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US4000206A Expired / Lapsed US ⏱️ 0.0 years remaining

Process for the production of benzene, cyclohexane and motor fuel from a C6 hydrocarbon stream

Assignee: Phillips Petroleum Co
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Filing: 1975-10-16
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Granted: 1976-12-28
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Expires: 1995-10-16
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Abstract

Abstract A C 6 hydrocarbon stream is converted to benzene, cyclohexane and a motor fuel blending stock by a combination of steps comprising fractionation, hydrogenation and isomerization of the fractions boiling in the isohexanes range and above the n-hexane range, and reforming of the fraction boiling in the n-hexane range and separately recovering a motor fuel blending stock, cyclohexane and benzene as products of the process.

Inventors

  • 👤 Lewis E. Drehman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 07:02
CPC Classifications
C; C10; C10G; C10G35/00; C10G35/04; C10G35/06; C10G35/085; C10G35/09; C07; C07C; C07C13/00; C07C13/02; C07C13/16; C07C13/18; C07C15/00; C07C15/02; C07C15/04; C07C9/00; C07C9/14; C07C9/16; C10G59/00; C10G59/02; C10L; C10L1/00; C10L1/04; C10L1/06

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 219 words
A process for producing benzene, cyclohexane and an isohexane concentrate which comprises the steps of: a. processing a hydrocarbon-containing feedstock to obtain a first stream consisting essentially of hydrocarbons having six carbon atoms; b. fractionating said first stream to obtain a second stream comprising hydrocarbons having a boiling point in the isohexanes range and a third stream comprising hydrocarbons having a boiling point above the isohexanes range; c. fractionating said third stream to obtain a fourth stream comprising hydrocarbons boiling in the n-hexane range and a fifth stream comprising hydrocarbons having a boiling point above the n-hexane range; d. combining said second stream and said fifth stream to obtain a sixth stream; e. hydrogenating said sixth stream to obtain a seventh stream comprising saturated hydrocarbons having six carbon atoms; f. isomerizing said seventh stream to obtain an eighth stream comprising isohexanes, cyclohexane and n-hexane; g. fractionating said eighth stream to obtain an isohexane concentrate and a ninth stream comprising cyclohexane, isohexane and n-hexane; h. withdrawing said isohexane concentrate as a first product of the process; i. recovering from said ninth stream a cyclohexane concentrate as a second product of the process; j. reforming said fourth stream to obtain a tenth reformate stream; and k. recovering from said reformate stream a benzene concentrate as a third product of the process.
Claim 2
Dependent Claim 219 words
A process for producing benzene, cyclohexane and an isohexane concentrate which comprises the steps of: a. processing a hydrocarbon-containing feedstock to obtain a first stream consisting essentially of hydrocarbons having six carbon atoms; b. fractionating said first stream to obtain a second stream comprising hydrocarbons having a boiling point in the isohexanes range and a third stream comprising hydrocarbons having a boiling point above the isohexanes range; c. fractionating said third stream to obtain a fourth stream comprising hydrocarbons boiling in the n-hexane range and a fifth stream comprising hydrocarbons having a boiling point above the n-hexane range; d. combining said second stream and said fifth stream to obtain a sixth stream; e. hydrogenating said sixth stream to obtain a seventh stream comprising saturated hydrocarbons having six carbon atoms; f. isomerizing said seventh stream to obtain an eighth stream comprising isohexanes, cyclohexane and n-hexane; g. fractionating said eighth stream to obtain an isohexane concentrate and a ninth stream comprising cyclohexane, isohexane and n-hexane; h. withdrawing said isohexane concentrate as a first product of the process; i. recovering from said ninth stream a cyclohexane concentrate as a second product of the process; j. reforming said fourth stream to obtain a tenth reformate stream; and k. recovering from said reformate stream a benzene concentrate as a third product of the process.
Claim 3
Dependent Claim 37 words
The process of claim 1 wherein there is recovered from said ninth stream an eleventh stream comprising n-hexane and isohexane, wherein said eleventh stream is combined with said seventh stream and the resulting combined stream is isomerized.
Claim 4
Dependent Claim 21 words
The process of claim 1 wherein said cyclohexane concentrate is further fractionated to obtain a product stream consisting essentially of cyclohexane.
Claim 5
Dependent Claim 47 words
The process of claim 1 wherein said reformate stream is fractionated to obtain said benzene concentrate, a twelfth stream consisting of hydrogen and a thirteenth stream comprising methane and wherein at least a portion of said twelfth stream is passed to and combined with said sixth stream.
Claim 6
Dependent Claim 29 words
The process of claim 4 wherein said benzene concentrate is further treated to obtain a product stream consisting essentially of benzene and a fourteenth stream comprising n-hexane and isohexane.
Claim 7
Dependent Claim 15 words
The process of claim 5 wherein said fourteenth stream is combined with said first stream.
Claim 8
Dependent Claim 52 words
The process of claim 1 wherein said fourth stream is reformed in a reforming zone under reforming conditions in the presence of steam and in the presence of a reforming catalyst selected from the group consisting of at least one Group VIII metal in combination with a tin-modified Group II metal aluminate.
Claim 9
Dependent Claim 25 words
The process of claim 7 wherein said Group VIII metal is selected from the group consisting of nickel, platinum, palladium, iridium, osmium and mixtures thereof.
Claim 10
Dependent Claim 12 words
The process of claim 8 wherein said Group VIII metal is platinum
Claim 11
Dependent Claim 14 words
The process of claim 7 wherein said Group VII metal aluminate is zinc aluminate.

References Cited (Backward Citations)

US2953606A Cited
US3009002A Cited
US3150195A Cited
US3211797A Cited
US3250816A Cited
US3670044A Cited
US3644196A Cited
US3844935A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-28 1980-06-28 1980-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-28 1984-06-28 1984-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-28 1988-06-28 1988-12-28 $7700.00 Window Closed / Lapsed

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