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Plasticized tarpolymers of vinyl chloride/vinyl acetate/hydroxyalkyl acrylate with good metalic adhesion

Assignee: Hexion Inc
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Filing: 1974-12-16
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Granted: 1976-12-28
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Expires: 1994-12-16
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Abstract

Abstract This invention involves terpolymers of vinyl chloride, vinyl acetate and hydroxyalkyl acrylate wherein there is incorporated about 2.00 to about 5.5% by weight of the latter two monomers. These polymers provide efficacious protective coatings capable of forming a particularly effective adhesive bond to metallic substrates.

Inventors

  • 👤 Peter Michael Galland
  • 👤 Eugene Norman Skiest
  • 👤 Milton Kline

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 18:46
CPC Classifications
B; B05; B05D; B05D7/00; B05D7/14; B05D7/16; C; C08; C08K; C08K5/00; C08K5/01; C08K5/04; C08K5/10; C08K5/11; C08K5/12; C08K5/49; C08K5/51; C08K5/52; C08L; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L67/00; C08L67/02; C09; C09D; C09D127/00; C09D127/02; C09D127/04; C09D127/06

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 120 words
A thermoplastic resinous adhesive composition capable of forming a protective barrier for and adhering effectively to similar and dissimilar substrates comprising a resin plasticized with 35 to 150 parts of a plasticizer per 100 parts of the resin, said resin has a particle size of 25 to 150 microns, a relative viscosity of 1.55 to 2.00 measured at 25° C of 1% resin in cyclohexanone and is prepared from 2.00 to 5.5% by weight of hydroxyalkyl acrylate where the alkyl group contains from 1 to 4 carbon atoms, from 2.00 to 5.5% by weight of vinyl acetate, and from 96.0 to 89.0% by weight of vinyl chloride, the amounts being based on weight of monomers used in preparing said resin.
Claim 2
Dependent Claim 120 words
A thermoplastic resinous adhesive composition capable of forming a protective barrier for and adhering effectively to similar and dissimilar substrates comprising a resin plasticized with 35 to 150 parts of a plasticizer per 100 parts of the resin, said resin has a particle size of 25 to 150 microns, a relative viscosity of 1.55 to 2.00 measured at 25° C of 1% resin in cyclohexanone and is prepared from 2.00 to 5.5% by weight of hydroxyalkyl acrylate where the alkyl group contains from 1 to 4 carbon atoms, from 2.00 to 5.5% by weight of vinyl acetate, and from 96.0 to 89.0% by weight of vinyl chloride, the amounts being based on weight of monomers used in preparing said resin.
Claim 3
Dependent Claim 31 words
Coating composition of claim 1 wherein said monomeric components are incorporated in amount by weight of about 94.5% of vinyl chloride, about 2.75% vinyl acetate and about 2.75% of hydroxyalkyl acrylate.
Claim 4
Dependent Claim 30 words
Coating composition of claim 2 wherein said plasticizer is selected from phthalates and wherein said coating composition is formed for application as a solution, plastisol, dry blend or electrostatic spray.
Claim 5
Dependent Claim 22 words
Coating composition of claim 1 wherein said acrylate is hydroxyethyl acrylate and said resin has a relative viscosity of 1.65 to 1.75.
Claim 6
Dependent Claim 94 words
A flexible film-forming resin composition capable of adhering to metal substrates comprising resin plasticized with 35 to 150 parts of a plasticizer per 100 units of the resin, said resin having a relative viscosity of 1.55 to 2.00 measures at 25° C of 1% resin in cyclohexanone and a particle size of 25 to 150 microns, is a terpolymer polymerized from ingredients comprising 2.00 to 5.5% of hydroxyethyl acrylate, 2.00 to 5.5% of vinyl acetate and the remainder being vinyl chloride, the amounts being based on weight of monomers used in preparing said resin.
Claim 7
Dependent Claim 94 words
A flexible film-forming resin composition capable of adhering to metal substrates comprising resin plasticized with 35 to 150 parts of a plasticizer per 100 units of the resin, said resin having a relative viscosity of 1.55 to 2.00 measures at 25° C of 1% resin in cyclohexanone and a particle size of 25 to 150 microns, is a terpolymer polymerized from ingredients comprising 2.00 to 5.5% of hydroxyethyl acrylate, 2.00 to 5.5% of vinyl acetate and the remainder being vinyl chloride, the amounts being based on weight of monomers used in preparing said resin.
Claim 8
Dependent Claim 12 words
Resin of claim 5 having a relative viscosity of 1.65 to 1.75.

References Cited (Backward Citations)

US2686172A Cited
US3161623A Cited
GB1097613A Cited
US3269994A Cited
US3554953A Cited
US3755271A Cited
US3884887A Cited
US3826669A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-12-28 1980-06-28 1980-12-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-12-28 1984-06-28 1984-12-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-12-28 1988-06-28 1988-12-28 $7700.00 Window Closed / Lapsed

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