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US3989798A Expired / Lapsed US ⏱️ 0.0 years remaining

Regenerating flue gas desulfurization catalysts with reducing gas

Assignee: ExxonMobil Technology and Engineering Co
•
Filing: 1973-07-23
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Granted: 1976-11-02
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Expires: 1993-07-23
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Abstract

Abstract Flue gas is desulfurized by absorbing it onto a selective absorbent-catalytic material. The absorbed SO 2 is recovered by contacting it in a desorption cycle with a reducing desorption gas. In one embodiment, multiple absorbent beds are employed and alternate absorption-desorption cycles are used in each of the multiple beds with the flue gas and the desorption gas used alternately. The sulfur oxide is recovered in concentrated form in the desorption gas stream and is then utilized as feed in a conventional sulfuric acid plant yielding concentrated sulfuric acid.

Inventors

  • 👤 David F. Greene
  • 👤 Robert J. Lang
  • 👤 Albert B. Welty, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 11:03
CPC Classifications
C; C01; C01B; C01B17/00; C01B17/48; C01B17/50; C01B17/60; B; B01; B01D; B01D53/00; B01D53/34; B01D53/74; B01D53/86; B01D53/8603; B01D53/8609; C01B17/69; C01B17/74; C01B17/76; F; F23; F23J; F23J2215/00; F23J2215/20; F23J2219/00; F23J2219/60

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 131 words
A process for the removal of SO 2 from a flue gas stream containing such flue gas and the production of a concentrated stream of SO 2 , said process comprising the steps of passing the flue gas at a temperature in the range of about 600° to 900° F. into contact with an absorbent-catalyst material comprising vanadium oxide supported on an inorganic oxide carrier whereby SO 2 is absorbed from the flue gas and a stream of flue gas relatively free of SO 2 is obtained and then in a separate cycle, contacting the absorbent-catalyst material containing absorbed SO 2 with a reducing desorption agent at a temperature in the range of about 800° to 900° F. whereby SO 2 is desorbed from the absorbent-catalyst into the desorption gas stream.
Claim 2
Dependent Claim 131 words
A process for the removal of SO 2 from a flue gas stream containing such flue gas and the production of a concentrated stream of SO 2 , said process comprising the steps of passing the flue gas at a temperature in the range of about 600° to 900° F. into contact with an absorbent-catalyst material comprising vanadium oxide supported on an inorganic oxide carrier whereby SO 2 is absorbed from the flue gas and a stream of flue gas relatively free of SO 2 is obtained and then in a separate cycle, contacting the absorbent-catalyst material containing absorbed SO 2 with a reducing desorption agent at a temperature in the range of about 800° to 900° F. whereby SO 2 is desorbed from the absorbent-catalyst into the desorption gas stream.
Claim 3
Dependent Claim 15 words
The process of claim 1 wherein said absorbent-catalyst material contains an alkali metal oxide promoter.
Claim 4
Dependent Claim 12 words
The process of claim 1 in which the reducing agent is hydrogen.
Claim 5
Dependent Claim 18 words
The process of claim 1 in which the reducing agent is a mixture of carbon monoxide and hydrogen.
Claim 6
Dependent Claim 31 words
A process according to claim 1 in which said absorbent-catalyst material is contacted with said reducing desorption agent at a temperature in the range of about 800° to about 800° F.

References Cited (Backward Citations)

US3411865A Cited
US3454356A Cited
US3501897A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-11-02 1980-05-03 1980-11-02 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-11-02 1984-05-03 1984-11-02 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-11-02 1988-05-03 1988-11-02 $7700.00 Window Closed / Lapsed

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