Claims Analysis
Total Claims: 21
Claim 1
Independent Claim
252 words
A process for the hydrocarbonization of coal particles employing a fluid-bed zone of hydrocarbonization comprising: a. fluidizing coal particles with a non-oxidizing gas to form a dense phase; b. pressurizing said particles with a hydrogen-rich gas; c. preheating said coal particles in said dense phase in an essentially oxygen-free environment to a predetermined temperature below a temperature at which said coal particles undergo plastic transformation; d. providing a fluid-bed within a hydrocarbonization zone at a reaction temperature of between about 480° C and about 600° C, said fluid-bed consisting essentially of a matrix of non-agglomerating coal and char particles at said reaction temperature fluidized by a hydrogenrich, oxygen-free gas; e. continuously introducing said preheating coal particles and a hydrogen-rich, oxygen-free conveying gas into the lower portion of said zone in an essentially vertically upwards direction, said coal particles having a velocity sufficient to rapidly and uniformly disperse at said predetermined temperature, within said matrix, said velocity being greater than about 200 feet per second; f. continuously reacting said coal particles in said zone with hydrogen in said zone at said reaction temperature to produce a product comprising a condensable vapor and solid char; g. maintaining the solids in said zone for an average residence time of about 5 to about 60 minutes and said vapor for about 10 to about 250 seconds; h. maintaining the average hydrogen partial pressure in said zone at about 100 p.s.i. to about 1200 p.s.i.; and i. continuously withdrawing from said zone said product vapor and solids.
Claim 2
Dependent Claim
252 words
A process for the hydrocarbonization of coal particles employing a fluid-bed zone of hydrocarbonization comprising: a. fluidizing coal particles with a non-oxidizing gas to form a dense phase; b. pressurizing said particles with a hydrogen-rich gas; c. preheating said coal particles in said dense phase in an essentially oxygen-free environment to a predetermined temperature below a temperature at which said coal particles undergo plastic transformation; d. providing a fluid-bed within a hydrocarbonization zone at a reaction temperature of between about 480° C and about 600° C, said fluid-bed consisting essentially of a matrix of non-agglomerating coal and char particles at said reaction temperature fluidized by a hydrogenrich, oxygen-free gas; e. continuously introducing said preheating coal particles and a hydrogen-rich, oxygen-free conveying gas into the lower portion of said zone in an essentially vertically upwards direction, said coal particles having a velocity sufficient to rapidly and uniformly disperse at said predetermined temperature, within said matrix, said velocity being greater than about 200 feet per second; f. continuously reacting said coal particles in said zone with hydrogen in said zone at said reaction temperature to produce a product comprising a condensable vapor and solid char; g. maintaining the solids in said zone for an average residence time of about 5 to about 60 minutes and said vapor for about 10 to about 250 seconds; h. maintaining the average hydrogen partial pressure in said zone at about 100 p.s.i. to about 1200 p.s.i.; and i. continuously withdrawing from said zone said product vapor and solids.
Claim 3
Dependent Claim
32 words
A process as defined in claim 1 wherein in step e, said coal particles and said conveying gas are introduced through the substantially axially central portion of the bottom of said zone.
Claim 4
Dependent Claim
47 words
A process as defined in claim 2 wherein said coal particles and said conveying gas are introduced into the lower portion of said zone through at least one inlet having a constricted cross-sectional area designed to accelerate said coal particles and said conveying gas to said velocity.
Claim 5
Dependent Claim
29 words
A process as defined in claim 3 wherein said coal particles and said conveying gas are introduced into said lower portion of said zone through a multiplicity of inlets.
Claim 6
Dependent Claim
23 words
A process as defined in claim 3 wherein the surface of said inlet through which said coal particles flow comprises a wear-resistant material.
Claim 7
Dependent Claim
14 words
A process as defined in claim 5 wherein said wear-resistant material is tungsten carbide.
Claim 8
Dependent Claim
23 words
A process as defined in claim 1 wherein in step g, said average solids residence time is about 8 to about 30 minutes.
Claim 9
Dependent Claim
41 words
A process as defined in claim 1 wherein in step d, said non-agglomerating particles comprise partially reacted coal and char particles, and in step h, said hydrogen partial pressure in said zone is between about 200 p.s.i. and about 800 p.s.i.
Claim 10
Dependent Claim
20 words
A process as defined in claim 1 wherein said coal particles of step a comprise non-agglomeration sub-bituminous or lignitic coals.
Claim 11
Dependent Claim
23 words
A process as defined in claim 9 wherein said coal particles have at no time been exposed to oxidizing conditions prior to hydrocarbonization.
Claim 12
Dependent Claim
18 words
A process as defined in claim 1 wherein said coal particles are finer than about 8 Tyler mesh.
Claim 13
Dependent Claim
18 words
A process as defined in claim 1 wherein said coal particles of step a comprise agglomerating bituminous coals.
Claim 14
Dependent Claim
20 words
A process as defined in claim 1 wherein said coal particles velocity is greater than about 400 feet per second.
Claim 15
Dependent Claim
41 words
A process as defined in claim 1 further including in step e introducing a stream of recycle oil into the lower portion of said zone in an essentially vertically upwards direction at a velocity greater than about 200 feet per second.
Claim 16
Dependent Claim
20 words
A process as defined in claim 14 wherein said recycle oil velocity is greater than about 400 feet per second.
Claim 17
Dependent Claim
21 words
A process as defined in claim 1 wherein said predetermined preheat temperature is between about 200° C and about 375° C.
Claim 18
Dependent Claim
21 words
A process as defined in claim 16 wherein said predetermined preheat temperature is between about 325° C and about 375° C.
Claim 19
Dependent Claim
32 words
A process as defined in claim 1 further including after step i, j. lowering the temperature of said solid char product to a temperature between about 300° C and about 375° C.
Claim 20
Dependent Claim
77 words
A process as defined in claim 1 wherein the reaction temperature, hydrogen partial pressure and solids residence time conform to the equation: S.sub.H = T(P).sup.0.067 (t).sup.0.067 wherein S H is a hydrocarbonization severity factor having a value of from 550 to 700; T is the hydrocarbonization temperature in ° C; P is the log mean average hydrogen partial pressure in said hydrocarbonization zone in psi divided by 1000; and t is the solids residence time in minutes.
Claim 21
Dependent Claim
66 words
A process as defined in claim 19 where in order to maximize total liquid product and minimize hydrogen consumption, the temperature and vapor residence time conform to the equation: S.sub.c = T(θ).sup.0.048 wherein S c is a vapor cracking severity factor having a value of from 600 to 690; T is the temperature is ° C; and θ is the average vapor residence time in seconds.