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US3984243A Expired / Lapsed US ⏱️ 0.0 years remaining

Photographic developer compositions for obtaining high contrast images

Assignee: Fujifilm Holdings Corp
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Filing: 1973-12-21
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Granted: 1976-10-05
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Expires: 1993-12-21
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Abstract

Abstract A photographic developer composition for obtaining high contrast images which comprises (1) a dihydroxybenzene developing agent, (2) an alkanolamine and (3) a compound having the following formula (I) ##SPC1## wherein R 1 and R 2 each represents a lower aliphatic hydrocarbon group, wherein R 1 and R 2 may combine to form a ring, n represents 0 or 1, and X.sup.⊖ represents an anion.

Inventors

  • 👤 Isao Shimamura
  • 👤 Yoo Iijima
  • 👤 Katsumi Hayashi
  • 👤 Haruhiko Iwano
  • 👤 Tadao Shishido

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 13:13
CPC Classifications
G; G03; G03C; G03C5/00; G03C5/26; G03C5/29; G03C5/305

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 152 words
A photographic developer composition for obtaining high contrast images which comprises (1) a p-dihydroxybenzene developing agent, (2) an alkanolamine which has the general formula ##EQU1## wherein R is a hydroxyalkyl group having 1 to 5 carbon atoms and R 3 and R 4 are each a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, (3) a compound having the following formula (I) ##SPC5## wherein R 3 and R 4 each represents an alkyl group having from 1 to 5 carbon atoms, and wherein R 1 and R 2 may combine to form a 6-, 7- or 8-membered ring which may form an alkylene group or a vinylene group or which may further contain a benzene nucleus fused thereto, n represents 0 or 1, and X - represents an anion, and (4) sulfite in amounts of not more than 5g/l.
Claim 2
Dependent Claim 152 words
A photographic developer composition for obtaining high contrast images which comprises (1) a p-dihydroxybenzene developing agent, (2) an alkanolamine which has the general formula ##EQU1## wherein R is a hydroxyalkyl group having 1 to 5 carbon atoms and R 3 and R 4 are each a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or a hydroxyalkyl group having 1 to 3 carbon atoms, (3) a compound having the following formula (I) ##SPC5## wherein R 3 and R 4 each represents an alkyl group having from 1 to 5 carbon atoms, and wherein R 1 and R 2 may combine to form a 6-, 7- or 8-membered ring which may form an alkylene group or a vinylene group or which may further contain a benzene nucleus fused thereto, n represents 0 or 1, and X - represents an anion, and (4) sulfite in amounts of not more than 5g/l.
Claim 3
Dependent Claim 14 words
The photographic developer composition of claim 1, wherein said compound having the formula ##SPC6##
Claim 4
Dependent Claim 17 words
The photographic developer composition of claim 1, wherein said dihydroxybenzene developing agent is a hydroquinone developing agent.
Claim 5
Dependent Claim 22 words
The photographic developer composition of claim 3, wherein said hydroquinone developing agent is hydroquinone, chlorohydroquinone, bromohydroquinone, isopropylhydroquinone, toluhydroquinone, methylhydroquinone, 2,3-dichlorohydroquinone or 2,5-dimethylhydroquinone.
Claim 6
Dependent Claim 14 words
The photographic developer composition of claim 4, wherein said hydroquinone developing agent is hydroquinone.
Claim 7
Dependent Claim 17 words
The photographic developer composition of claim 1, wherein said alkanolamine is tertiary alkanolamine or a secondary alkanolamine.
Claim 8
Dependent Claim 16 words
The photographic developer composition of claim 6, wherein said alkanolamine is diethanolamine, diisopropylamine, triethanolamine or triisopropanolamine.
Claim 9
Dependent Claim 89 words
The photographic developer composition of claim 1, wherein said dihydroxybenzene developing agent, said alkanolamine and said compound having the formula (I) are present in said composition so as to provide from 5 to 50 grams per liter of a developer prepared therefrom for said dihydroxybenzene developing agent, 5 to 400 grams per liter of a developer solution prepared therefrom for said alkanolamine and from 1 × 10.sup. -5 to 1 × 10.sup. -2 mols per liter of a developer solution prepared therefrom for said compound having the formula (I).
Claim 10
Dependent Claim 31 words
The photographic developer composition of claim 1, wherein said developer composition contains at least one of a sulfite ion buffer, an alkali metal sulfite salt, an alkali and a pH buffer.
Claim 11
Dependent Claim 25 words
The photographic developer composition of claim 9, wherein said developer composition contains at least 1 of an antioxidant, an antifogging agent, and a water softener.
Claim 12
Dependent Claim 38 words
A method for the development of imagewise exposed high contrast photographic materials having a silver halide layer containing not less than 50 mol% silver chloride comprising developing said photographic materials in the photographic developer composition of claim 1.
Claim 13
Dependent Claim 16 words
The method for development of claim 11, wherein said compound having the formula (I) is ##SPC7##
Claim 14
Dependent Claim 17 words
The method of development of claim 11, wherein said dihydroxybenzene developing agent is a hydroquinone developing agent.
Claim 15
Dependent Claim 22 words
The method of development of claim 13, wherein said hydroquinone developing agent is hydroquinone, chlorohydroquinone, bromohydroquinone, isopropylhydroquinone, toluhydroquinone, methylhydroquinone, 2,3-dichlorohydroquinone or 2,5-dimethylhydroquinone.
Claim 16
Dependent Claim 14 words
The method of development of claim 14, wherein said hydroquinone developing agent is hydroquinone.
Claim 17
Dependent Claim 18 words
The method of development of claim 11, wherein said alkanolamine is a tertiary alkanolamine or a secondary alkanolamine.
Claim 18
Dependent Claim 16 words
The method of development of claim 16, wherein said alkanolamine is diethanolamine, diisopropylamine, triethanolamine or triisopropanolamine.
Claim 19
Dependent Claim 90 words
The method of development of claim 11, wherein said dihydroxybenzene developing agent, said alkanolamine and said compound having the formula (I) are present in said composition so as to provide from 5 to 50 grams per liter of a developer solution prepared therefrom for said dihydroxybenzene developing agent, 5 to 400 grams per liter of a developer solution prepared therefrom for said alkanolamine and from 1 × 10.sup. -5 to 1 × 10.sup. -2 mols per liter of a developer solution prepared therefrom for said compound having the formula (I).
Claim 20
Dependent Claim 31 words
The method of development of claim 11, wherein said developer composition contains at least one of a sulfite ion buffer, an alkali metal sulfite salt, an alkali and a pH buffer.
Claim 21
Dependent Claim 25 words
The method of development of claim 19, wherein said developer composition contains at least one of an antioxidant, an antifogging agent, and a water softener.

References Cited (Backward Citations)

US3615524A Cited
US3713827A Cited
US3615488A Cited
US3749574A Cited
US3708303A Cited
US3847618A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1979-10-05 1980-04-05 1980-10-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1983-10-05 1984-04-05 1984-10-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1987-10-05 1988-04-05 1988-10-05 $7700.00 Window Closed / Lapsed

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