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US3985823A Expired / Lapsed US ⏱️ 0.0 years remaining

Isoparaffin-olefin alkylation with HF alkylation and isomerization in a soaking zone

Assignee: Honeywell UOP LLC
•
Filing: 1975-12-22
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Granted: 1976-10-12
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Expires: 1995-12-22
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Abstract

Abstract A process for producing hydrocarbon alkylate from an isoparaffin and an olefin-acting agent. The isoparaffin, the olefin and a first, relatively low strength hydrogen fluoride catalyst are contacted in an alkylation reaction to form a reaction mixture, the reaction mixture is settled to separate a first hydrocarbon phase from the low strength catalyst phase, the first hydrocarbon phase is admixed with a second, relatively higher strength hydrogen fluoride catalyst phase in an alkylation soaker, the effluent from the soaker is settled to separate a second hydrocarbon phase from the high strength catalyst phase, and the hydrocarbon alkylate is recovered from the second hydrocarbon phase.

Inventors

  • 👤 Jay E. Sobel
  • 👤 Bipin V. Vora

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 10:56
CPC Classifications
C; C07; C07C; C07C9/00; C07C9/14; C07C9/16; C07C2/00; C07C2/54; C07C2/56; C07C2/58; C07C2/62; C07C2/86; C07C2/861; C07C5/00; C07C5/22; C07C5/27; C07C5/2767; C07C5/277; C07C5/2778; C07C5/2786; C07C2527/00; C07C2527/06; C07C2527/08; C07C2527/12; C07C2527/1206

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 223 words
A process for producing an alkylation reaction product from an isoparaffin and an olefin, which comprises the steps of: a. reacting said olefin with said isoparaffin in admixture with a relatively low strength hydrogen fluoride catalyst containing 75 to 95 wt. percent HF at a catalyst to hydrocarbon volume ratio of 1:1 to 5:1; b. settling the resultant reaction mixture of step (a) to separate the same into a hydrocarbon phase and a catalyst phase; c. commingling with said hydrocarbon phase, without further addition of olefin, a relatively high strength catalyst of hydrogen fluoride and organic diluent containing 90 to 98 wt. percent HF, and 2 to 10 wt. percent of organic diluent, said catalyst having a higher strength than the catalyst utilized in step (a) and in a lower catalyst to hydrocarbon volume ratio than step (a); d. introducing the resulting mixture of step (c) into a soaking zone and therein isomerizing lower octane alkylate hydrocarbons to higher octane alkylate hydrocarbons, converting alkyl fluorides into high quality alkylate and HF acid, by maintaining said mixture in the soaking zone at a temperature of 50° to 120° F for 5 to 20 minutes; e. separating the effluent of the soaking zone into a second hydrocarbon phase and a second catalyst phase, and; f. recovering said alkylation reaction product from said second hydrocarbon phase.
Claim 2
Dependent Claim 223 words
A process for producing an alkylation reaction product from an isoparaffin and an olefin, which comprises the steps of: a. reacting said olefin with said isoparaffin in admixture with a relatively low strength hydrogen fluoride catalyst containing 75 to 95 wt. percent HF at a catalyst to hydrocarbon volume ratio of 1:1 to 5:1; b. settling the resultant reaction mixture of step (a) to separate the same into a hydrocarbon phase and a catalyst phase; c. commingling with said hydrocarbon phase, without further addition of olefin, a relatively high strength catalyst of hydrogen fluoride and organic diluent containing 90 to 98 wt. percent HF, and 2 to 10 wt. percent of organic diluent, said catalyst having a higher strength than the catalyst utilized in step (a) and in a lower catalyst to hydrocarbon volume ratio than step (a); d. introducing the resulting mixture of step (c) into a soaking zone and therein isomerizing lower octane alkylate hydrocarbons to higher octane alkylate hydrocarbons, converting alkyl fluorides into high quality alkylate and HF acid, by maintaining said mixture in the soaking zone at a temperature of 50° to 120° F for 5 to 20 minutes; e. separating the effluent of the soaking zone into a second hydrocarbon phase and a second catalyst phase, and; f. recovering said alkylation reaction product from said second hydrocarbon phase.
Claim 3
Dependent Claim 20 words
The process of claim 1 wherein at least a portion of said second catalyst phase is supplied to step (a).
Claim 4
Dependent Claim 31 words
The process of claim 1 wherein the strength of said second catalyst phase is controlled by admixing substantially pure hydrogen fluoride with said low strength hydrogen fluoride catalyst from step (a).
Claim 5
Dependent Claim 30 words
The process of claim 1 wherein the relatively high strength hydrogen fluoride catalyst in step (c) contains about 95 wt. percent HF acid and about 5 wt. percent organic diluent.
Claim 6
Dependent Claim 28 words
The process of claim 1 wherein at least a portion of said second catalyst phase is recycled to said soaking zone after separation from said second hydrocarbon phase.
Claim 7
Dependent Claim 37 words
The process of claim 1 wherein from about 0.01 to about 1 volume of said second catalyst phase is introduced into said soaking zone for each volume of said first hydrocarbon phase introduced into said soaking zone.
Claim 8
Dependent Claim 18 words
The process of claim 1 wherein said low strength catalyst phase contains 80 to 98 wt. percent HF.
Claim 9
Dependent Claim 10 words
The process of claim 1 wherein said isoparaffin is isobutane.
Claim 10
Dependent Claim 17 words
The process of claim 1 wherein said olefin-acting agent is mono-olefin selected from propylene, butenes and pentenes.
Claim 11
Dependent Claim 22 words
The process of claim 1 wherein said olefin-acting agent is an alkyl fluoride selected from propyl fluoride, butyl fluorides and pentyl fluorides.

References Cited (Backward Citations)

US2376060A Cited
US2430228A Cited
US3204011A Cited
US3408419A Cited
US3560587A Cited
US3607970A Cited
US3784628A Cited
US3787518A Cited
US3780131A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-12 1980-04-12 1980-10-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-12 1984-04-12 1984-10-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-12 1988-04-12 1988-10-12 $7700.00 Window Closed / Lapsed

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