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Alkylthioamido sulfonic acids and derivatives thereof

Assignee: Novartis Corp
•
Filing: 1975-12-19
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Granted: 1976-12-28
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Expires: 1995-12-19
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Abstract

Abstract The invention is directed to alkylthio alkylamido sulfonic acids and salts of the formula ##STR1## R 6 is unsubstituted or substituted alkyl, cycloalkyl or phenyl, alkylthio, tert-alkylamine, furfuryl or a group derived from a polyfunctional mercaptan, R 1 is hydrogen or lower alkyl and each of R 2 , R 4 and R 5 is individually hydrogen or a hydrocarbon radical. R 3 is hydrogen, alkyl, aryl or pyridyl, M is hydrogen, a monovalent alkali metal, an alkaline earth metal, an organic base or ammonium, and n is an integer corresponding to the valency of M. Said compounds are prepared by a base catalyzed addition reaction of a reactive mercaptan to an alkylenylamidoalkane sulfonic acid salt. The compounds are useful as surfactants.

Inventors

  • 👤 Robert Ernest Arthur Dear
  • 👤 Eduard Karl Kleiner

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 11:52
CPC Classifications
C; C07; C07C; C07C309/00; C07C309/01; C07C309/02; C07C309/03; C07C309/13; C07C309/14; C07C309/15

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 82 words
A compound of the formula ##STR20## wherein R 1 is hydrogen or lower alkyl, R 2 , r 4 and R 5 are independently hydrogen or alkyl group of 1 to 12 carbons, R 3 is hydrogen or alkyl of 1 to 12 carbons, R 6 is a straight or branched chain alkyl of 1 to 25 carbons, and M is hydrogen, a monovalent alkali metal or an alkaline earth metal, and n is an integer corresponding to the valency of M.
Claim 2
Dependent Claim 82 words
A compound of the formula ##STR20## wherein R 1 is hydrogen or lower alkyl, R 2 , r 4 and R 5 are independently hydrogen or alkyl group of 1 to 12 carbons, R 3 is hydrogen or alkyl of 1 to 12 carbons, R 6 is a straight or branched chain alkyl of 1 to 25 carbons, and M is hydrogen, a monovalent alkali metal or an alkaline earth metal, and n is an integer corresponding to the valency of M.
Claim 3
Dependent Claim 39 words
A compound of claim 1 wherein R 1 , R 4 and R 5 are hydrogen, R 2 and R 3 are methyl, R 6 is straight or branched chain alkyl and M is hydrogen, sodium, potassium, or magnesium.
Claim 4
Dependent Claim 12 words
A compound of claim 1 which is sodium or potassium 2-[3-n-decylthiopropionamido]-2-methylpropane sulfonate.
Claim 5
Dependent Claim 12 words
A compound of claim 1 which is sodium or potassium 2-[3-n-butylthiopropionamido]-2-methylpropane sulfonate.
Claim 6
Dependent Claim 12 words
A compound of claim 1 which is sodium or potassium 2-[3-n-hexylthiopropionamido]-2-methylpropane sulfonate.
Claim 7
Dependent Claim 12 words
A compound of claim 1 which is sodium or potassium 2-[3-n-octylthiopropionamido]-2-methylpropane sulfonate.
Claim 8
Dependent Claim 12 words
A compound of claim 1 which is sodium or potassium 2-[3-n-dodecylthiopropionamido]-2-methylpropane sulfonate.
Claim 9
Dependent Claim 9 words
A compound of claim 1 wherein M is hydrogen.

References Cited (Backward Citations)

US3235549A Cited
US3544597A Cited
US3793226A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-28 1980-06-28 1980-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-28 1984-06-28 1984-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-28 1988-06-28 1988-12-28 $7700.00 Window Closed / Lapsed

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