Electrophotographic member having improved sensitizer and process utilizing same

Claim 2

An electrophotographic element comprising an electrically conductive support member and a photoconductive layer disposed thereon, said photoconductive layer comprising an admixture of (a) organic photoconductive materials selected from the group of heterocyclic, photoconductive materials and photoconductive materials consisting of high molecular weight of at least 1,000 selected from the group consisting of polyvinyl carbazole, polyvinylphenathiazine and carbazoleformaldehyde resin and (b) quaternary salts formed by the reaction of inorganic or organic acid with indolinospirobenzopyrans, said quaternary salts being from about 1.0 to 10.0% by weight of said photoconductive materials and said indolinospirobenzopyrans being of the general formula ##STR8## wherein R 1 is a phenylradical, an alkyl radical with one to five carbon atoms, or a substituted alkyl radical with one to five carbon atoms where the substitute is a carboxy radical, a cyano radical, an alkoxycarbonyl radical with one to five carbon atoms, a halogen atom, an alkoxy radical with one to five carbon atoms, or a phenyl radical; R 2 and R 3 are an alkyl radical with one to five carbon atoms, a phenyl radical, or R 2 +R.sub. 3 can be (CH 2 ) n where n is 4 or 5; X is a hydrogen atom, a nitro radical, a halogen atom, a carboxy radical, an alkoxycarbonyl radical, an alkyl radical with one to five carbon atoms, or a alkoxy radical with one to five carbon atoms; and Y is a hydrogen atom, a nitro radical, a halogen atom, a formyl radical, or an alkoxy radical with one to five carbon atoms.

Claim 3

An electrophotographic member for electrophotographic photosensitive materials claimed in claim 1, wherein said inorganic salts is selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, pherchloric acid, boron trifluoride, stannous chloride, titanium chloride, ferric chloride, phosphoric acid, phosphorous molybdenate and zinc chloride.

Claim 4

An electrophotographic member for electrophotographic photosensitive materials claimed in claim 1, wherein said organic salts is selected from the group consisting of oxalic acid, acetic acid, benzenesulfonic acid, toluene-sulfonic acid, salicylic acid, picric acid, dimethylsulfuric acid and diethylsulfuric acid.

Claim 5

An electrophotographic element comprising an electrically conductive support member and a photoconductive layer disposed thereon, said photoconductive layer comprising an admixture of (a) organic photoconductive materials selected from the group consisting of polyvinylcarbazole, polyvinylphenothiazine and carbazoleformaldehyde resin and having a molecular weight from 1,000 to 1,000,000 and (b) quaternary salts formed by the reaction of inorganic or organic acid with indolinospirobenzopyrans, said quaternary salts being from about 1.0 to 10.0% by weight of said photoconductive materials and said indolinospirobenzopyrans being of the general formula ##STR9## wherein R 1 is a phenylradical, an alkyl radical with one to five carbon atoms, or a substituted alkyl radical with one to five carbon atoms where the substitute is a carboxy radical, a cyano radical, an alkoxycarbonyl radical with one to five carbon atoms, a halogen atom, an alkoxy radical with one to five carbon atoms, or a phenyl radical; R 2 and R 3 are an alkyl radical with one to five carbon atoms, a phenyl radical, or R 2 +R 3 can be (CH 2 ) n where n is 4 or 5; X is a hydrogen atom, a nitro radical, a halogen atom, a carboxy radical, an alkoxycarbonyl radical, an alkyl radical with one to five carbon atoms, or an alkoxy radical with one to five carbon atoms; and Y is a hydrogen atom, a nitro radical, a halogen atom, a formyl radical, or an alkoxy radical with one to five carbon atoms.

Claim 6

An electrophotographic element comprising an electrically conductive support member and a photoconductive layer disposed thereon, said photoconductive layer comprising an admixture of (a) organic photoconductive materials selected from the group consisting of polyvinylcarbazole, polyvinylphenothiazine and carbazoleformaldehyde resin and having a molecular weight from 1,000 to 1,000,000 and (b) quaternary salts formed by the reaction of inorganic or organic acid with indolinospirobenzopyrans, said quaternary salts being from about 1.0 to 10.0% by weight of said photoconductive materials and said indolinospirobenzopyrans being of the general formula ##STR9## wherein R 1 is a phenylradical, an alkyl radical with one to five carbon atoms, or a substituted alkyl radical with one to five carbon atoms where the substitute is a carboxy radical, a cyano radical, an alkoxycarbonyl radical with one to five carbon atoms, a halogen atom, an alkoxy radical with one to five carbon atoms, or a phenyl radical; R 2 and R 3 are an alkyl radical with one to five carbon atoms, a phenyl radical, or R 2 +R 3 can be (CH 2 ) n where n is 4 or 5; X is a hydrogen atom, a nitro radical, a halogen atom, a carboxy radical, an alkoxycarbonyl radical, an alkyl radical with one to five carbon atoms, or an alkoxy radical with one to five carbon atoms; and Y is a hydrogen atom, a nitro radical, a halogen atom, a formyl radical, or an alkoxy radical with one to five carbon atoms.

Claim 7

An electrophotographic member for electrophotographic photosensitive materials claimed in claim 1, wherein said photosensitizer contains about 1.0 to about 10 wt% of the photoconductive materials.

Claim 8

An electrophotographic process comprising the steps of charging an electrophotographic element comprising an electrically conductive support member and a photoconductive layer disposed thereon, said photoconductive layer comprising an admixture of (a) organic photoconductive materials selected from the group of heterocyclic, photoconductive materials and photoconductive materials consisting of high molecular weight of at least 1,000 selected from the group consisting of polyvinyl carbazole, polyvinylphenathiazine and carbazoleformaldehyde resin and (b) quaternary salts formed by the reaction of inorganic or organic acid with indolinospirobenzopyrans, said quaternary salts being from about 1.0 to 10.0% by weight of said photoconductive materials and said indolinospirobenzopyrans being of the general formula, ##STR10## wherein R 1 is a phenylradical, an alkyl radical with one to five carbon atoms, or a substituted alkyl radical with one to five carbon atoms where the substituent is a carboxy radical, a cyano radical, an alkoxycarbonyl radical with one to five carbon atoms, a halogen atom, an alkoxy radical with one to five carbon atoms, or a phenyl radical; R 2 and R 3 are an alkyl radical with one to five carbon atoms, a phenyl radical, or R 2 +R 3 can be (CH 2 ) n where n is 4 or 5; carboxy radical, an alkoxycarbonyl radical, an alkyl radical with one to five carbon atoms, or an alkoxy radical with one to five carbon atoms; and Y is a hydrogen atom, a nitro radical, a halogen atom, a formyl radical, or an alkoxy radical with one to five carbon atoms, projecting an image on said electrophotographic member, and developing the electrophotographic member to reproduce said image.

Claim 9

An electrophotographic process comprising the steps of charging an electrophotographic element comprising an electrically conductive support member and a photoconductive layer disposed thereon, said photoconductive layer comprising an admixture of (a) organic photoconductive materials selected from the group of heterocyclic, photoconductive materials and photoconductive materials consisting of high molecular weight of at least 1,000 selected from the group consisting of polyvinyl carbazole, polyvinylphenathiazine and carbazoleformaldehyde resin and (b) quaternary salts formed by the reaction of inorganic or organic acid with indolinospirobenzopyrans, said quaternary salts being from about 1.0 to 10.0% by weight of said photoconductive materials and said indolinospirobenzopyrans being of the general formula, ##STR10## wherein R 1 is a phenylradical, an alkyl radical with one to five carbon atoms, or a substituted alkyl radical with one to five carbon atoms where the substituent is a carboxy radical, a cyano radical, an alkoxycarbonyl radical with one to five carbon atoms, a halogen atom, an alkoxy radical with one to five carbon atoms, or a phenyl radical; R 2 and R 3 are an alkyl radical with one to five carbon atoms, a phenyl radical, or R 2 +R 3 can be (CH 2 ) n where n is 4 or 5; carboxy radical, an alkoxycarbonyl radical, an alkyl radical with one to five carbon atoms, or an alkoxy radical with one to five carbon atoms; and Y is a hydrogen atom, a nitro radical, a halogen atom, a formyl radical, or an alkoxy radical with one to five carbon atoms, projecting an image on said electrophotographic member, and developing the electrophotographic member to reproduce said image.

Claim 10

An electrophotographic process as in claim 6, wherein said inorganic salts is selected from the group consisting of hydrochloric acid, sulfuric acid, nitric acid, pherchloric acid, boron trifluoride, stannous chloride, titanium chloride, ferric chloride, phosphoric acid, phosphorous molybdenate and zinc chloride.

Claim 11

An electrophotographic process as in claim 6, wherein said organic salts is selected from the group consisting of oxalic acid, acetic acid, benzenesulfonic acid, toluene-sulfonic acid, salicylic acid, picric acid, dimethylsulfuric acid and diethylsulfuric acid.

Claim 12

An electrophotographic process as in claim 6, wherein said photosensitive materials are selected from the group consisting of polyvinylcarbazole, polyvinylphenothiazine and carbazoleformaldehyde resin and have a molecular weight from 1000 to 1,000,000.

Claim 13

An electrophotographic process as in claim 6, wherein said photosensitizer contains about 1.0 to about 10 wt% of the photoconductive materials.