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US3990992A Expired / Lapsed US ⏱️ 0.0 years remaining

Regeneration of cracking catalyst in a vessel with a partition forming an upper and lower zone

Assignee: Standard Oil Co
•
Filing: 1974-04-12
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Granted: 1976-11-09
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Expires: 1994-04-12
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Abstract

Abstract In a fluidized cracking unit, the cracking catalyst regeneration vessel is specially adapted for high temperature operation to permit essentially complete combustion of coke on the spent catalyst particles and, in addition, the essentially complete combustion of carbon monoxide produced thereby, within the dense phase zone of the regenerator. A partition in the regenerator divides the lower dense phase zone operating at high temperatures from the upper dilute phase zone which may be cooled, for instance, by boiler tubes, water sprays and the like. The partition contains one or more rough separation catalyst knock-out means such as cyclone separators whereby hot catalyst particles are separated from the rising combusted gases and returned to the dense phase regeneration zone. In one embodiment, the regeneration vessel is elongated to facilitate recovery of most of the extra heat produced by complete carbon monoxide combustion by the catalyst particles returning to the dense phase zone. This invention is directed to both the high temperature dense phase zone catalyst regeneration process and to the apparatus employed in the process.

Inventors

  • 👤 Claude O. McKinney

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 12:40
CPC Classifications
B; B01; B01J; B01J8/00; B01J8/18; B01J8/24; B01J8/26; B01J8/28; C; C10; C10G; C10G11/00; C10G11/14; C10G11/18; C10G11/182

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 352 words
A process for the regeneration of a fluidizable cracking catalyst which has been deactivated with coke deposits while employed in a catalytic hydrocarbon cracking process, comprising the steps of passing coked catalyst particles to a lower portion of a regeneration vessel, said regeneration vessel having a partition dividing said vessel into a lower zone and an upper zone and said partition being at a position which is about 25 to 80 percent of the internal height of the vessel; contacting the coked catalyst particles in the lower zone of the regeneration vessel with an oxygen-containing regeneration gas stream at fluidizing velocities, said gas stream providing at least sufficient oxygen for burning coke from the catalyst particles and for essentially complete combustion of the resulting carbon monoxide formed during the burning of the coke; burning the coke from the catalyst particles within the lower zone which contains a dense catalyst phase, and essentially completely combusting resulting carbon monoxide while the carbon monoxide and oxygen-containing regeneration gas are within the lower zone, wherein said partition, in conjunction with the burning, facilitates the maintenance of temperatures sufficient for essentially complete combustion of carbon monoxide within the lower zone while in contact with said catalyst particles in an amount sufficient to absorb a major amount of heat resulting from the carbon monoxide combustion and avoid temperatures which may be damaging to catalyst particles; passing the resulting combustion gases and entrained catalyst particles through catalyst separation means whereby most of the catalyst particles are returned to the lower zone and the combustion gases with remaining entrained catalyst particles are sent to the upper zone wherein said combustion gases, with the remaining entrained catalyst particles, reach a temperature which is lower than in said separation means; passing the combustion gases with remaining entrained catalyst particles through catalyst separation means in the upper zone, whereby particles separated from the combustion gases are returned to the lower zone, and the combustion gases having a low carbon monoxide content are exhausted; and withdrawing regenerated catalyst particles having a low content of residual coke, from the lower zone of the regeneration vessel.
Claim 2
Dependent Claim 352 words
A process for the regeneration of a fluidizable cracking catalyst which has been deactivated with coke deposits while employed in a catalytic hydrocarbon cracking process, comprising the steps of passing coked catalyst particles to a lower portion of a regeneration vessel, said regeneration vessel having a partition dividing said vessel into a lower zone and an upper zone and said partition being at a position which is about 25 to 80 percent of the internal height of the vessel; contacting the coked catalyst particles in the lower zone of the regeneration vessel with an oxygen-containing regeneration gas stream at fluidizing velocities, said gas stream providing at least sufficient oxygen for burning coke from the catalyst particles and for essentially complete combustion of the resulting carbon monoxide formed during the burning of the coke; burning the coke from the catalyst particles within the lower zone which contains a dense catalyst phase, and essentially completely combusting resulting carbon monoxide while the carbon monoxide and oxygen-containing regeneration gas are within the lower zone, wherein said partition, in conjunction with the burning, facilitates the maintenance of temperatures sufficient for essentially complete combustion of carbon monoxide within the lower zone while in contact with said catalyst particles in an amount sufficient to absorb a major amount of heat resulting from the carbon monoxide combustion and avoid temperatures which may be damaging to catalyst particles; passing the resulting combustion gases and entrained catalyst particles through catalyst separation means whereby most of the catalyst particles are returned to the lower zone and the combustion gases with remaining entrained catalyst particles are sent to the upper zone wherein said combustion gases, with the remaining entrained catalyst particles, reach a temperature which is lower than in said separation means; passing the combustion gases with remaining entrained catalyst particles through catalyst separation means in the upper zone, whereby particles separated from the combustion gases are returned to the lower zone, and the combustion gases having a low carbon monoxide content are exhausted; and withdrawing regenerated catalyst particles having a low content of residual coke, from the lower zone of the regeneration vessel.
Claim 3
Dependent Claim 19 words
The process of claim 1 wherein said combusted gases with any entrained particles are cooled in said upper zone.
Claim 4
Dependent Claim 25 words
The process of claim 1 wherein the regeneration temperature within the lower zone is maintained in the range from about 1150° to about 1450° F.
Claim 5
Dependent Claim 23 words
The process of claim 3 wherein the temperature within the lower zone is maintained in the range from about 1250° to 1400° F.
Claim 6
Dependent Claim 24 words
The process of claim 1 wherein the temperature in the upper zone is maintained in the range from about 1150° to about 1275° F.
Claim 7
Dependent Claim 16 words
The process of claim 5 wherein said temperature in the upper zone is controlled by cooling.
Claim 8
Dependent Claim 17 words
The process of claim 1 wherein the catalyst comprises silica and alumina together with a crystalline aluminosilicate.
Claim 9
Dependent Claim 19 words
The process of claim 7 wherein the catalyst comprises between about 1 and about 15 wt. % crystalline aluminosilicate.
Claim 10
Dependent Claim 19 words
The process of claim 1 wherein the regenerated catalyst particles contain no more than about 0.05 wt. % coke.
Claim 11
Dependent Claim 19 words
The process of claim 9 wherein the regenerated catalyst particles contain no more than about 0.03 wt. % coke.
Claim 12
Dependent Claim 20 words
The process of claim 1 wherein the flue gas stream contains no more than about 0.2 vol. % carbon monoxide.
Claim 13
Dependent Claim 27 words
The process of claim 11 wherein the carbon monoxide content of the flue gas stream is in the range from about 0 ppm. to about 500 ppm.
Claim 14
Dependent Claim 106 words
The process of claim 1 wherein the regeneration gas stream comprises air flowing upwardly from the lower zone to fluidize the catalyst particles, the temperature within the lower zone is maintained within the range from about 1250° to about 1400° F., the temperature within the upper zone is maintained within the range from about 1150° to about 1275° F., the regenerated catalyst particles contain less than 0.10 wt. % coke, flue gas stream withdrawn from the regeneration vessel contains less than 1.0 vol. % carbon monoxide, and the temperature in the upper zone is at least about 100° F. less than that in the lower zone.
Claim 15
Dependent Claim 20 words
The process of claim 13 wherein the regenerated catalyst particles contain from about 0.01 to about 0.05 wt. % coke.
Claim 16
Dependent Claim 27 words
The process of claim 14 wherein the carbon monoxide content of the flue gas stream is within the range from about 0.05 to about 0.20 vol. %.
Claim 17
Dependent Claim 26 words
The process of claim 14 wherein the carbon monoxide content of the flue gas stream is in the range of 0 ppm. to about 500 ppm.
Claim 18
Dependent Claim 30 words
The process of claim 1 wherein the combusted gases with any remaining entrained catalyst particles are passed through the upper zone at a higher velocity than through the lower zone.
Claim 19
Dependent Claim 19 words
The process of claim 17 wherein the upper zone higher velocity is at least twice the lower zone velocity.

References Cited (Backward Citations)

US2419245A Cited
US2382382A Cited
US3083082A Cited
DE2256276A1 Cited
US3843330A Cited
US3844973A Cited
US3838036A Cited
US3856659A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-09 1980-05-10 1980-11-09 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-09 1984-05-10 1984-11-09 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-09 1988-05-10 1988-11-09 $7700.00 Window Closed / Lapsed

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