inventors
- 👤 Lewis E. Drehman
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 10:48
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/085; C10G35/09; C07; C07C; C07C13/00; C07C13/02; C07C13/16; C07C13/18; C07C15/00; C07C15/02; C07C15/04; C07C9/00; C07C9/14; C07C9/16; C10G59/00; C10G59/02; C10L; C10L1/00; C10L1/04; C10L1/06
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
219 words
A process for producing benzene, cyclohexane and an isohexane concentrate which comprises the steps of: a. processing a hydrocarbon-containing feedstock to obtain a first stream consisting essentially of hydrocarbons having six carbon atoms; b. fractionating said first stream to obtain a second stream comprising hydrocarbons having a boiling point in the isohexanes range and a third stream comprising hydrocarbons having a boiling point above the isohexanes range; c. fractionating said third stream to obtain a fourth stream comprising hydrocarbons boiling in the n-hexane range and a fifth stream comprising hydrocarbons having a boiling point above the n-hexane range; d. combining said second stream and said fifth stream to obtain a sixth stream; e. hydrogenating said sixth stream to obtain a seventh stream comprising saturated hydrocarbons having six carbon atoms; f. isomerizing said seventh stream to obtain an eighth stream comprising isohexanes, cyclohexane and n-hexane; g. fractionating said eighth stream to obtain an isohexane concentrate and a ninth stream comprising cyclohexane, isohexane and n-hexane; h. withdrawing said isohexane concentrate as a first product of the process; i. recovering from said ninth stream a cyclohexane concentrate as a second product of the process; j. reforming said fourth stream to obtain a tenth reformate stream; and k. recovering from said reformate stream a benzene concentrate as a third product of the process.
Claim 2
Dependent Claim
219 words
A process for producing benzene, cyclohexane and an isohexane concentrate which comprises the steps of: a. processing a hydrocarbon-containing feedstock to obtain a first stream consisting essentially of hydrocarbons having six carbon atoms; b. fractionating said first stream to obtain a second stream comprising hydrocarbons having a boiling point in the isohexanes range and a third stream comprising hydrocarbons having a boiling point above the isohexanes range; c. fractionating said third stream to obtain a fourth stream comprising hydrocarbons boiling in the n-hexane range and a fifth stream comprising hydrocarbons having a boiling point above the n-hexane range; d. combining said second stream and said fifth stream to obtain a sixth stream; e. hydrogenating said sixth stream to obtain a seventh stream comprising saturated hydrocarbons having six carbon atoms; f. isomerizing said seventh stream to obtain an eighth stream comprising isohexanes, cyclohexane and n-hexane; g. fractionating said eighth stream to obtain an isohexane concentrate and a ninth stream comprising cyclohexane, isohexane and n-hexane; h. withdrawing said isohexane concentrate as a first product of the process; i. recovering from said ninth stream a cyclohexane concentrate as a second product of the process; j. reforming said fourth stream to obtain a tenth reformate stream; and k. recovering from said reformate stream a benzene concentrate as a third product of the process.
Claim 3
Dependent Claim
37 words
The process of claim 1 wherein there is recovered from said ninth stream an eleventh stream comprising n-hexane and isohexane, wherein said eleventh stream is combined with said seventh stream and the resulting combined stream is isomerized.
Claim 4
Dependent Claim
21 words
The process of claim 1 wherein said cyclohexane concentrate is further fractionated to obtain a product stream consisting essentially of cyclohexane.
Claim 5
Dependent Claim
47 words
The process of claim 1 wherein said reformate stream is fractionated to obtain said benzene concentrate, a twelfth stream consisting of hydrogen and a thirteenth stream comprising methane and wherein at least a portion of said twelfth stream is passed to and combined with said sixth stream.
Claim 6
Dependent Claim
29 words
The process of claim 4 wherein said benzene concentrate is further treated to obtain a product stream consisting essentially of benzene and a fourteenth stream comprising n-hexane and isohexane.
Claim 7
Dependent Claim
15 words
The process of claim 5 wherein said fourteenth stream is combined with said first stream.
Claim 8
Dependent Claim
52 words
The process of claim 1 wherein said fourth stream is reformed in a reforming zone under reforming conditions in the presence of steam and in the presence of a reforming catalyst selected from the group consisting of at least one Group VIII metal in combination with a tin-modified Group II metal aluminate.
Claim 9
Dependent Claim
25 words
The process of claim 7 wherein said Group VIII metal is selected from the group consisting of nickel, platinum, palladium, iridium, osmium and mixtures thereof.
Claim 10
Dependent Claim
12 words
The process of claim 8 wherein said Group VIII metal is platinum
Claim 11
Dependent Claim
14 words
The process of claim 7 wherein said Group VII metal aluminate is zinc aluminate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-12-28 | 1980-06-28 | 1980-12-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-12-28 | 1984-06-28 | 1984-12-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-12-28 | 1988-06-28 | 1988-12-28 | $7700.00 | Window Closed / Lapsed |