US3933509A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Photo-polymerizable composition containing an acid salt of an indolinobenzospiropyran
Assignee: Fujifilm Holdings Corp
•
Filing: 1973-08-22
•
Granted: 1976-01-20
•
Expires: 1993-08-22
Abstract
Abstract A photo-polymerizable composition comprising (A) a photopolymerization initiator comprising at least one inorganic or organic acid salt of an indolinobenzospiropyran represented by the following general formula (I): ##SPC1## wherein R 1 represents an alkyl group, substituted alkyl group or a phenyl group; R 2 and R 3 each represents an alkyl group or a phenyl group or, when taken together, R 2 and R 3 form a methylene chain CH 2 wherein n is an integer of 4 or 5; X represents a hydrogen atom, a nitro group, a halogen atom, a carboxy group; and Y represents one or more substituents selected from the group consisting of a hydrogen atom, a nitro group, a halogen atom, a formyl group and an alkoxy group, and (B) at least one cationically polymerizable substance.
Inventors
- 👤 Yasuhiro Noguchi
- 👤 Syu Watarai
- 👤 Chiaki Osada
- 👤 Hisatake Ono
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 20:24
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/26; G03F7/34; G03F7/346; C; C08; C08F; C08F2/00; C08F2/46; G03F7/004; G03F7/027; G03F7/028; G03F7/029; G03F7/031; G03F7/28; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/107; Y10S430/108; Y10S430/111; Y10S430/114; Y10S430/115; Y10S430/116; Y10S430/127; Y10S522/00; Y10S522/91
Claims Analysis
Total Claims: 17
Claim 1
Independent Claim
172 words
A photo-polymerizable composition comprising (A) a photo-polymerization initiator comprising at least one inorganic or organic acid salt of a Lewis acid or proton acid effective as an initiator for cationic polymerization and an indolinobenzospiropyran represented by the following general formula (I); ##SPC3## wherein R 1 represents an alkyl group, substituted alkyl group or a phenyl group; R 2 and R 3 each represents an alkyl group or a phenyl group or, when taken together, R 2 and R 3 form a methylene chain -CH 2 - n wherein n is an integer of 4 to 5; X represents a hydrogen atom, a nitro group, a halogen atom, a carboxy group, an alkoxycarbonyl group, an alkyl group or an alkoxy group; and Y represents one or more substituents selected from the group consisting of a hydrogen atom, a nitro group, a halogen atom, a formyl group and an alkoxy group, and (B) at least one cationically polymerizable substance having an ethylenically unsaturated bond or having a cyclic group capable of ring-opening for polymerization.
Claim 2
Dependent Claim
172 words
A photo-polymerizable composition comprising (A) a photo-polymerization initiator comprising at least one inorganic or organic acid salt of a Lewis acid or proton acid effective as an initiator for cationic polymerization and an indolinobenzospiropyran represented by the following general formula (I); ##SPC3## wherein R 1 represents an alkyl group, substituted alkyl group or a phenyl group; R 2 and R 3 each represents an alkyl group or a phenyl group or, when taken together, R 2 and R 3 form a methylene chain -CH 2 - n wherein n is an integer of 4 to 5; X represents a hydrogen atom, a nitro group, a halogen atom, a carboxy group, an alkoxycarbonyl group, an alkyl group or an alkoxy group; and Y represents one or more substituents selected from the group consisting of a hydrogen atom, a nitro group, a halogen atom, a formyl group and an alkoxy group, and (B) at least one cationically polymerizable substance having an ethylenically unsaturated bond or having a cyclic group capable of ring-opening for polymerization.
Claim 3
Dependent Claim
174 words
The photo-polymerizable composition as described in claim 1, wherein R 1 represents an alkyl group having 1 - 5 carbon atoms; a substituted alkyl group having 1 - 5 carbon atoms, said substituent being a carboxy group, cyano group, an alkoxycarbonyl group having 1 - 5 carbon atoms, a hydroxy group, a halogen atom, an alkoxy group having 1 - 5 carbon atoms or a phenyl group; or a phenyl group or, when taken together, R 2 and R 3 form a methylene chain -CH 2 - n wherein n is an integer of 4 or 5; X represents a hydrogen atom, a nitro group, a halogen atom, a carboxy group, an alkoxycarbonyl group having 2 - 6 carbon atoms, an alkyl group having 1 - 5 carbon atoms or an alkoxy group having 1 - 5 carbon atoms; and Y represents one or more substituents selected from the group consisting of a hydrogen atom, a nitro group, a halogen atom, a formyl group and an alkoxy group having 1 - 5 carbon atoms.
Claim 4
Dependent Claim
34 words
The photo-polymerizable composition as described in claim 2, wherein said acid salt of indolinobenzospiropyran (A) is capable of forming free acid when irradiated with an actinic radiation of 250 - 700 mμ in wavelength.
Claim 5
Dependent Claim
56 words
The photo-polymerizable composition as described in claim 2, wherein said acid salt of said indolinobenzospiropyran (A) comprises at least one salt selected from the hydrochloric salt, nitrate salt, perchlorate salt, acetate salt, sulfanilate salt, benzenesulfonate salt, toluenesulfonate salt, dinitro-o-cresol salt, picrate salt, salicylate salt, boron trifluoroetherate, ferric chloride salt, titanium trichloride salt, and stannous chloride salt.
Claim 6
Dependent Claim
24 words
The photo-polymerizable composition as described in claim 2, wherein said cation-polymerizable substance comprises at least one of the vinyl ethers or the N-vinyl compounds.
Claim 7
Dependent Claim
110 words
The photo-polymerizable composition as described in claim 5, wherein said vinyl ether is a compound represented by the general formula (II): ##EQU2## wherein X represents an alkyl group having 1 - 20 carbon atoms or a substituted alkyl group having 1- 5 carbon atoms, said substituent being a halogen atom, an alkoxy group having 1 - 10 carbon atoms, an alkyl group in which the carbon chain is interrupted with at least one oxygen atom, an aryloxy group, an arylcarboxy group, a haloaryloxy group, an alkylaryloxy group having 1 - 5 carbon atoms in the alkyl moiety, or an alkoxyaryloxy having 1 - 5 carbon atoms in the alkoxy moiety.
Claim 8
Dependent Claim
86 words
The photo-polymerizable composition as described in claim 6, wherein said compound represented by the general formula (II) is methyl vinyl ether, ethyl vinyl ether, isobutyl vinyl ether, diisopropylmethyl vinyl ether, decyl vinyl ether, cetyl vinyl ether, 2-chloroethyl vinyl ether, 2-methoxyethyl vinyl ether, 2-(2-ethoxyethoxy)-ethyl vinyl ether, 2-phenoxyethyl vinyl ether, α-naphthoxyethyl vinyl ether, 2-(2,4,6-trichlorophenoxy)-ethyl vinyl ether, 2-(2,4,5-trichlorophenoxy)-ethyl vinyl ether, 2-(2,4,6-tribromophenoxy) ethyl vinyl ether, p-methoxy-naphthoxyethyl vinyl ether, p-methoxyphenoxyethyl vinyl ether, 2-vinyloxyethyl benzoate, 3,5-dimethylphenoxyethyl vinyl ether, pentaerythritol tetravinyl ether, p-bis-2-vinyloxyethoxybenzene, 2,2-bis-(3',5'-dibromo-4'-vinyloxyethoxyphenyl)propane, 2,2-bis-(p-vinyloxyethoxyphenyl) propane, tetraethylene glycol divinyl ether or poly(2-vinyloxyethyl methacrylate).
Claim 9
Dependent Claim
18 words
The photo-polymerizable composition as described in claim 5, wherein said N-vinyl comound is N-vinylcarbazole, N-vinylpyrrolidone or derivatives thereof.
Claim 10
Dependent Claim
34 words
The photo-polymerizable composition as described in claim 2, wherein the amount of said acid salt of indolinobenzospiropyran (A) is 0.0001% to 15% by weight based on the total amount of the cation-polymerizable compound (B).
Claim 11
Dependent Claim
17 words
The photo-polymerizable composition as described in claim 2, wherein said photo-polymerizable composition contains a spectrally sensitizing dye.
Claim 12
Dependent Claim
38 words
The photo-polymerizable composition as described in claim 10, wherein said sentizing dye is at least one of cyanine dyes, the merocyanine dyes, the triphenylmethane dyes, the acridine dyes, the thiazine dyes, the xanthene dyes or the anthraquinone dyes.
Claim 13
Dependent Claim
36 words
The photo-polymerizable composition as described in claim 2, wherein said photo-polymerizable composition contains at least one of a colorant, a thickening agent, a plasticizer, a thermally fusible compound, a diluent or an organic or inorganic filler.
Claim 14
Dependent Claim
16 words
The photo-polymerizable composition as described in claim 2, wherein said photo-polymerizable composition contains a film-forming binder.
Claim 15
Dependent Claim
59 words
The photo-polymerizable composition as described in claim 13, wherein said film-forming binder is at least one of paraffin, chlorinated paraffin, wax, polyolefin chloride, polyacrylic ester, polymethacrylic ester, vinyl polymer, vinylidene polymer, polyamide, polycarbonate, cellulose derivative, vinyl chloride-vinyl acetate copolymer, vinylidene chlorideacrylonitrile copolymer, styrene-butadiene copolymer, polyisobutylene, phenol-formamide resin, ketone resin, chlorinated rubber, gelatin, polyvinyl alcohol, or polyvinyl acetal forming binder.
Claim 16
Dependent Claim
17 words
A photo-polymerizable light-sensitive material comprising a support having thereon the photo-polymerizable composition as described in claim 2.
Claim 17
Dependent Claim
59 words
The photo-polymerizable light-sensitive material as described in claim 15, wherein said support is a cellulose derivative film, a polyvinyl compound film, a polyester film, a poly-γ-olefin film, said olefin having 2 - 10 carbon atoms, a polycarbonate film, a polyolefin laminated paper, a polyolefin laminated metal plate, a polyolefin laminated ceramic plate, a metal plate or a ceramic plate.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-01-19 | 1979-07-21 | 1980-01-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-01-19 | 1983-07-21 | 1984-01-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-01-19 | 1987-07-21 | 1988-01-20 | $7700.00 | Window Closed / Lapsed |