Patent US1779460A successfully refreshed from Google Patents.
Patent US3985928A successfully refreshed from Google Patents.
US3985928A
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US
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Heat-resistant laminating resin composition and method for using same
Assignee: Sumitomo Bakelite Co Ltd
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Filing: 1975-04-28
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Granted: 1976-10-12
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Expires: 1995-04-28
Abstract
Abstract A heat-resistant resin composition suitable for use in multilayer super high density printed circuit boards, comprising a polyaminobismaleimide, a polyepoxy compound, and an aromatic vinyl copolymer containing as structural unit maleic anhydride and/or an alkyl maleate. This resin composition is excellent in thermal resistance and dimensional stability, which are important properties of a resin composition for practical use in lamination, and when used in lamination, exhibits favorable flow and curing properties so that it can be easily and economically processed under conventional laminating conditions. When used as a multilayer printed circuit board material, it is also characterized by excellent adhesion to a copper foil, particularly in bonding an inner circuit copper foil to the board. Although particularly suitable for use in multilayer printed circuit boards of numerous layers (eight or more layers) bearing highly packed circuits and as an interlayer adhesive sheet, the present resin composition can be used in general heat-resistant printed circuit boards and in general heat-resistant structural laminates.
Inventors
- 👤 Tsutomu Watanabe
- 👤 Sigenori Yamaoka
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 21:36
CPC Classifications
B; B32; B32B; B32B15/00; B32B15/14; B32B38/00; B32B38/08; C; C08; C08G; C08G59/00; C08G59/18; C08G59/40; C08G59/4007; C08G59/4014; C08G59/4042; C08J; C08J5/00; C08J5/24; C08J5/241; C08J5/244; C08L; C08L35/00; C08L63/00; C08L79/00; C08L79/04; C08L79/08; C08L79/085; H; H05; H05K; H05K1/00; H05K1/02; H05K1/03; H05K1/0313; H05K1/032; H05K1/0346; B32B2305/00; B32B2305/07; B32B2305/076; B32B2307/00; B32B2307/30; B32B2307/306; B32B2457/00; B32B2457/08; C08J2379/00; C08J2379/04; C08J2379/08; Y; Y10; Y10S; Y10S428/00; Y10S428/901; Y10S428/92; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31525; Y10T428/31529; Y10T428/31551; Y10T428/31623; Y10T428/31721; Y10T442/00; Y10T442/20; Y10T442/2631; Y10T442/2713; Y10T442/30; Y10T442/3472; Y10T442/3504; Y10T442/3512
Claims Analysis
Total Claims: 26
Claim 1
Independent Claim
132 words
A heat-resistant laminating resin composition consisting essentially of 100 parts by weight of a polyaminobismaleimide obtained by reacting at least one N,N'-bismaleimide represented by the general formula [I], ##EQU1## wherein R represents an aliphatic, cycloaliphatic, or aromatic divalent radical, with at least one diamine selected from the group consisting of aliphatic diamines, cycloaliphatic diamines, and aromatic diamines, 10 to 300 parts by weight of a polyepoxy compound having in the molecule at least two epoxy groups, and 5 to 150 parts by weight of at least one copolymer selected from the group consisting of (A) copolymers of aromatic vinyl compounds and maleic anhydride, (B) partial alkyl esters of said copolymers (A), (C) copolymers of aromatic vinyl compounds and alkyl maleates, and (D) copolymers of aromatic vinyl compounds, maleic anhydride, and alkyl maleates.
Claim 2
Dependent Claim
132 words
A heat-resistant laminating resin composition consisting essentially of 100 parts by weight of a polyaminobismaleimide obtained by reacting at least one N,N'-bismaleimide represented by the general formula [I], ##EQU1## wherein R represents an aliphatic, cycloaliphatic, or aromatic divalent radical, with at least one diamine selected from the group consisting of aliphatic diamines, cycloaliphatic diamines, and aromatic diamines, 10 to 300 parts by weight of a polyepoxy compound having in the molecule at least two epoxy groups, and 5 to 150 parts by weight of at least one copolymer selected from the group consisting of (A) copolymers of aromatic vinyl compounds and maleic anhydride, (B) partial alkyl esters of said copolymers (A), (C) copolymers of aromatic vinyl compounds and alkyl maleates, and (D) copolymers of aromatic vinyl compounds, maleic anhydride, and alkyl maleates.
Claim 3
Dependent Claim
42 words
A heat-resistant laminating resin composition according to claim 1, wherein the ratio of the N,N'-bismaleimide to the diamine is one mole of the double bond present in said bisimide to 0.5 to 3 moles of the active hydrogen present in said diamine.
Claim 4
Dependent Claim
24 words
A heat-resistant laminating resin composition according to claim 1, wherein the polyaminobismaleimide has a melting point in the range from 50° to 150° C.
Claim 5
Dependent Claim
25 words
A heat-resistant laminating resin composition according to claim 1, wherein the polyepoxy compound is an epoxy resin having an epoxy equivalent of 100 to 4,000.
Claim 6
Dependent Claim
26 words
A heat-resistant laminating resin composition according to claim 1, wherein the copolymer (A) contains in the molecule at least 30 mole-% of maleic anhydride structural units.
Claim 7
Dependent Claim
32 words
A heat-resistant laminating resin composition according to claim 1, wherein the copolymer (B) has an esterification degree of at most 50 mole-% based on the total maleic anhydride structural units before esterification.
Claim 8
Dependent Claim
26 words
A heat-resistant laminating resin composition according to claim 1, wherein the copolymer (C) contans in the molecle at least 30 mole-% of monoalkyl maleate structural units.
Claim 9
Dependent Claim
35 words
A heat-resistant laminating resin composition according to claim 1, wherein the copolymer (D) contains in the molecule at least 30 mole-%, in total, of the maleic anhydride structural units and the monoalkyl maleate structural units.
Claim 10
Dependent Claim
44 words
A heat-resistant laminating resin composition according to claim 1, wherein the weight ratio of the polyepoxy compound to the at least one copolymer selected from the group consisting of the copolymers (A), (B), (C), and (D) is in the range from 0.5 to 10.0.
Claim 11
Dependent Claim
52 words
A method for preparing a heat-resistant laminating resin prepreg, which is characterized by impregnating a fibrous insulating base material with a varnish obtained by dissolving the resin composition according to claim 1 in an inert solvent, heating the impregnated base material to dryness to alloy the resin composition to react the B-stage.
Claim 12
Dependent Claim
39 words
A method for manufacturing a heat-resistant resin laminate, which comprises applying simultaneously heat and pressure to one sheet of or a stack of several tens of superposed sheets of the prepreg obtained by the method according to claim 10.
Claim 13
Dependent Claim
49 words
A method for manufacturing a metal-clad heat-resistant resin laminate, which comprises applying simultaneously heat and pressure to one sheet of or a stack of several tens of superposed sheets of the prepreg obtained by the method according to claim 10, said stack having been overlaid with a metal foil.
Claim 14
Dependent Claim
16 words
A method according to claim 10, wherein the fibrous insulating base material is a glass fabric.
Claim 15
Dependent Claim
16 words
A method according to claim 11, wherein the fibrous insulating base material is a glass fabric.
Claim 16
Dependent Claim
16 words
A method according to claim 12, wherein the fibrous insulating base material is a glass fabric.
Claim 17
Dependent Claim
14 words
A method according to claim 15, wherein the metal foil is a copper foil.
Claim 18
Dependent Claim
44 words
A method for manufacturing a multilayer heat-resistant resin printed circuit board, which comprises using the prepreg obtained by the method according to claim 13 as an inner circuit board and/or a surface circuit board and/or an interlayer adhesive sheet and applying heat and pressure.
Claim 19
Dependent Claim
12 words
A heat-resistant resin prepreg obtained by the method according to claim 10.
Claim 20
Dependent Claim
12 words
A heat-resistant resin prepreg obtained by the method according to claim 13.
Claim 21
Dependent Claim
12 words
A heat-resistant resin laminate obtained by the method according to claim 11.
Claim 22
Dependent Claim
12 words
A heat-resistant resin laminate obtained by the method according to claim 14.
Claim 23
Dependent Claim
13 words
A metal-clad heat-resistant resin laminate obtained by the method according to claim 12.
Claim 24
Dependent Claim
13 words
A metal-clad heat-resistant resin laminate obtained by the method according to claim 15.
Claim 25
Dependent Claim
13 words
A copper-clad heat-resistant resin laminate obtained by the metod according to claim 16.
Claim 26
Dependent Claim
14 words
A multilayer heat-resistant printed circuit board obtained by the method according to claim 17.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-10-12 | 1980-04-12 | 1980-10-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-10-12 | 1984-04-12 | 1984-10-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-10-12 | 1988-04-12 | 1988-10-12 | $7700.00 | Window Closed / Lapsed |