Process for preparation of solid phase dispersion of photoconductive materials

Claim 2

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in an insulating matrix comprising a polymer capable of transport of charge carriers, said process comprising: a. forming a polymeric composition from a film forming insulating polymer capable of transport of charge carriers and an organo-selenium compound capable of selectively undergoing carbon-selenium bond scission when subjected to a source of electromagnetic, thermal or electron beam energy; and b. forming elemental selenium within the insulating polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 3

The process of claim 1, wherein the relative weight ratio of organo selenium compound to film forming polymeric resin in the polymeric composition, prior to the deposition of elemental selenium, can range from about 10:90 to 90:10.

Claim 4

The process of claim 1, wherein the energy source is ultraviolet light.

Claim 5

The process of claim 1, wherein the energy source is visible light.

Claim 6

The process of claim 1, wherein the energy source is an electron beam.

Claim 7

The process of claim 1, wherein the energy uniformly blankets the exposed surface of the polymeric composition.

Claim 8

The process of claim 1, wherein the energy selectively impinges the surface of the polymeric composition.

Claim 9

The process of claim 1, wherein the energy is capable of substantial penetration below the surface of the polymeric composition.

Claim 10

The process of claim 1, wherein the energy is incapable of substantial penetration below the surface of the polymeric composition.

Claim 11

The process of claim 1, wherein the solid phase dispersion is heated subsequent to selenium deposition for the purpose of promoting selenium crystal growth, the duration of said heating and temperature to which the dispersion is exposed being insufficient to effect substantial depletion of elemental selenium from the dispersion.

Claim 12

The process of claim 1, wherein elemental selenium is deposited in response to thermal radiation.

Claim 13

The process of claim 1, wherein the relative weight ratio of organo-selenium compound to polymer in the polymeric composition, prior to extrusion and deposition of elemental selenium, can range from about 20:80 to about 30:70.

Claim 14

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating polymer capable of transport of charge carriers, said process comprising: a. forming a polymeric composition from a film forming insulating polymer capable of transport of charge carriers and at least one organo-selenium compound of the formula R -- (Se).sub.n -- R.sub.1 wherein R and R 1 are independently selected from the group consisting of benzyl, alkyl substituted benzyl, alkoxy substituted benzyl, acyl substituted benzyl, amino substituted benzyl, amido substituted benzyl, arylalkyl substituted benzyl, aryl substituted benzyl, alkoxy alkyl substituted benzyl, aryloxy alkyl substituted benzyl, amino alkyl substituted benzyl, hydroxy alkyl substituted benzyl, alkyl amino substituted benzyl, aryl amino substituted benzyl, alkyl carbonyl substituted benzyl, alkyl thio substituted benzyl, alkyl seleno substituted benzyl, carboxamido substituted benzyl, halogen substituted benzyl, carboxyl substituted benzyl, cyano substituted benzyl, and nitro substituted benzyl; alkyl, alkoxy, amino substituted alkyl, amido substituted alkyl, aryl alkyl, alkoxy alkyl, aryloxy alkyl, hydroxy substituted alkyl, carbonyl substituted alkyl, thio substituted alkyl, seleno substituted alkyl, carboxamido substituted alkyl, halogen substituted alky, carboxy substituted alkyl, cyano substituted alkyl, and nitro substituted alkyl; cyclo alkyl and substituted cyclo alkyl; heterocyclic radicals; and acyl radicals; n is about 1 to about 4; and b. forming elemental selenium within the insulating polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 15

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating polymer capable of transport of charge carriers, said process comprising: a. forming a polymeric composition from a film forming insulating polymer capable of transport of charge carriers and at least one organo-selenium compound of the formula R -- (Se).sub.n -- R.sub.1 wherein R and R 1 are independently selected from the group consisting of benzyl, alkyl substituted benzyl, alkoxy substituted benzyl, acyl substituted benzyl, amino substituted benzyl, amido substituted benzyl, arylalkyl substituted benzyl, aryl substituted benzyl, alkoxy alkyl substituted benzyl, aryloxy alkyl substituted benzyl, amino alkyl substituted benzyl, hydroxy alkyl substituted benzyl, alkyl amino substituted benzyl, aryl amino substituted benzyl, alkyl carbonyl substituted benzyl, alkyl thio substituted benzyl, alkyl seleno substituted benzyl, carboxamido substituted benzyl, halogen substituted benzyl, carboxyl substituted benzyl, cyano substituted benzyl, and nitro substituted benzyl; alkyl, alkoxy, amino substituted alkyl, amido substituted alkyl, aryl alkyl, alkoxy alkyl, aryloxy alkyl, hydroxy substituted alkyl, carbonyl substituted alkyl, thio substituted alkyl, seleno substituted alkyl, carboxamido substituted alkyl, halogen substituted alky, carboxy substituted alkyl, cyano substituted alkyl, and nitro substituted alkyl; cyclo alkyl and substituted cyclo alkyl; heterocyclic radicals; and acyl radicals; n is about 1 to about 4; and b. forming elemental selenium within the insulating polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 16

The process of claim 13 wherein R 1 and R 2 are benzyl.

Claim 17

The process of claim 13 wherein at least one of R 1 or R 2 are alkyl.

Claim 18

The process of claim 13 wherein the polymeric matrix comprises poly(N-vinylcarbazole).

Claim 19

The process of claim 13 wherein the polymeric matrix comprises poly(vinylpyrene).

Claim 20

The process of claim 13 wherein the polymeric matrix comprises poly(N-ethyl-3-vinylcarbazole).

Claim 21

The process of claim 13 wherein elemental selenium is deposited in response to ultraviolet light.

Claim 22

The process of claim 13 wherein elemental selenium is deposited in response to a thermal radiation.

Claim 23

The process of claim 13 wherein the relative weight ratio of organo-selenium compound to polymer in the polymeric composition, prior to deposition of elemental selenium, can range from about 10:90 to about 90:10.

Claim 24

The process of claim 13 wherein the relative weight ratio of organo-selenium compound to polymer in the polymeric composition, prior to deposition of elemental selenium, can range from about 20:80 to about 30:70.

Claim 25

The process of claim 13 wherein the elemental selenium is deposited at random.

Claim 26

The process of claim 13 wherein the elemental selenium is deposited selectively.

Claim 27

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating hole transport polymer, said process comprising: a. forming a polymeric composition from a film forming insulating hole transport polymer and an organo-selenium compound capable of selectively undergoing carbon-selenium bond scission when subjected to a source of electromagnetic, thermal or electron beam energy; and b. forming elemental selenium within the insulating hole transport polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said matrix to said energy.

Claim 28

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating hole transport polymer, said process comprising: a. forming a polymeric composition from a film forming insulating hole transport polymer and an organo-selenium compound capable of selectively undergoing carbon-selenium bond scission when subjected to a source of electromagnetic, thermal or electron beam energy; and b. forming elemental selenium within the insulating hole transport polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said matrix to said energy.

Claim 29

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating hole transport polymer, said process comprising: a. forming a polymeric composition from a film forming insulating hole transport polymer and at least one organo-selenium compound of the formula R -- (Se).sub.n -- R.sub.1 wherein R and R 1 are independently selected from the group consisting of benzyl, alkyl substituted benzyl, alkoxy substituted benzyl, acyl substituted benzyl, amino substituted benzyl, amido substituted benzyl, arylalkyl substituted benzyl, aryl substituted benzyl, alkoxy alkyl substituted benzyl, aryloxy alkyl substituted benzyl, amino alkyl substituted benzyl, hydroxy alkyl substituted benzyl, alkyl amino substituted benzyl, aryl amino substituted benzyl, alkyl carbonyl substituted benzyl, alkyl thio substituted benzyl, alkyl seleno substituted benzyl, carboxamido substituted benzyl, halogen substituted benzyl, carboxyl substituted benzyl, cyano substituted benzyl, and nitro substituted benzyl; alkyl, alkoxy, amino substituted alkyl, amido substituted alkyl, aryl alkyl, alkoxy alkyl, aryloxy alkyl, hydroxy substituted alkyl, carbonyl substituted alkyl, thio substituted alkyl, seleno substituted alkyl, carboxamido substituted alkyl, halogen substituted alky, carboxy substituted alkyl, cyano substituted alkyl, and nitro substituted alkyl; cyclo alkyl and substituted cyclo alkyl; heterocyclic radicals; and acyl radicals; n is about 1 to about 4; and b. forming elemental selenium within the insulating polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 30

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating hole transport polymer, said process comprising: a. forming a polymeric composition from a film forming insulating hole transport polymer and at least one organo-selenium compound of the formula R -- (Se).sub.n -- R.sub.1 wherein R and R 1 are independently selected from the group consisting of benzyl, alkyl substituted benzyl, alkoxy substituted benzyl, acyl substituted benzyl, amino substituted benzyl, amido substituted benzyl, arylalkyl substituted benzyl, aryl substituted benzyl, alkoxy alkyl substituted benzyl, aryloxy alkyl substituted benzyl, amino alkyl substituted benzyl, hydroxy alkyl substituted benzyl, alkyl amino substituted benzyl, aryl amino substituted benzyl, alkyl carbonyl substituted benzyl, alkyl thio substituted benzyl, alkyl seleno substituted benzyl, carboxamido substituted benzyl, halogen substituted benzyl, carboxyl substituted benzyl, cyano substituted benzyl, and nitro substituted benzyl; alkyl, alkoxy, amino substituted alkyl, amido substituted alkyl, aryl alkyl, alkoxy alkyl, aryloxy alkyl, hydroxy substituted alkyl, carbonyl substituted alkyl, thio substituted alkyl, seleno substituted alkyl, carboxamido substituted alkyl, halogen substituted alky, carboxy substituted alkyl, cyano substituted alkyl, and nitro substituted alkyl; cyclo alkyl and substituted cyclo alkyl; heterocyclic radicals; and acyl radicals; n is about 1 to about 4; and b. forming elemental selenium within the insulating polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 31

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating electron transport polymer, said process comprising: a. forming a polymeric composition from a film forming insulating electron transport polymer and an organo-selenium compound capable of selectively undergoing carbon-selenium bond scission when subjected to a source of electromagnetic, thermal or electron beam energy; and b. forming elemental selenium within the insulating electron transport polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 32

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating electron transport polymer, said process comprising: a. forming a polymeric composition from a film forming insulating electron transport polymer and an organo-selenium compound capable of selectively undergoing carbon-selenium bond scission when subjected to a source of electromagnetic, thermal or electron beam energy; and b. forming elemental selenium within the insulating electron transport polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 33

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating electron transport polymer, said process comprising: a. forming a polymeric compositions from a film-forming insulating electron transport polymer and at least one organo-selenium compound of the formula R -- (Se).sub.n -- R.sub.1 wherein R and R 1 are independently selected from the group consisting of benzyl, alkyl substituted benzyl, alkoxy substituted benzyl, acyl substituted benzyl, amino substituted benzyl, amido substituted benzyl, arylalkyl substituted benzyl, aryl substituted benzyl, alkoxy alkyl substituted benzyl, aryloxy alkyl substituted benzyl, amino alkyl substituted benzyl, hydroxy alkyl substituted benzyl, alkyl amino substituted benzyl, aryl amino substituted benzyl, alkyl carbonyl substituted benzyl, alkyl thio substituted benzyl, alkyl seleno substituted benzyl, carboxamido substituted benzyl, halogen substituted benzyl, carboxyl substituted benzyl, cyano substituted benzyl, and nitro substituted benzyl; alkyl, alkoxy, amino substituted alkyl, amido substituted alkyl, aryl alkyl, alkoxy alkyl, aryloxy alkyl, hydroxy substituted alkyl, carbonyl substituted alkyl, thio substituted alkyl, seleno substituted alkyl, carboxamido substituted alkyl, halogen substituted alkyl, carboxy substituted alkyl, cyano substituted alkyl, and nitro substituted alkyl; cyclo alkyl and substituted cyclo alkyl; heterocyclic radicals; and acyl radicals; n is about 1 to about 4; and b. forming elemental selenium within the insulating electron transport polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.

Claim 34

A process for preparation of a solid phase dispersion of inorganic photoconductive materials in a matrix comprising an insulating electron transport polymer, said process comprising: a. forming a polymeric compositions from a film-forming insulating electron transport polymer and at least one organo-selenium compound of the formula R -- (Se).sub.n -- R.sub.1 wherein R and R 1 are independently selected from the group consisting of benzyl, alkyl substituted benzyl, alkoxy substituted benzyl, acyl substituted benzyl, amino substituted benzyl, amido substituted benzyl, arylalkyl substituted benzyl, aryl substituted benzyl, alkoxy alkyl substituted benzyl, aryloxy alkyl substituted benzyl, amino alkyl substituted benzyl, hydroxy alkyl substituted benzyl, alkyl amino substituted benzyl, aryl amino substituted benzyl, alkyl carbonyl substituted benzyl, alkyl thio substituted benzyl, alkyl seleno substituted benzyl, carboxamido substituted benzyl, halogen substituted benzyl, carboxyl substituted benzyl, cyano substituted benzyl, and nitro substituted benzyl; alkyl, alkoxy, amino substituted alkyl, amido substituted alkyl, aryl alkyl, alkoxy alkyl, aryloxy alkyl, hydroxy substituted alkyl, carbonyl substituted alkyl, thio substituted alkyl, seleno substituted alkyl, carboxamido substituted alkyl, halogen substituted alkyl, carboxy substituted alkyl, cyano substituted alkyl, and nitro substituted alkyl; cyclo alkyl and substituted cyclo alkyl; heterocyclic radicals; and acyl radicals; n is about 1 to about 4; and b. forming elemental selenium within the insulating electron transport polymer in conformity with the distribution of electromagnetic, thermal or electron beam energy therein by subjecting the organo-selenium compounds contained within said polymer to said energy.