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US3984248A
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Photographic polymeric film supports containing photobleachable o-nitroarylidene dyes
Assignee: Eastman Kodak Co
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Filing: 1975-02-03
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Granted: 1976-10-05
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Expires: 1995-02-03
Abstract
Abstract Novel o-nitro-substituted arylidene dyes are provided in which the o-nitro aryl group of the arylidene dye is joined through a methine chain linkage to a basic heterocyclic radical containing an electron donating atom. These dyes are photobleachable. The photobleachable properties are useful to provide light-sensitive elements in which images can be formed in or on a support by exposure to light to which the dye is sensitive and to provide photobleachable halation protection in photographic elements having coated thereon a photographic imaging layer. The o-nitro-substituted arylidene dyes can be used for antihalation purposes in photothermographic elements. The dyes can be incorporated within silver halide emulsions to reduce internal light scattering (i.e., internal halation) or to desensitize the emulsion. The dyes are also useful in filter layers.
Inventors
- 👤 David M. Sturmer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 15:36
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/36; C; C09; C09B; C09B23/00; C09B23/02; G03C1/76; G03C1/825; G03C1/83; G03C1/832
Claims Analysis
Total Claims: 16
Claim 1
Independent Claim
123 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye which has the following formula: ##EQU1## wherein: a. k represents 0 or 1; b. m represents 0 or 1; c. each L represents a methine group; d. A represents oxygen, sulfur or N--R 1 ; e. R 1 represents an alkyl group, an alkenyl group or an aryl group; f. Z 1 represents the nonmetallic atoms completing a 5- or 6-membered heterocyclic ring whose skeletal atoms consist of the oxygen, sulfur or nitrogen atom of A, carbon atoms and one other atom chosen from the group consisting of carbon, oxygen, nitrogen, selenium and sulfur atoms, and g. Y represents the atoms necessary to complete a nitro-substituted phenyl or naphthyl group.
Claim 2
Dependent Claim
123 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye which has the following formula: ##EQU1## wherein: a. k represents 0 or 1; b. m represents 0 or 1; c. each L represents a methine group; d. A represents oxygen, sulfur or N--R 1 ; e. R 1 represents an alkyl group, an alkenyl group or an aryl group; f. Z 1 represents the nonmetallic atoms completing a 5- or 6-membered heterocyclic ring whose skeletal atoms consist of the oxygen, sulfur or nitrogen atom of A, carbon atoms and one other atom chosen from the group consisting of carbon, oxygen, nitrogen, selenium and sulfur atoms, and g. Y represents the atoms necessary to complete a nitro-substituted phenyl or naphthyl group.
Claim 3
Dependent Claim
37 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 1 in which said dye is present in an amount sufficient to impart an optical density to said support of 0.20.
Claim 4
Dependent Claim
37 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 2 in which said dye is present in an amount sufficient to impart an optical density to said support of 0.50.
Claim 5
Dependent Claim
29 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 1 in which said film support is a solvent cast photographic film support.
Claim 6
Dependent Claim
30 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 1 in which said film support is a melt formed polymeric photographic film support.
Claim 7
Dependent Claim
32 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 1 in which said film support is comprised of a polyalkylene or a terephthalic acid polyester.
Claim 8
Dependent Claim
29 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 6 in which said film support is comprised of polyethylene or poly(ethylene tetephthalate).
Claim 9
Dependent Claim
68 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 1 wherein Z 1 represents the nonmetallic atoms completing a thiazole nucleus, an oxazole nucleus, a selenazole nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, an indolenine nucleus, an imidazo[4,5-b]quinoxaline nucleus, a 3H-pyrrolo[2,3-b]pyridine nucleus, a thiazolo[4,5-b]quinoline nucleus, a 2H-pyran nucleus, a 4H-pyran nucleus or a dithiolane nucleus.
Claim 10
Dependent Claim
58 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye according to claim 1 wherein Y represents the atoms necessary to complete a nitro-substituted phenyl group having a 6-ring position electron-withdrawing group, a nitro-substituted phenyl or 1-naphthyl group having a 4-ring position electron-withdrawing group, a nitro-substituted phenyl group having 4- and 6-ring position electron-withdrawing groups.
Claim 11
Dependent Claim
153 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye having the following formula: ##STR12## wherein: a. k represents 0 or 1; b. m represents 0 or 1; c. each L represents a methine group; d. A represents oxygen, sulfur or N--R 1 ; e. Z 1 represents the nonmetallic atoms completing a 5- or 6-membered heterocyclic ring selected from the group consisting of an oxazole nucleus, a thiazole nucleus, a selenazole nucleus, a 3,3-dialkylindolenine nucleus, an imidazo[4,5-b]quinoxaline nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, a 3H-pyrrolo[2,3-b]pyridine nucleus and a thizolo[4,5-b]quinoline nucleus, a 2H-pyran nucleus, a 4H-pyran nucleus and a dithiolane nucleus; and f. Y represents the atoms necessary to complete a nitro-substituted phenyl or 1-naphthyl group having a 4-ring position electron-withdrawing group, a nitro-substituted phenyl group having a 6-position electron-withdrawing group or a nitro-substituted phenyl group having 4- and 6-ring position electron-withdrawing groups.
Claim 12
Dependent Claim
153 words
An otherwise transparent polymeric photographic film support having incorporated therein a photobleachable dye having the following formula: ##STR12## wherein: a. k represents 0 or 1; b. m represents 0 or 1; c. each L represents a methine group; d. A represents oxygen, sulfur or N--R 1 ; e. Z 1 represents the nonmetallic atoms completing a 5- or 6-membered heterocyclic ring selected from the group consisting of an oxazole nucleus, a thiazole nucleus, a selenazole nucleus, a 3,3-dialkylindolenine nucleus, an imidazo[4,5-b]quinoxaline nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, a 3H-pyrrolo[2,3-b]pyridine nucleus and a thizolo[4,5-b]quinoline nucleus, a 2H-pyran nucleus, a 4H-pyran nucleus and a dithiolane nucleus; and f. Y represents the atoms necessary to complete a nitro-substituted phenyl or 1-naphthyl group having a 4-ring position electron-withdrawing group, a nitro-substituted phenyl group having a 6-position electron-withdrawing group or a nitro-substituted phenyl group having 4- and 6-ring position electron-withdrawing groups.
Claim 13
Dependent Claim
25 words
An otherwise transparent polymeric photographic film support consisting essentially of polyethylene or poly(ethylene terephthalate) having incorporated therein a photobleachable dye, wherein said dye is 6-chloro-2-(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline.
Claim 14
Dependent Claim
25 words
An otherwise transparent polymeric photographic film support consisting essentially of polyethylene or poly(ethylene terephthalate) having incorporated therein a photobleachable dye, wherein said dye is 6-chloro-2-(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline.
Claim 15
Dependent Claim
39 words
An otherwise transparent polymeric photographic film support consisting essentially of polyethylene or poly(ethylene terephthalate) having incorporated therein a photobleachable dye, wherein said dye is selected from: a. 2(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline; b. 2-(2,4-dinitrobenzylidene)-3-ethyl-2,3-dihydrothiazolo[4,5-b]quinoline; c. 2-(2,4-dinitrobenzylidene)-3-ethyl-6-nitrobenzothiazoline; d. 2-(2,4-dinitrobenzylidene)-1,3,3-trimethylindolenine; e. 4-(2,4-dinitrobenzylidene)-1-ethylquinoline; and f. 4-(2,4-dinitrobenzylidene)-2,6-diphenyl-4H-pyran.
Claim 16
Dependent Claim
39 words
An otherwise transparent polymeric photographic film support consisting essentially of polyethylene or poly(ethylene terephthalate) having incorporated therein a photobleachable dye, wherein said dye is selected from: a. 2(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline; b. 2-(2,4-dinitrobenzylidene)-3-ethyl-2,3-dihydrothiazolo[4,5-b]quinoline; c. 2-(2,4-dinitrobenzylidene)-3-ethyl-6-nitrobenzothiazoline; d. 2-(2,4-dinitrobenzylidene)-1,3,3-trimethylindolenine; e. 4-(2,4-dinitrobenzylidene)-1-ethylquinoline; and f. 4-(2,4-dinitrobenzylidene)-2,6-diphenyl-4H-pyran.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1979-10-05 | 1980-04-05 | 1980-10-05 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1983-10-05 | 1984-04-05 | 1984-10-05 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1987-10-05 | 1988-04-05 | 1988-10-05 | $7700.00 | Window Closed / Lapsed |